/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 20 Indicate whether the following b... [FREE SOLUTION] | 91影视

91影视

Indicate whether the following balanced equations involve oxidation-reduction. If they do, identify the elements that undergo changes in oxidation number. $$ \text { (a) } 2 \mathrm{AgNO}_{3}(a q)+\mathrm{CoCl}_{2}(a q) \longrightarrow 2 \mathrm{AgCl}(s)+ $$ \(\mathrm{Co}\left(\mathrm{NO}_{3}\right)_{2}(a q)\) $$ \begin{array}{l} \text { (b) } 2 \mathrm{PbO}_{2}(s) \longrightarrow 2 \mathrm{PbO}(s)+\mathrm{O}_{2}(g) \\ \text { (c) } 2 \mathrm{H}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{NaBr}(s) \longrightarrow \mathrm{Br}_{2}(l)+\mathrm{SO}_{2}(g)+ \end{array} $$ \(\mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l)\)

Short Answer

Expert verified
(a) Not a redox reaction. (b) Redox, Pb reduced, O oxidized. (c) Redox, S reduced, Br oxidized.

Step by step solution

01

Analyze Equation (a)

For the equation \( 2 \text{AgNO}_3 (aq) + \text{CoCl}_2 (aq) \rightarrow 2 \text{AgCl} (s) + \text{Co}(\text{NO}_3)_2 (aq) \), note that silver (Ag) is always +1 in AgNO鈧 and AgCl. Cobalt (Co) stays +2 in both CoCl鈧 and Co(NO鈧)鈧. Chlorine (Cl) remains -1 in both compounds, and nitrogen (N) is +5, while oxygen (O) is -2 in both NO鈧冣伝 ions. Since no elements change oxidation states, this is not a redox reaction.
02

Analyze Equation (b)

For the equation \( 2 \text{PbO}_2 (s) \rightarrow 2 \text{PbO} (s) + \text{O}_2 (g) \), check the oxidation states: \( \text{Pb} \) in PbO鈧 is +4, while in PbO it is +2, indicating that lead is reduced. Oxygen goes from -2 in PbO鈧 to 0 in O鈧 as it is oxidized. Thus, this is an oxidation-reduction reaction where lead is reduced and oxygen is oxidized.
03

Analyze Equation (c)

For equation \( 2 \text{H}_2\text{SO}_4 (aq) + 2 \text{NaBr} (s) \rightarrow \text{Br}_2 (l) + \text{SO}_2 (g) + \text{Na}_2\text{SO}_4 (aq) + 2 \text{H}_2\text{O} (l) \), sulfur (S) in H鈧係O鈧 is +6 and in SO鈧 remains +4, indicating sulfur is reduced. Bromine (Br) in NaBr is -1 and becomes 0 in Br鈧, indicating oxidation of bromine. This confirms it is an oxidation-reduction reaction where sulfur is reduced and bromine is oxidized.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation States
Understanding oxidation states is crucial for identifying redox reactions. An oxidation state is a number assigned to an element in a compound, reflecting the number of electrons lost or gained by an atom. This helps in determining whether an element is oxidized or reduced during a chemical reaction. In a nutshell, the more positive the oxidation state, the more electrons have been lost (oxidation), and vice versa for reduction where electrons are gained. For example, in \(\text{Step 1}\) of our original problem, we see that in the reaction of \(2 \text{AgNO}_3 (aq) + \text{CoCl}_2 (aq) \rightarrow 2 \text{AgCl} (s) + \text{Co(NO}_3)_2 (aq)\), nothing changes in the oxidation states of silver, cobalt, chlorine, nitrogen, or oxygen, hence no redox reaction occurs. On the other hand, in \(\text{Step 2}\), \(2 \text{PbO}_2 (s) \rightarrow 2 \text{PbO} (s) + \text{O}_2 (g)\), lead's oxidation state falls from +4 to +2 (reduction), while oxygen's state increases from -2 to 0 (oxidation). This shift indicates that a redox reaction is taking place. Remember, identifying changes in oxidation states in any chemical equation is the first step in recognizing an oxidation-reduction reaction.
Chemical Equations
Chemical equations represent chemical reactions using symbols and formulas. They consist of reactants (the starting materials) on the left and products (the substances formed) on the right, with an arrow pointing from reactants to products. Balancing these equations is essential because it ensures the conservation of mass, meaning the same type and number of atoms are present on both sides of the equation.When dealing with redox reactions, it is crucial to not only balance atoms, but also to account for changes in oxidation states. In equation (b) \(2 \text{PbO}_2 \rightarrow 2 \text{PbO} + \text{O}_2\), we see the balancing of atoms and charges, reflecting the transfer of electrons that defines a redox change: lead is reduced and oxygen is oxidized.Chemical equations become a powerful tool in analyzing redox processes by systematically showing these transformations and helping us understand the overall flow of electrons.
Redox Reaction Analysis
Redox reaction analysis involves identifying which elements in a reaction route undergo oxidation and which are reduced. This understanding is essential because oxidation-reduction reactions involve electron transfer between substances. A straightforward way to identify such reactions is to look for changes in oxidation states. As we saw in step \(\text{Step 3}\), involving \(2 \text{H}_2\text{SO}_4 + 2 \text{NaBr} \rightarrow \text{Br}_2 + \text{SO}_2 + \text{Na}_2\text{SO}_4 + 2 \text{H}_2\text{O}\), sulfur goes from +6 in \(\text{H}_2\text{SO}_4\) to +4 in \(\text{SO}_2\), thus being reduced. Bromine shifts from -1 in NaBr to 0 in Br鈧, thus being oxidized.By systematically analyzing the changes in oxidation states, we can pinpoint which atoms donate electrons (oxidized) and which accept electrons (reduced). This method ensures we accurately identify and understand electron transfers in chemical reactions, enriching our comprehension of how reactions occur and interact.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

During the discharge of an alkaline battery, \(4.50 \mathrm{~g}\) of \(\mathrm{Zn}\) is consumed at the anode of the battery. (a) What mass of \(\mathrm{MnO}_{2}\) is reduced at the cathode during this discharge? (b) How many coulombs of electrical charge are transferred from \(\mathrm{Zn}\) to \(\mathrm{MnO}_{2} ?\)

Aqueous solutions of ammonia \(\left(\mathrm{NH}_{3}\right)\) and bleach (active ingredient \(\mathrm{NaOCl}\) ) are sold as cleaning fluids, but bottles of both of them warn: "Never mix ammonia and bleach, as toxic gases may be produced." One of the toxic gases that can be produced is chloroamine, \(\mathrm{NH}_{2} \mathrm{Cl}\). (a) What is the oxidation number of chlorine in bleach? (b) What is the oxidation number of chlorine in chloramine? (c) Is Cl oxidized, reduced, or neither, upon the conversion of bleach to chloramine? (d) Another toxic gas that can be produced is nitrogen trichloride, \(\mathrm{NCl}_{3}\). What is the oxidation number of \(\mathrm{N}\) in nitrogen trichloride? (e) Is N oxidized, reduced, or neither, upon the conversion of ammonia to nitrogen trichloride?

(a) What conditions must be met for a reduction potential to be a standard reduction potential? (b) What is the standard reduction potential of a standard hydrogen electrode? (c) Why is it impossible to measure the standard reduction potential of a single half-reaction?

Cytochrome, a complicated molecule that we will represent as \(\mathrm{CyFe}^{2+}\), reacts with the air we breathe to supply energy required to synthesize adenosine triphosphate (ATP). The body uses ATP as an energy source to drive other reactions (Section 19.7). At \(\mathrm{pH} 7.0\) the following reduction potentials pertain to this oxidation of \(\mathrm{CyFe}^{2+}\) : $$ \begin{aligned} \mathrm{O}_{2}(g)+4 \mathrm{H}^{+}(a q)+4 \mathrm{e}^{-} & \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(l) & E_{\mathrm{red}}^{\circ} &=+0.82 \mathrm{~V} \\\ \mathrm{CyFe}^{3+}(a q)+\mathrm{e}^{-} & \longrightarrow \mathrm{CyFe}^{2+}(a q) & E_{\mathrm{red}}^{\circ} &=+0.22 \mathrm{~V} \end{aligned} $$ (a) What is \(\Delta G\) for the oxidation of \(\mathrm{CyFe}^{2+}\) by air? \((\mathbf{b})\) If the synthesis of \(1.00 \mathrm{~mol}\) of ATP from adenosine diphosphate (ADP) requires a \(\Delta G\) of \(37.7 \mathrm{~kJ},\) how many moles of ATP are synthesized per mole of \(\mathrm{O}_{2} ?\)

A voltaic cell consists of a strip of cadmium metal in a solution of \(\mathrm{Cd}\left(\mathrm{NO}_{3}\right)_{2}\) in one beaker, and in the other beaker a platinum electrode is immersed in a NaCl solution, with \(\mathrm{Cl}_{2}\) gas bubbled around the electrode. A salt bridge connects the two beakers. (a) Which electrode serves as the anode, and which as the cathode? (b) Does the Cd electrode gain or lose mass as the cell reaction proceeds? (c) Write the equation for the overall cell reaction. (d) What is the emf generated by the cell under standard conditions?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.