Chapter 25: Problem 16
Give the general formula for any cyclic alkene, that is, a cyclic hydrocarbon with one double bond.
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Chapter 25: Problem 16
Give the general formula for any cyclic alkene, that is, a cyclic hydrocarbon with one double bond.
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How many structural isomers are there for a fivemember straight carbon chain with one double bond? For a six-member straight carbon chain with two double bonds?
Explain why the boiling point of ethanol \(\left(78^{\circ} \mathrm{C}\right)\) is much higher than that of its isomer, dimethyl ether \(\left(-25^{\circ} \mathrm{C}\right)\) and why the boiling point of \(\mathrm{CH}_{2} \mathrm{~F}_{2}\left(-52{ }^{\circ} \mathrm{C}\right)\) is far above that of \(\mathrm{CH}_{4}\left(-128^{\circ} \mathrm{C}\right)\).
Draw the structure for 2-bromo-2-chloro-3-methylpentane, and indicate any chiral carbons in the molecule.
Starch, glycogen, and cellulose are all polymers of glucose. What are the structural differences among them?
(a) Describe the primary, secondary, and tertiary structures of proteins. (b) Quaternary structures of proteins arise if two or more smaller polypeptides or proteins associate with each other to make an overall much larger protein structure. The association is due to the same hydrogen bonding, electrostatic, and dispersion forces we have seen before. Hemoglobin, the protein used to transport oxygen molecules in our blood, is an example of a protein that has quaternary structure. Hemoglobin is a tetramer; it is made of four smaller polypeptides, two "alphas" and two "betas." (These names do not imply anything about the number of alpha helices or beta sheets in the individual polypeptides.) What kind of experiments would provide sound evidence that hemoglobin exists as a tetramer and not as one enormous polypeptide chain? You may need to look into the chemical literature to discover techniques that chemists and biochemists use to make these decisions.
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