Chapter 3: Problem 55
Why is it essential to use balanced chemical equations when determining the quantity of a product formed from a given quantity of a reactant?
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Chapter 3: Problem 55
Why is it essential to use balanced chemical equations when determining the quantity of a product formed from a given quantity of a reactant?
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The koala dines exclusively on eucalyptus leaves. Its digestive system detoxifies the eucalyptus oil, a poison to other animals. The chief constituent in eucalyptus oil is a substance called eucalyptol, which contains \(77.87 \% \mathrm{C}\), \(11.76 \% \mathrm{H}\), and the remainder \(\mathrm{O}\). (a) What is the empirical formula for this substance? (b) A mass spectrum of eucalyptol shows a peak at about 154 amu. What is the molecular formula of the substance?
Balance the following equations: (a) \(\mathrm{Li}(s)+\mathrm{N}_{2}(g) \longrightarrow \mathrm{Li}_{3} \mathrm{~N}(s)\) (b) \(\mathrm{La}_{2} \mathrm{O}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{La}(\mathrm{OH})_{3}(a q)\) (c) \(\mathrm{NH}_{4} \mathrm{NO}_{3}(s) \longrightarrow \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) (d) \(\mathrm{Ca}_{3} \mathrm{P}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{PH}_{3}(g)\) (e) \(\mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{H}_{3} \mathrm{PO}_{4}(a q) \longrightarrow\) \(\mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l)\) (f) \(\mathrm{AgNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{SO}_{4}(a q) \longrightarrow\) \(\mathrm{Ag}_{2} \mathrm{SO}_{4}(\mathrm{~s})+\mathrm{NaNO}_{3}(a q)\) (g) \(\mathrm{CH}_{3} \mathrm{NH}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow\) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)+\mathrm{N}_{2}(g)\)
The molecular formula of allicin, the compound responsible for the characteristic smell of garlic, is \(\mathrm{C}_{6} \mathrm{H}_{10} \mathrm{OS}_{2}\). (a) What is the molar mass of allicin? (b) How many moles of allicin are present in \(5.00 \mathrm{mg}\) of this substance? (c) How many molecules of allicin are in \(5.00 \mathrm{mg}\) of this substance? (d) How many \(\mathrm{S}\) atoms are present in 5.00 mg of allicin?
One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of \(\mathrm{NH}_{3}\) to \(\mathrm{NO}\) : $$ 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) $$ In a certain experiment, \(1.50 \mathrm{~g}\) of \(\mathrm{NH}_{3}\) reacts with \(2.75 \mathrm{~g}\) of \(\mathrm{O}_{2}\) (a) Which is the limiting reactant? (b) How many grams of \(\mathrm{NO}\) and of \(\mathrm{H}_{2} \mathrm{O}\) form? (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed? (d) Show that your calculations in parts (b) and (c) are consistent with the law of conservation of mass.
Calculate the following quantities: (a) mass, in grams, of \(0.105\) moles sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) (b) moles of \(\mathrm{Zn}\left(\mathrm{NO}_{3}\right)_{2}\) in \(143.50 \mathrm{~g}\) of this substance (c) number of molecules in \(1.0 \times 10^{-6} \mathrm{~mol} \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) (d) number of \(\mathrm{N}\) atoms in \(0.410 \mathrm{~mol} \mathrm{NH}_{3}\)
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