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Indicate the principal type of solute-solvent interaction in each of the following solutions and rank the solutions from weakest to strongest solute- solvent interaction: (a) KCl in water, (b) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\) in benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\), (c) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) in water.

Short Answer

Expert verified
The interactions ranked from weakest to strongest are: (b) CH鈧侰l鈧 in benzene, (c) methanol in water, (a) KCl in water.

Step by step solution

01

Identify Solute-Solvent Interactions in KCl in Water

In KCl dissolved in water, the principal interaction is ion-dipole. Potassium cations (K鈦) and chloride anions (Cl鈦) interact with the partial charges of water molecules, where water acts as a polar solvent.
02

Identify Solute-Solvent Interactions in CH2Cl2 in Benzene

In the solution of dichloromethane ( CH鈧侰l鈧) in benzene (C鈧咹鈧), the primary interaction is dispersion forces (London dispersion forces). Both molecules are non-polar, and thus, they primarily interact via induced dipole interactions.
03

Identify Solute-Solvent Interactions in Methanol in Water

The interaction between methanol ( CH鈧僌H) and water is primarily hydrogen bonding. Methanol, a polar molecule, can form hydrogen bonds with water through its hydroxyl (-OH) group.
04

Rank the Interactions from Weakest to Strongest

Based on the interactions: Dispersion forces (weakest) < Hydrogen bonding < Ion-dipole (strongest). Thus, Dichloromethane in benzene is the weakest, methanol in water is intermediate, and KCl in water is the strongest interaction.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ion-Dipole Interactions
In chemistry, ion-dipole interactions are a captivating aspect of solute-solvent interactions. These interactions occur when an ionic compound is dissolved in a polar solvent. Imagine you have a salt like potassium chloride (KCl) being poured into water. What happens? The potassium ions (K鈦) and chloride ions (Cl鈦) separate and become surrounded by water molecules.
This happens because water molecules are polar, with a positive and a negative end. The positive ends of the water molecules are attracted to the negatively charged chloride ions, while the negative ends are attracted to the positively charged potassium ions. This results in a strong ion-dipole interaction.
  • Effectiveness of Ion-Dipole: Ion-dipole forces are very strong due to the full charges present on ions, making them crucial in solubility.
  • In Context: In KCl in water, the ion-dipole interactions are the strongest among the examples given.
Understanding ion-dipole interactions is essential when studying the solubility of ionic compounds in polar solvents.
Dispersion Forces
Dispersion forces, often referred to as London dispersion forces, are a type of van der Waals force and are considered the weakest form of intermolecular interaction. However, they are present in all molecules, whether they are polar or nonpolar. When you have a solution like dichloromethane (CH鈧侰l鈧) in benzene (C鈧咹鈧), dispersion forces come into play. Both these molecules are non-polar, which means they do not have areas of positive and negative charge.
So how do they interact? Dispersion forces arise when the electrons within a molecule temporarily become unevenly distributed, creating a temporary dipole moment. This can induce a corresponding temporary dipole in a neighboring molecule, leading to a weak attraction between the two.
  • Characteristics of Dispersion Forces: These forces increase with larger molecules due to the larger electron cloud.
  • In Context: In the example of CH鈧侰l鈧 in benzene, dispersion forces are the weakest solute-solvent interactions occurring.
Despite their weakness, dispersion forces play a significant role, especially in solvents that lack stronger polar or ionic interactions.
Hydrogen Bonding
Hydrogen bonding is a special type of dipole-dipole interaction where a hydrogen atom is bonded to a highly electronegative atom such as oxygen, nitrogen, or fluorine. This bond results in significant polar characteristics and a particularly strong type of interaction. Think about methanol (CH鈧僌H) sharing a glass with water. Here, hydrogen bonding is at play.
Methanol contains an -OH group, allowing it to form hydrogen bonds with water. This clustering of molecules can lead to significantly strong interactions that influence the properties of the solution.
  • Traits of Hydrogen Bonds: They are stronger than dispersion forces but generally weaker than ion-dipole interactions, making them effective in binding molecules tightly, leading to higher boiling points and solubilities.
  • In Context: In a mixture of methanol and water, hydrogen bonding accounts for intermediate strength interactions when compared to the other interactions mentioned.
Deepening your understanding of hydrogen bonding can enrich your comprehension of why certain substances mix so well, and how they behave in solution.

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Most popular questions from this chapter

A supersaturated solution of sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) is made by dissolving sucrose in hot water and slowly letting the solution cool to room temperature. After a long time, the excess sucrose crystallizes out of the solution. Indicate whether each of the following statements is true or false: (a) After the excess sucrose has crystallized out, the remaining solution is saturated. (b) After the excess sucrose has crystallized out, the system is now unstable and is not in equilibrium. (c) After the excess sucrose has crystallized out, the rate of sucrose molecules leaving the surface of the crystals to be hydrated by water is equal to the rate of sucrose molecules in water attaching to the surface of the crystals.

(a) A sample of hydrogen gas is generated in a closed container by reacting \(1.750 \mathrm{~g}\) of zinc metal with \(50.0 \mathrm{~mL}\) of \(1.00 \mathrm{M}\) hydrochloric acid. Write the balanced equation for the reaction, and calculate the number of moles of hydrogen formed, assuming that the reaction is complete. (b) The volume over the solution in the container is 150 \(\mathrm{mL}\). Calculate the partial pressure of the hydrogen gas in this volume at \(25^{\circ} \mathrm{C}\), ignoring any solubility of the gas in the solution. (c) The Henry's law constant for hydrogen in water at \(25^{\circ} \mathrm{C}\) is \(7.7 \times 10^{-6} \mathrm{~mol} / \mathrm{m}^{3}-\mathrm{Pa}\). Estimate the number of moles of hydrogen gas that remain dissolved in the solution. What fraction of the gas molecules in the system is dissolved in the solution? Was it reasonable to ignore any dissolved hydrogen in part (b)?

You take a sample of water that is at room temperature and in contact with air and put it under a vacuum. Right away, you see bubbles leave the water, but after a little while, the bubbles stop. As you keep applying the vacuum, more bubbles appear. A friend tells you that the first bubbles were water vapor, and the low pressure had reduced the boiling point of water, causing the water to boil. Another friend tells you that the first bubbles were gas molecules from the air (oxygen, nitrogen, and so forth) that were dissolved in the water. Which friend is mostly likely to be correct? What, then, is responsible for the second batch of bubbles?

The following table presents the solubilities of several gases in water at \(25^{\circ} \mathrm{C}\) under a total pressure of gas and water vapor of \(101.3 \mathrm{kPa}\). (a) What volume of \(\mathrm{CH}_{4}(g)\) under standard conditions of temperature and pressure is contained in \(4.0 \mathrm{~L}\) of a saturated solution at \(25^{\circ} \mathrm{C} ?\) (b) The solubilities (in water) of the hydrocarbons are as follows: methane \(<\) ethane \(<\) ethylene. Is this because ethylene is the most polar molecule? (c) What intermolecular interactions can these hydrocarbons have with water? (d) Draw the Lewis dot structures for the three hydrocarbons. Which of these hydrocarbons possess \(\pi\) bonds? Based on their solubilities, would you say \(\pi\) bonds are more or less polarizable than \(\sigma\) bonds? (e) Explain why \(\mathrm{NO}\) is more soluble in water than either \(\mathrm{N}_{2}\) or \(\mathrm{O}_{2}\). (f) \(\mathrm{H}_{2} \mathrm{~S}\) is more water-soluble than almost all the other gases in table. What intermolecular forces is \(\mathrm{H}_{2} \mathrm{~S}\) likely to have with water? \((\mathbf{g}) \mathrm{SO}_{2}\) is by far the most water-soluble gas in table. What intermolecular forces is \(\mathrm{SO}_{2}\) likely to have with water? $$ \begin{array}{lc} \hline \text { Gas } & \text { Solubility (mM) } \\ \hline \mathrm{CH}_{4} \text { (methane) } & 1.3 \\ \mathrm{C}_{2} \mathrm{H}_{6} \text { (ethane) } & 1.8 \\ \mathrm{C}_{2} \mathrm{H}_{4} \text { (ethylene) } & 4.7 \\ \mathrm{~N}_{2} & 0.6 \\ \mathrm{O}_{2} & 1.2 \\ \mathrm{NO} & 1.9 \\ \mathrm{H}_{2} \mathrm{~S} & 99 \\ \mathrm{SO}_{2} & 1476 \\ \hline \end{array} $$

The presence of the radioactive gas radon (Rn) in well water presents a possible health hazard in parts of the United States. (a) Assuming that the solubility of radon in water with \(15.2 \mathrm{kPa}\) pressure of the gas over the water at \(30^{\circ} \mathrm{C}\) is \(0.109 \mathrm{M}\), what is the Henry's law constant for radon in water at this temperature? (b) A sample consisting of various gases contains 4.5 -ppm radon (mole fraction). This gas at a total pressure of \(5.07 \mathrm{MPa}\) is shaken with water at \(30^{\circ} \mathrm{C} .\) Calculate the molar concentration of radon in the water.

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