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Hydrogen peroxide is capable of oxidizing (a) hydrazine to \(\mathrm{N}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\), (b) \(\mathrm{SO}_{2}\) to \(\mathrm{SO}_{4}^{2-}\), (c) \(\mathrm{NO}_{2}^{-}\) to \(\mathrm{NO}_{3}^{-}\), (d) \(\mathrm{H}_{2} \mathrm{~S}(g)\) to \(\mathrm{S}(\mathrm{s})\) (e) \(\mathrm{Fe}^{2+}\) to \(\mathrm{Fe}^{3+} .\) Write a balanced net ionic equation for each of these redox reactions.

Short Answer

Expert verified
The balanced net ionic equations for the given redox reactions are: (a) \(N2H4 + H2O2 \to N2 + 2H2O\) (b) \(2H2O2 + SO2 \to 2H2O + SO4^{2-} + 4H^+\) (c) \(2NO2^- + H2O2 \to 2NO3^- + 2H2O\) (d) \(H2O2 + H2S \to O2 + 2H2O + S\) (e) \(2Fe^{2+} + H2O2 \to 2Fe^{3+} + O2 + 2H^+\)

Step by step solution

01

(a) Oxidizing Hydrazine to N鈧 and H鈧侽

1. Identify the oxidation and reduction half-reactions: Oxidation: H鈧侽鈧 is reduced to H鈧侽, as its oxygen (O) atom gains two electrons. Reduction: Hydrazine (N鈧侶鈧) is oxidized to N鈧, as its nitrogen (N) atom loses one electron. 2. Write the half-reactions: Oxidation: \(N2H4 \to N2 + 4H^+\) Reduction: \(H2O2 + 2H^+ \to 2H2O\) 3. Balance the half-reactions and combine: The half-reactions are already balanced for mass and charge. Combining them, we get: \(N2H4 + H2O2 \to N2 + 2H2O\)
02

(b) Oxidizing SO鈧 to SO鈧劼测伝

1. Identify the oxidation and reduction half-reactions: Oxidation: H鈧侽鈧 is reduced to O鈧, as its oxygen (O) atom gains two electrons. Reduction: SO鈧 is oxidized to SO鈧劼测伝, as its sulfur (S) atom loses two electrons. 2. Write the half-reactions: Oxidation: \(2H2O2 \to O2 + 2H2O\) Reduction: \(SO2 + 2H2O \to SO4^{2-} + 4H^+\) 3. Balance the half-reactions and combine: The half-reactions are already balanced for mass and charge. Combining them, we get: \(2H2O2 + SO2 \to 2H2O + SO4^{2-} + 4H^+\)
03

(c) Oxidizing NO鈧傗伝 to NO鈧冣伝

1. Identify the oxidation and reduction half-reactions: Oxidation: H鈧侽鈧 is reduced to H鈧侽, as its oxygen (O) atom gains two electrons. Reduction: NO鈧傗伝 is oxidized to NO鈧冣伝, as its nitrogen (N) atom loses one electron. 2. Write the half-reactions: Oxidation: \(H2O2 + 2H^+ \to 2H2O\) Reduction: \(2NO2^- + H2O \to 2NO3^- + 2H^+\) 3. Balance the half-reactions and combine: The half-reactions are already balanced for mass and charge. Combining them, we get: \(2NO2^- + H2O2 \to 2NO3^- + 2H2O\)
04

(d) Oxidizing H鈧係 to S

1. Identify the oxidation and reduction half-reactions: Oxidation: H鈧侽鈧 is reduced to H鈧侽, as its oxygen (O) atom gains two electrons. Reduction: H鈧係 is oxidized to S, as its sulfur (S) atom loses two electrons. 2. Write the half-reactions: Oxidation: \(H2O2 \to O2 + 2H^+ + 2e^-\) Reduction: \(H2S + 2e^- \to S + 2H^+\) 3. Balance the half-reactions and combine: The half-reactions are already balanced for mass and charge. Combining them, we get: \(H2O2 + H2S \to O2 + 2H2O + S\)
05

(e) Oxidizing Fe虏鈦 to Fe鲁鈦

1. Identify the oxidation and reduction half-reactions: Oxidation: H鈧侽鈧 is reduced to O鈧, as its oxygen (O) atom gains two electrons. Reduction: Fe虏鈦 is oxidized to Fe鲁鈦, as its iron (Fe) atom loses one electron. 2. Write the half-reactions: Oxidation: \(H2O2 \to O2 + 2H^+ + 2e^-\) Reduction: \(2Fe^{2+} + 2e^- \to 2Fe^{3+}\) 3. Balance the half-reactions and combine: The half-reactions are already balanced for mass and charge. Combining them, we get: \(2Fe^{2+} + H2O2 \to 2Fe^{3+} + O2 + 2H^+\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation-Reduction
Redox reactions, short for reduction-oxidation reactions, are chemical processes where electrons are transferred between two substances. These reactions are central to energy production in biological systems and many industrial processes.
Oxidation refers to the loss of electrons. In the context of the given exercise, hydrazine (\( \mathrm{N}_{2}\)) in part (a) loses electrons and transforms into nitrogen gas (\( \mathrm{N}_{2}\)). On the other hand, reduction is the gain of electrons. In this reaction, hydrogen peroxide (H鈧侽鈧) gains electrons and reduces to water (\( \mathrm{H}_{2}\mathrm{O}\)).
To identify a redox reaction, look for changes in oxidation states of elements between reactants and products. The substance that loses electrons is being oxidized, while the one gaining electrons is being reduced. This electron exchange is key in these intricate chemical transformations.
Balanced Chemical Equations
Balanced chemical equations are essential to accurately describe chemical reactions. In the context of redox reactions, balancing not only involves ensuring that the number of atoms for each element is the same on both sides of the equation, but also ensuring the electric charges are balanced.
For instance, in step 1 of the exercise, the reaction involves the oxidation of hydrazine and the reduction of hydrogen peroxide. The overall chemical equation:
  • \( \mathrm{N}_{2}\mathrm{H}_{4} + \mathrm{H}_{2}\mathrm{O}_{2} \to \mathrm{N}_{2} + 2\mathrm{H_2O} \)
is already balanced for atoms and charge. This involves checking that both sides have the same number of each type of atom, as well as equivalent total charge. Balancing chemical equations makes it possible for chemists to predict the correct quantity of reactants and products involved in the reaction.
Half-Reactions
Half-reactions simplify understanding redox reactions by separating them into two parts: one for oxidation and one for reduction.
Each half-reaction displays either the oxidation or reduction process. In these exercises, half-reactions help isolate and identify which species are gaining or losing electrons.
Take step 5 of the exercise, where iron (\( \mathrm{Fe}^{2+} \)) is oxidized to iron (\( \mathrm{Fe}^{3+} \)). The respective half-reactions are:
  • Oxidation (Fe): \( 2\mathrm{Fe}^{2+} \to 2\mathrm{Fe}^{3+} + 2e^- \)
  • Reduction (H鈧侽鈧): \( \mathrm{H}_{2}\mathrm{O}_{2} \to \mathrm{O}_{2} + 2\mathrm{H}^{+} + 2e^- \)
These half-reactions show the individual electron exchanges occurring. By examining and combining them, we can generate a complete, balanced redox equation. This process enables a clear view of all the interactions and electron movements in the chemical equation.

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Most popular questions from this chapter

Identify each of the following elements as a metal, nonmetal, or metalloid: (a) phosphorus, (b) strontium, (c) manganese, (d) selenium, (e) rhodium, (f) krypton.

The standard heats of formation of \(\mathrm{H}_{2} \mathrm{O}(g), \mathrm{H}_{2} S(g)\), \(\mathrm{H}_{2} \mathrm{Se}(g)\), and \(\mathrm{H}_{2} \mathrm{Te}(g)\) are \(-241.8,-20.17,+29.7\), and \(+99.6 \mathrm{~kJ} / \mathrm{mol}\), respectively. The enthalpies necessary to convert the elements in their standard states to one mole of gaseous atoms are \(248,277,227\), and \(197 \mathrm{~kJ} / \mathrm{mol}\) of atoms for \(\mathrm{O}, \mathrm{S}\), Se, and Te, respectively. The enthalpy for dissociation of \(\mathrm{H}_{2}\) is \(436 \mathrm{~kJ} / \mathrm{mol} .\) Calculate the average \(\mathrm{H}-\mathrm{O}, \mathrm{H}-\mathrm{S}, \mathrm{H}-\mathrm{Se}\), and \(\mathrm{H}-\) Te bond enthalpies, and comment on their trend.

Consider the elements \(\mathrm{O}, \mathrm{Ba}, \mathrm{Co}, \mathrm{Be}, \mathrm{Br}\), and Se. From this list select the element that (a) is most electronegative, (b) exhibits a maximum oxidation state of \(+7\), (c) loses an electron most readily, (d) forms \(\pi\) bonds most readily, (e) is a transition metal.

Carbon forms an unusual, unstable oxide of formula \(\mathrm{C}_{3} \mathrm{O}_{2}\) called carbon suboxide. Carbon suboxide is made by using \(\mathrm{P}_{2} \mathrm{O}_{5}\) to dehydrate the dicarboxylic acid called malonic acid, which has the formula \(\mathrm{HOOC}-\mathrm{CH}_{2}-\mathrm{COOH}\). (a) Write a balanced reaction for the production of carbon suboxide from malonic acid. (b) Suggest a Lewis structure for \(\mathrm{C}_{3} \mathrm{O}_{2}\). (Hint: The Lewis structure of malonic acid suggests which atoms are connected to which.) (c) By using the information in Table \(8.5\), predict the \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{C}-\mathrm{O}\) bond lengths in \(\mathrm{C}_{3} \mathrm{O}_{2}\). (d) Sketch the Lewis structure of a product that could result by the addition of \(2 \mathrm{~mol}\) of \(\mathrm{H}_{2}\) to 1 mol of \(\mathrm{C}_{3} \mathrm{O}_{2}\)

Removal of perchlorate from water supplies is difficult. Naturally occurring microorganisms are, however, capable of destroying perchlorate in solution in minutes. What do you think might be the type of reaction occurring in the microorganisms, and what do you predict might be the fate of the perchlorate ion in the reaction?

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