Chapter 22: Problem 29
Describe two characteristics of hydrogen that are favorable for its use as a general energy source in vehicles.
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Chapter 22: Problem 29
Describe two characteristics of hydrogen that are favorable for its use as a general energy source in vehicles.
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Write the chemical formula for each of the following compounds, and indicate the oxidation state of nitrogen in each: (a) sodium nitrite, (b) ammonia, (c) nitrous oxide, (d) sodium cyanide, (e) nitric acid, (f) nitrogen dioxide.
Carbon forms an unusual, unstable oxide of formula \(\mathrm{C}_{3} \mathrm{O}_{2}\) called carbon suboxide. Carbon suboxide is made by using \(\mathrm{P}_{2} \mathrm{O}_{5}\) to dehydrate the dicarboxylic acid called malonic acid, which has the formula \(\mathrm{HOOC}-\mathrm{CH}_{2}-\mathrm{COOH}\). (a) Write a balanced reaction for the production of carbon suboxide from malonic acid. (b) Suggest a Lewis structure for \(\mathrm{C}_{3} \mathrm{O}_{2}\). (Hint: The Lewis structure of malonic acid suggests which atoms are connected to which.) (c) By using the information in Table \(8.5\), predict the \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{C}-\mathrm{O}\) bond lengths in \(\mathrm{C}_{3} \mathrm{O}_{2}\). (d) Sketch the Lewis structure of a product that could result by the addition of \(2 \mathrm{~mol}\) of \(\mathrm{H}_{2}\) to 1 mol of \(\mathrm{C}_{3} \mathrm{O}_{2}\)
Write a balanced equation for each of the following reactions. (You may have to guess at one or more of the reaction products, but you should be able to make a reasonable guess, based on your study of this chapter.) (a) Hydrogen selenide can be prepared by reaction of an aqueous acid solution on aluminum selenide. (b) Sodium thiosulfate is used to remove excess \(\mathrm{Cl}_{2}\) from chlorine-bleached fabrics. The thiosulfate ion forms \(\mathrm{SO}_{4}^{2-}\) and elemental sulfur, while \(\mathrm{Cl}_{2}\) is reduced to \(\mathrm{Cl}^{-} .\)
Give the chemical formula for (a) hydrocyanic acid, (b) nickel tetracarbonyl, (c) barium bicarbonate, (d) calcium acetylide.
The dissolved oxygen present in any highly pressurized, high-temperature steam boiler can be extremely corrosive to its metal parts. Hydrazine, which is completely miscible with water, can be added to remove oxygen by reacting with it to form nitrogen and water. (a) Write the balanced equation for the reaction between gaseous hydrazine and oxygen. (b) Calculate the enthalpy change accompanying this reaction. (c) Oxygen in air dissolves in water to the extent of \(9.1 \mathrm{ppm}\) at \(20^{\circ} \mathrm{C}\) at sea level. How many grams of hydrazine are required to react with all the oxygen in \(3.0 \times 10^{4} \mathrm{~L}\) (the volume of a small swimming pool) under these conditions?
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