Chapter 20: Problem 78
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid? Explain.
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Chapter 20: Problem 78
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid? Explain.
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The \(K_{\infty}\) value for \(\mathrm{PbS}(s)\) is \(8.0 \times 10^{-28} .\) By using this value together with an electrode potential from Appendix \(\mathrm{E}\), determine the value of the standard reduction potential for the reaction $$ \mathrm{PbS}(s)+2 \mathrm{e}^{-}-\cdots \mathrm{Pb}(s)+\mathrm{S}^{2-}(a q) $$
Complete and balance the following half-reactions. In each case indicate whether the half-reaction is an oxidation or a reduction. (a) \(\mathrm{Sn}^{2+}(a q)-\cdots \mathrm{Sn}^{4+}(a q)\) (acidic or basic solution) (b) \(\mathrm{TiO}_{2}(s)-\cdots \mathrm{Ti}^{2+}(a q)\) (acidic solution) (c) \(\mathrm{ClO}_{3}^{-}(a q)-\cdots \mathrm{Cl}^{-}(a q)\) (acidic solution) (d) \(\mathrm{N}_{2}(g) \longrightarrow \mathrm{NH}_{4}{ }^{+}(a q)\) (acidic solution) (e) \(\mathrm{OH}^{-}(a q) \rightarrow \mathrm{O}_{2}(g)\) (basic solution) (f) \(\mathrm{SO}_{3}^{2-}(a q)-\cdots \mathrm{SO}_{4}^{2-}(a q)\) (basic solution) (g) \(\mathrm{N}_{2}(\mathrm{~g}) \rightarrow \mathrm{NH}_{3}(\mathrm{~g})\) (basic solution)
Two important characteristics of voltaic cells are their cell potential and the total charge that they can deliver. Which of these characteristics depends on theamount of reactants in the cell, and which one depends on their concentration?
(a) Calculate the mass of Li formed by electrolysis of molten LiCl by a current of \(7.5 \times 10^{4}\) A flowing for a period of \(24 \mathrm{~h}\). Assume the electrolytic cell is \(85 \%\) efficient. (b) What is the energy requirement for this electrolysis per mole of Li formed if the applied emf is \(+7.5 \mathrm{~V} ?\)
(a) What is a standard reduction potential? (b) What is the standard reduction potential of a standard hydrogen electrode?
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