Chapter 8: Problem 73
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
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Chapter 8: Problem 73
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
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Draw Lewis structures for the following: (a) \(\mathrm{SiH}_{4}\), (b) \(\mathrm{CO}\), (c) \(\mathrm{SF}_{2}\), (d) \(\mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{H}\) is bonded to \(\mathrm{O})\), (e) \(\mathrm{ClO}_{2}^{-}\) (f) \(\mathrm{NH}_{2} \mathrm{OH}\).
You and a partner are asked to complete a lab entitled "Oxides of Ruthenium" that is scheduled to extend over two lab periods. The first lab, which is to be completed by your partner, is devoted to carrying out compositional analysis. In the second lab, you are to determine melting points. Upon going to lab you find two unlabeled vials, one containing a soft yellow substance and the other a black powder. You also find the following notes in your partner's notebook-Compound 1: \(76.0 \%\) Ru and \(24.0 \%\) O (by mass), Compound 2: \(61.2 \%\) Ru and \(38.8 \% \mathrm{O}\) (by mass). (a) What is the empirical formula for Compound \(1 ?\) (b) What is the empirical formula for Compound 2? (c) Upon determining the melting points of these two compounds, you find that the yellow compound melts at \(25^{\circ} \mathrm{C}\), while the black powder does not melt up to the maximum temperature of your apparatus, \(1200^{\circ} \mathrm{C}\). What is the identity of the yellow compound? What is the identity of the black compound? Be sure to use the appropriate naming convention depending upon whether the compound is better described as a molecular or ionic compound.
Draw the Lewis structures for each of the following ions or molecules. Identify those that do not obey the octet rule, and explain why they do not. (a) \(\mathrm{SO}_{3}{ }^{2-}\), (b) \(\mathrm{AlH}_{3}\), (c) \(\mathrm{N}_{3}^{-}\), (d) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\), (e) \(\mathrm{SbF}_{5}\).
(a) State the octet rule. (b) Does the octet rule apply to ionic as well as to covalent compounds? Explain, using examples as appropriate.
The iodine monobromide molecule, IBr, has a bond length of \(2.49 \AA\) and a dipole moment of \(1.21 \mathrm{D}\). (a) Which atom of the molecule is expected to have a negative charge? Explain. (b) Calculate the effective charges on the I and Br atoms in IBr, in units of the electronic charge \(e\).
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