Chapter 25: Problem 29
What is the octane number of a mixture of \(35 \%\) heptane and \(65 \%\) isooctane?
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Chapter 25: Problem 29
What is the octane number of a mixture of \(35 \%\) heptane and \(65 \%\) isooctane?
These are the key concepts you need to understand to accurately answer the question.
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An unknown organic compound is found on elemental analysis to contain \(68.1 \%\) carbon, \(13.7 \%\) hydrogen, and \(18.2 \%\) oxygen by mass. It is slightly soluble in water. Upon careful oxidation it is converted into a compound that behaves chemically like a ketone and contains \(69.7 \%\) carbon, \(11.7 \%\) hydrogen, and \(18.6 \%\) oxygen by mass. Indicate two or more reasonable structures for the unknown.
Write the condensed structural formula for each of the following compounds: (a) 2 -pentanol, (b) 1,2 propanediol, (c) ethyl acetate, (d) diphenyl ketone, (e) methyl ethyl ether.
Write a balanced chemical equation using condensed structural formulas for (a) the formation of butyl propionate from the appropriate acid and alcohol, (b) the saponification (base hydrolysis) of methyl benzoate.
One of the most important molecules in biochemical systems is adenosine triphosphate (ATP), for which the structure is ATP is the principal carrier of biochemical energy. It is considered an energy-rich compound because the hydrolysis of ATP to yield adenosine diphosphate (ADP) and inorganic phosphate is spontaneous underaqueous biochemical conditions. (a) Write a balanced equation for the reaction of ATP with water to yield ADP and inorganic phosphate ion. [Hint: Hydrolysis reactions are just the reverse of condensation reactions(Section 22.8).] (b) What would you expect for the sign of the free-energy change for this reaction? (c) ADP can undergo further hydrolysis. What would you expect for the product of that reaction?
Give the molecular formula of a cyclic alkane, a cyclic alkene, a linear alkyne, and an aromatic hydrocarbon that in each case contains six carbon atoms. Which are saturated and which are unsaturated hydrocarbons?
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