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Carbon dioxide in the atmosphere dissolves in raindrops to produce carbonic acid \(\left(\mathrm{H}_{2} \mathrm{CO}_{3}\right),\) causing the \(\mathrm{pH}\) of clean, unpolluted rain to range from about 5.2 to \(5.6 .\) What are the ranges of \(\left[\mathrm{H}^{+}\right]\) and \(\left[\mathrm{OH}^{-}\right]\) in the raindrops?

Short Answer

Expert verified
The range for \\[ [H^+] \\] is \([2.51 \times 10^{-6}, 6.31 \times 10^{-6}] \text{ M}\) and for \\[ [OH^-] \\], it is \([1.58 \times 10^{-9}, 3.98 \times 10^{-9}] \text{ M}\).

Step by step solution

01

Understand the pH Scale

The pH scale measures how acidic or basic a solution is, ranging from 0 to 14. A pH of 7 is neutral, less than 7 is acidic, and greater than 7 is basic. The formula to find \([H^+]\) concentration is \([H^+] = 10^{-pH}\).
02

Calculate [H鈦篯 for pH 5.2

Using the formula \[ [H^+] = 10^{-pH} \], substitute pH = 5.2: \[ [H^+] = 10^{-5.2} \]. Calculating this, \[ [H^+] \approx 6.31 \times 10^{-6} \text{ M} \].
03

Calculate [H鈦篯 for pH 5.6

Similarly, for pH = 5.6, substitute in the formula: \[ [H^+] = 10^{-5.6} \]. Calculating this, \[ [H^+] \approx 2.51 \times 10^{-6} \text{ M} \].
04

Determine [H鈦篯 Range

The \[ [H^+] \] range for the pH values from 5.2 to 5.6 is approximately \([2.51 \times 10^{-6}, 6.31 \times 10^{-6}] \text{ M}\).
05

Calculate [OH鈦籡 using the Ion Product of Water

The ion product of water, \[ Kw = [H^+][OH^-] = 1.0 \times 10^{-14} \], is used to find \[ [OH^-] \]. Rearranging gives \[ [OH^-] = \frac{Kw}{[H^+]} \].
06

Calculate [OH鈦籡 for pH 5.2

Using \[ [H^+] \approx 6.31 \times 10^{-6} \text{ M} \], \[ [OH^-] = \frac{1.0 \times 10^{-14}}{6.31 \times 10^{-6}} \approx 1.58 \times 10^{-9} \text{ M} \].
07

Calculate [OH鈦籡 for pH 5.6

For \[ [H^+] \approx 2.51 \times 10^{-6} \text{ M} \], \[ [OH^-] = \frac{1.0 \times 10^{-14}}{2.51 \times 10^{-6}} \approx 3.98 \times 10^{-9} \text{ M} \].
08

Determine [OH鈦籡 Range

The \[ [OH^-] \] range for the pH values from 5.2 to 5.6 is approximately \([1.58 \times 10^{-9}, 3.98 \times 10^{-9}] \text{ M}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

pH Scale
The pH scale is a tool used to measure the acidity or basicity of a solution. It ranges from 0 to 14, where 7 is considered neutral. Solutions with a pH less than 7 are acidic, while those with a pH greater than 7 are basic (alkaline). The scale is logarithmic, which means each whole number step represents a tenfold difference in acidity.
  • Zero to 6: Acidic solutions; the lower the number, the more acidic.
  • Seven: Neutral, like pure water.
  • Eight to 14: Basic solutions; the higher the number, the more basic.
Understanding the pH scale is essential because it helps us determine how solutions will behave in various chemical reactions and everyday situations. For instance, in the given exercise, rainwater has a pH that typically ranges between 5.2 and 5.6, indicating it is slightly acidic due to dissolved carbon dioxide forming carbonic acid. This is a common condition for unpolluted rainwater.
Hydrogen Ion Concentration
The concentration of hydrogen ions (02H^+02) in a solution is directly tied to its pH value. By knowing the pH, the 02H^+02 concentration can be calculated using the formula \([H^+] = 10^{-pH}\). This relationship shows that as pH decreases, the hydrogen ion concentration increases, making the solution more acidic.
Let's explore how we calculate this for the exercise:
  • For a pH of 5.2: \([H^+] = 10^{-5.2} \approx 6.31 \times 10^{-6}\text{ M}\).
  • For a pH of 5.6: \([H^+] = 10^{-5.6} \approx 2.51 \times 10^{-6}\text{ M}\).
Therefore, the hydrogen ion concentration ranges from about \([2.51 \times 10^{-6}, 6.31 \times 10^{-6}]\text{ M}\) for the given pH values. This decrease in 02H^+02 concentration from pH 5.2 to 5.6 reflects a decrease in acidity as the pH moves closer to neutral.
Ion Product of Water
The ion product of water, symbolized as 02K_w02, is a crucial constant in chemistry. It is defined as the product of the concentrations of hydrogen ions (02H^+02) and hydroxide ions (02OH^鈭02) in water. Mathematically, this is expressed as \([K_w = [H^+][OH^-] = 1.0 \times 10^{-14}]\). This product remains constant at a given temperature (usually 25掳C).
How does this work in practice?
  • If you know 02H^+02 concentration, you can find 02OH^鈭02 by rearranging the formula: \([OH^-] =\frac{K_w}{[H^+]}\).
Applying this to the initial problem:
  • For pH 5.2 with \([H^+] \approx 6.31 \times 10^{-6}\text{ M}\): \([OH^-] \approx \frac{1.0 \times 10^{-14}}{6.31 \times 10^{-6}} \approx 1.58 \times 10^{-9}\text{ M}\).
  • For pH 5.6 with \([H^+] \approx 2.51 \times 10^{-6}\text{ M}\): \([OH^-] \approx \frac{1.0 \times 10^{-14}}{2.51 \times 10^{-6}} \approx 3.98 \times 10^{-9}\text{ M}\).
Thus, the 02OH^鈭02 concentration ranges from \([1.58 \times 10^{-9}, 3.98 \times 10^{-9}]\text{ M}\), showcasing how even slight changes in 02H^+02 concentration and pH can affect the balance of ions in water.

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Most popular questions from this chapter

Calculate the concentration of an aqueous solution of \(\mathrm{NaOH}\) that has a pH of \(12.70 .\)

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