Chapter 9: Problem 14
(a) How does one determine the number of electron domains in a molecule or ion? (b) What is the difference between a bonding electron domain and a nonbonding electron domain?
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Chapter 9: Problem 14
(a) How does one determine the number of electron domains in a molecule or ion? (b) What is the difference between a bonding electron domain and a nonbonding electron domain?
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What are the electron-domain and molecular geometries of a molecule that has the following electron domains on its central atom? (a) three bonding domains and no nonbonding domains, (b) three bonding domains and one nonbonding domain, (c) two bonding domains and two nonbonding domains.
(a) Write a single Lewis structure for \(\mathrm{SO}_{3}\), and determine the hybridization at the \(\mathrm{S}\) atom. (b) Are there other equivalent Lewis structures for the molecule? (c) Would you expect \(\mathrm{SO}_{3}\) to exhibit delocalized \(\pi\) bonding? Explain.
Sulfur tetrafluoride (SF \(_{4}\) ) reacts slowly with \(\mathrm{O}_{2}\) to form sulfur tetrafluoride monoxide \(\left(\mathrm{OSF}_{4}\right)\) according to the following unbalanced reaction: $$ \mathrm{SF}_{4}(g)+\mathrm{O}_{2}(g) \longrightarrow \operatorname{OSF}_{4}(g) $$ The \(\mathrm{O}\) atom and the four \(\mathrm{F}\) atoms in \(\mathrm{OSF}_{4}\) are bonded to a central \(S\) atom. (a) Balance the equation. (b) Write a Lewis structure of \(\mathrm{OSF}_{4}\) in which the formal charges of all atoms are zero. (c) Use average bond enthalpies (Table 8.4) to estimate the enthalpy of the reaction. Is it endothermic or exothermic? (d) Determine the electrondomain geometry of \(\mathrm{OSF}_{4}\), and write two possible molecular geometries for the molecule based on this electron-domain geometry. (e) Which of the molecular geometries in part (d) is more likely to be observed for the molecule? Explain.
A compound composed of \(2.1 \% \mathrm{H}, 29.8 \% \mathrm{~N}\), and \(68.1 \% \mathrm{O}\) has a molar mass of approximately \(50 \mathrm{~g} / \mathrm{mol}\). (a) What is the molecular formula of the compound? (b) What is its Lewis structure if \(\mathrm{H}\) is bonded to \(\mathrm{O}\) ? (c) What is the geometry of the molecule? (d) What is the hybridization of the orbitals around the \(\mathrm{N}\) atom? (e) How many \(\sigma\) and how many \(\pi\) bonds are there in the molecule?
The three species \(\mathrm{NH}_{2}^{-} \mathrm{NH}_{3}\), and \(\mathrm{NH}_{4}{ }^{+}\) have \(\mathrm{H}-\mathrm{N}-\mathrm{H}\) bond angles of \(105^{\circ}, 107^{\circ}\), and \(109^{\circ}\), respec- tively. Explain this variation in bond angles.
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