/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 99 Indicate whether each of the fol... [FREE SOLUTION] | 91影视

91影视

Indicate whether each of the following statements is correct or incorrect. (a) Every Br酶nsted-Lowry acid is also a Lewis acid. (b) Every Lewis acid is also a Br酶nsted-Lowry acid. (c) Conjugate acids of weak bases produce more acidic solutions than conjugate acids of strong bases. (d) \(\mathrm{K}^{+}\) ion is acidic in water because it causes hydrating water molecules to become more acidic. (e) The percent ionization of a weak acid in water increases as the concentration of acid decreases.

Short Answer

Expert verified
(a) Incorrect, (b) Incorrect, (c) Correct, (d) Incorrect, (e) Correct.

Step by step solution

01

Understand Br酶nsted-Lowry and Lewis Acid Definitions

Br酶nsted-Lowry acids are substances that donate a proton (H鈦), while Lewis acids are substances that accept an electron pair. Not all Br酶nsted-Lowry acids can accept an electron pair, making them not necessarily a Lewis acid. Hence, (a) is incorrect.
02

Examine Lewis and Br酶nsted-Lowry Acid Relationship

Lewis acids accept an electron pair, but they do not need to donate a proton to be an acid. Therefore, not all Lewis acids are Br酶nsted-Lowry acids. Thus, (b) is incorrect.
03

Conjugate Acids of Weak vs Strong Bases

A weak base has a strong conjugate acid because it tends to hold onto its proton, making it less stable and more reactive compared to conjugate acids of strong bases, which are more stable. Therefore, conjugate acids of weak bases are more acidic. So, (c) is correct.
04

Assessing Potassium Ion's Acidic Nature

The K鈦 ion does not significantly affect the acidity of water; it is a spectator ion that does not influence the acidity of hydrating water molecules. Hence, (d) is incorrect.
05

Analyzing Percent Ionization of Weak Acids

As the concentration of a weak acid decreases, the percent ionization increases due to dilution making the formation of ions more favorable as per Le Chatelier's principle. Therefore, (e) is correct.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Br酶nsted-Lowry Acid
In the realm of acid-base chemistry, the Br酶nsted-Lowry theory defines acids as substances that donate a proton, which is essentially a hydrogen ion, H鈦. This definition focuses on the transfer of protons during a chemical reaction.
Think of a Br酶nsted-Lowry acid as a donor. It has a hydrogen ion that it "gives away" to another substance, which is typically a base.
Unlike Lewis acids, Br酶nsted-Lowry acids specifically require the transfer of this proton. This distinction makes it clear that not all Br酶nsted-Lowry acids can be Lewis acids, since Lewis acids must accept an electron pair, rather than involve protons.
It's essential to recognize this unique behavior, which helps differentiate between these two acid descriptions in chemical reactions.
Lewis Acid
Lewis acids differ from Br酶nsted-Lowry acids by their ability to accept an electron pair instead of donating a proton.
Imagine Lewis acids as electron pair "acceptors," looking for a perfect electron match. This ability to accept electron pairs broadens the definition of acids beyond those involved in proton exchanges.
Some common examples of Lewis acids include substances like AlCl鈧 and BF鈧. These molecules accept electron pairs from other molecules or ions, typically bases, during chemical processes.
Notably, Lewis acids do not have to release protons, distinguishing them fundamentally from Br酶nsted-Lowry acids. This explains why not all Lewis acids qualify as Br酶nsted-Lowry acids.
Conjugate Acids
In acid-base reactions, the term "conjugate acid" refers to what forms when a base accepts a proton. It plays a vital role in identifying how a base changes in reaction.
A weak base typically has a strong conjugate acid since it tends to cling more firmly to the gained proton, making it more reactive and therefore more acidic than conjugate acids of strong bases.
Strong bases, on the contrary, have weaker conjugate acids. Since strong bases effectively donate electrons, their conjugate acids do not retain protons as aggressively.
This balance is crucial for understanding how different acids and bases behave in reactions, particularly when predicting solution acidity.
Percent Ionization
Percent ionization provides insight into how much a weak acid separates into its ions in a solution. It is a measure expressed as a percentage.
This concept is particularly notable for weak acids, which do not fully dissociate in water.
As the concentration of a weak acid decreases, it becomes more likely that the acid will ionize, or separate into ions. According to Le Chatelier's principle, reducing the concentration pushes the equilibrium towards further ionization.
Thus, the percent ionization increases with decreasing concentration, providing an essential concept for understanding weak acid behavior in dilute solutions.
Spectator Ions
Spectator ions are ions that appear in a chemical reaction but do not participate in the actual chemical change. They merely "observe" the reaction without undergoing any transformation themselves.
For instance, in a solution, the potassium ion, K鈦, serves as a spectator ion as it does not affect the acidity or basicity; it remains unchanged throughout the reaction.
The presence of spectator ions can often be disregarded in the net ionic equations of reactions because they do not influence the outcome.
Identifying these ions helps simplify chemical equations and focus on the ions or molecules directly involved in the reaction processes.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Ephedrine, a central nervous system stimulant, is used in nasal sprays as a decongestant. This compound is a weak organic base: $$ \mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ON}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ONH}^{+}(a q)+\mathrm{OH}^{-}(a q) $$ A \(0.035 \mathrm{M}\) solution of ephedrine has a \(\mathrm{pH}\) of 11.33 . (a) What are the equilibrium concentrations of \(\mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ON}, \mathrm{C}_{10} \mathrm{H}_{15} \mathrm{ONH}^{+},\) and \(\mathrm{OH}^{-} ?\) (b) Calculate \(K_{b}\) for ephedrine.

Which of the following statements is false? (a) An Arrhenius base increases the concentration of \(\mathrm{OH}^{-}\) in water. (b) A Bronsted-Lowry base is a proton acceptor. (c) Water can act as a Br酶nsted-Lowry acid. (d) Water can act as a Br酶nsted-Lowry base. (e) Any compound that contains an -OH group acts as a Bronsted-Lowry base.

Based on their compositions and structures and on conjugate acid-base relationships, select the stronger base in each of the following pairs: (a) \(\mathrm{NO}_{3}^{-}\) or \(\mathrm{NO}_{2}^{-},(\mathbf{b}) \mathrm{PO}_{4}^{3-}\) or \(\mathrm{AsO}_{4}^{3-},\) (c) \(\mathrm{HCO}_{3}^{-}\) or \(\mathrm{CO}_{3}^{2-}\).

A \(0.100 \mathrm{M}\) solution of bromoacetic acid \(\left(\mathrm{BrCH}_{2} \mathrm{COOH}\right)\) is 13.2\% ionized. Calculate \(\left[\mathrm{H}^{+}\right],\left[\mathrm{Br} \mathrm{CH}_{2} \mathrm{COO}^{-}\right],\left[\mathrm{BrCH}_{2} \mathrm{COOH}\right]\) and \(K_{a}\) for bromoacetic acid.

By what factor does \(\left[\mathrm{H}^{+}\right]\) change for a \(\mathrm{pH}\) change of (a) 3.0 units, (b) 0.3 units?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.