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Hydrogen phosphate \(\left(\mathrm{HPO}_{4}^{2-}\right)\) can be removed in water treatment by the addition of slaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2} .\) Write a balanced chemical equation for the reaction (using ions as reactant), in which \(\mathrm{Ca}_{5}(\mathrm{OH})\left(\mathrm{PO}_{4}\right)_{3}\) forms as a precipitate.

Short Answer

Expert verified
The balanced reaction is \( 5\text{Ca(OH)}_2 + 3\text{HPO}_4^{2-} \rightarrow \text{Ca}_5(\text{OH})(\text{PO}_4)_3 + 3\text{H}_2\text{O} \).

Step by step solution

01

Identify the reactants

The reactants in this chemical reaction are hydrogen phosphate ions \( \text{HPO}_4^{2-} \) and slaked lime \( \text{Ca(OH)}_2 \). These will react with each other in the solution.
02

Write the products

When these reactants interact, one of the products is a precipitate known as calcium hydroxyapatite, \( \text{Ca}_5(\text{OH})(\text{PO}_4)_3 \), and water is also formed in this reaction.
03

Balance the atoms involved

To balance the chemical equation, ensure that the number of atoms for each element is equal on both sides of the equation. The balanced equation is:\[ 5\text{Ca(OH)}_2 + 3\text{HPO}_4^{2-} \rightarrow \text{Ca}_5(\text{OH})(\text{PO}_4)_3 + 3\text{H}_2\text{O} \]Here, the calcium \( \text{Ca} \), phosphate \( \text{PO}_4^{3-} \), hydrogen \( \text{H} \), and oxygen \( \text{O} \) atoms are balanced on both sides of the equation.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balancing Chemical Equations
Balancing chemical equations is a crucial part of writing accurate representations of chemical reactions. It ensures that the law of conservation of mass is upheld, which states that matter cannot be created or destroyed in a chemical reaction. To balance a chemical equation effectively, you must have the same number of each type of atom on both sides of the equation.
When balancing equations, follow these steps:
  • Start by writing the skeleton equation with the correct formulae for all reactants and products. This includes ensuring the correct ionic forms and stoichiometry.
  • Count the number of atoms of each element on both the reactant and product sides.
  • Adjust coefficients—not subscripts—to get the same number of each type of atom on both sides. The coefficients are the numbers placed before compounds.
In our exercise, we balanced the reaction between hydrogen phosphate and slaked lime using these principles. By doing so, we ensure that each element's quantity remains constant across the reaction, providing a clear and correct depiction of the reaction occurring during water treatment.
Precipitation Reaction
A precipitation reaction occurs when two solutions are mixed and an insoluble solid, known as the precipitate, forms. This type of reaction is common in both laboratory experiments and real-world applications. During these reactions, ions from the solutions combine to form an insoluble compound that separates from the solution.
The exercise provided an example of a precipitation reaction where calcium ions from slaked lime and hydrogen phosphate ions from a solution form calcium hydroxyapatite, a solid precipitate. This reaction is represented as:\[5\text{Ca(OH)}_2 + 3\text{HPO}_4^{2-} \rightarrow \text{Ca}_5(\text{OH})(\text{PO}_4)_3 + 3\text{H}_2\text{O}\]This equation highlights the formation of a solid (\text{Ca}_5(\text{OH})(\text{PO}_4)_3) out of soluble reactants. Understanding precipitation reactions can help in predicting the outcomes of mixing various ionic compounds in solution, a valuable skill in areas like water treatment, agriculture, and environmental science.
Water Treatment Chemistry
Water treatment chemistry involves various chemical processes, including precipitation, to remove impurities from water. One common objective is to eliminate chemical compounds, such as phosphates, which can contribute to water pollution.
In the exercise example, hydrogen phosphate is removed from water by adding slaked lime, resulting in the formation of calcium hydroxyapatite, a compound that precipitates out of the solution and can be filtered off. This process is beneficial in reducing phosphate levels in water, thus minimizing the risk of eutrophication—a phenomenon where excessive nutrients lead to the overgrowth of algae and depletion of oxygen in water bodies.
Key benefits of using precipitation in water treatment include:
  • Effective removal of both inorganic and organic substances.
  • Reduction of nutrient loads, improving water quality.
  • Potential recovery of valuable materials from precipitates.
Water treatment processes like precipitation demonstrate the applied side of chemical equations, playing a critical role in environmental management and sustainability.

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Most popular questions from this chapter

A friend of yours has seen each of the following items in newspaper articles and would like an explanation: (a) acid rain, \((\mathbf{b})\) greenhouse gas, \((\mathbf{c})\) photochemical smog, (d) ozone depletion. Give a brief explanation of each term and identify one or two of the chemicals associated with each.

It was estimated that the eruption of the Mount Pinatubo volcano resulted in the injection of 20 million metric tons of \(\mathrm{SO}_{2}\) into the atmosphere. Most of this \(\mathrm{SO}_{2}\) underwent oxidation to \(\mathrm{SO}_{3}\), which reacts with atmospheric water to form an aerosol. (a) Write chemical equations for the processes leading to formation of the aerosol. (b) The aerosols caused a \(0.5-0.6^{\circ} \mathrm{C}\) drop in surface temperature in the northern hemisphere. What is the mechanism by which this occurs? (c) The sulfate aerosols, as they are called, also cause loss of ozone from the stratosphere. How might this occur?

Sulfur is present in seawater to the extent of \(0.09 \%\) by mass. Assuming that the sulfur is present as sulfate, \(\mathrm{SO}_{4}^{2-}\), calculate the corresponding molar concentration of \(\mathrm{SO}_{4}^{2-}\) in seawater.

A 500 megawatt electrical power plant typically burned (a) Assuming that 1,430,000 metric tons of coal in a year. the coal was \(80 \%\) carbon and \(3 \%\) sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide produced by the plant during the year. \((\mathbf{b})\) If \(50 \%\) of the \(\mathrm{SO}_{2}\) could be removed by reaction with powdered \(\mathrm{CaO}\) to form \(\mathrm{CaSO}_{3},\) how many tons of \(\mathrm{CaSO}_{3}\) would be produced?

Why is rainwater naturally acidic, even in the absence of polluting gases such as \(\mathrm{SO}_{2} ?\)

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