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Which would you expect to be the more ductile element, (a) Ag or Mo, (b) Zn or Si? In each case explain your reasoning.

Short Answer

Expert verified
(a) Ag is the more ductile element due to its weaker metallic bonds and more open crystal structure. (b) Zn is the more ductile element due to its metallic properties, more open crystal structure, and weaker metallic bonds compared to Si (Silicon).

Step by step solution

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(a) Pair 1: Ag and Mo

Ag (Silver) is a precious metal found in group 11 of the periodic table. It is known for its excellent electrical conductivity and its malleability. Mo (Molybdenum) is a transition metal in group 6 and is a strong, ductile metal with a high melting point. Comparing the two elements, silver has a more open crystal structure with weaker metallic bonds due to its more significant atomic radius and lower electronegativity, allowing its atoms to slide over each other more easily than molybdenum atoms. Therefore, we can conclude that Ag is more ductile than Mo.
02

(b) Pair 2: Zn and Si

Zn (Zinc) is a transition metal located in group 12 of the periodic table. It has metallic properties and is considered to be moderately ductile. Si (Silicon), on the other hand, is a metalloid found in group 14. It is a semiconductor with a strong covalent bond structure in a diamond lattice, which makes it relatively brittle and less ductile than metals. Comparing the two elements, zinc possesses better metallic characteristics and a more open crystal structure than silicon. Its metallic bonds are weaker, which makes it easier for the atoms to slide past each other, resulting in higher ductility. Consequently, we can conclude that Zn is more ductile than Si. In summary:
03

Answer (a) Ag or Mo:

Ag (Silver) is the more ductile element due to its weaker metallic bonds and more open crystal structure.
04

Answer (b) Zn or Si:

Zn (Zinc) is the more ductile element due to its metallic properties, more open crystal structure, and weaker metallic bonds compared to Si (Silicon).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Crystal Structure
The arrangement of atoms within a metal greatly influences its ductility. In metals like silver (Ag) and zinc (Zn), the crystal structure is more open. This openness allows the atoms to slide over each other more easily when force is applied. This sliding, facilitated by an open crystal structure, contributes to the metal's ductility.

In contrast, materials like molybdenum (Mo) and silicon (Si) have denser and more complex crystal arrangements. Mo, though a metal, has strong bonds within its structure due to its transition metal characteristics. Si, a metalloid, adopts a diamond-like structure that is rigid. Such structures don't allow for easy movement of atoms, making these materials less ductile.
Metallic Bonds
Metallic bonds play a pivotal role in the ductility of an element. They consist of a lattice of positive ions embedded in a "sea" of delocalized electrons. This type of bonding is generally weaker than covalent or ionic bonds, granting metals like Ag and Zn a degree of flexibility.
  • These electrons allow metals to bend and stretch without breaking.
  • The weaker the metallic bonds, the more ductile the metal, as atoms can shift position more easily.
Mo has relatively strong metallic bonds compared to Ag, due to its small atomic radius and higher electronegativity, making it tougher and less ductile. Conversely, Si relies on covalent bonding, which is stronger and more rigid, resulting in brittleness instead of ductility.
Periodic Table
The periodic table provides valuable insights into the properties of elements, including ductility. Metals located in groups with lower atomic numbers and higher periods, like Ag and Zn, tend to be more ductile. This is because these metals have more electrons in their outer shell but larger atomic radii, allowing for easier movement of atoms.

Ag can be found in group 11, where elements are known for good conductivity and malleability, while Zn, in group 12, shares similar traits albeit to a lesser extent. Mo, located in group 6, features properties that cater to its role as a strong and heat-resistant metal, but not as ductile as Ag. Si sits in group 14 as a metalloid, with its semiconducting properties and rigid network structure, reducing its ductility significantly.
Metals vs Metalloids
Metals and metalloids differ in their fundamental properties, which influences their ductility. Metals like Ag and Zn exhibit characteristics such as high electrical conductivity, malleability, and ductility. These properties are a result of their metallic bonding and open crystal structures.
  • Metals can stretch into wires (ductility) and are often shiny (lustrous).
  • They tend to conduct heat and electricity well, thanks to free-moving electrons.
Metalloids, such as Si, straddle the divide between metals and non-metals. They typically possess a combination of properties but lean more towards the rigidity of non-metals.

Silicon, while useful as a semiconductor, doesn't exhibit ductility. Its covalent bonding and diamond-like structure prevent the degree of atomic mobility seen in metals, making it much less malleable and therefore more brittle.

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Most popular questions from this chapter

Two of the most heavily utilized metals are aluminum and iron. What are the most important natural sources of these elements? In what oxidation state is each metal found in nature?

On the atomic level, what distinguishes a paramagnetic material from a diamagnetic one? How does each behave in a magnetic field?

The heats of atomization, \(\Delta H_{\text {atom }}\), in \(\mathrm{kJ} / \mathrm{mol}\), of the first transition series of elements are as follows: \(\begin{array}{lllllllllll} \text { Element } & \text { Ca } & \text { Sc } & \text { Ti } & \text { V } & \text { Cr } & \text { Mn } & \text { Fe } & \text { Co } & \text { Ni } & \text { Cu } \\ \hline \Delta H_{\text {atom }} & 178 & 378 & 471 & 515 & 397 & 281 & 415 & 426 & 431 & 338 \end{array}\) (a) Write an equation for the process involved in atomization, and describe the electronic and structural changes that occur. (b) \(\Delta H_{\text {atom }}\) varies irregularly in the series following \(\mathrm{V}\). How can this be accounted for, at least in part, using the electronic configurations of the gaseous atoms? (Hint: Recall the discussions of Sections \(6.8\) and \(6.9 .)\)

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