Chapter 18: Problem 37
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
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Chapter 18: Problem 37
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
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It is estimated that the lifetime for HFCs in the stratosphere is \(2-7\) years. If HFCs have such long lifetimes, why are they being used to replace CFCs?
The following data was collected for the destruction of \(\mathrm{O}_{3}\) by \(\mathrm{H}\left(\mathrm{O}_{3}+\mathrm{H} \rightarrow \mathrm{O}_{2}+\mathrm{OH}\right)\) at very low concentrations: $$\begin{array}{llll} \text { Experiment } & {\left[\mathrm{O}_{3}\right], \boldsymbol{M}} & {[\mathrm{H}], M} & \text { Initial Rate, } \boldsymbol{M} / \mathrm{s} \\ \hline 1 & 5.17 \times 10^{-33} & 3.22 \times 10^{-26} & 1.88 \times 10^{-14} \\\ 2 & 2.59 \times 10^{-33} & 3.25 \times 10^{-26} & 9.44 \times 10^{-15} \\ 3 & 5.19 \times 10^{-33} & 6.46 \times 10^{-26} & 3.77 \times 10^{-14} \end{array}$$ (a) Write the rate law for the reaction. (b) Calculate the rate constant.
Why is the photodissociation of \(\mathrm{N}_{2}\) in the atmosphere relatively unimportant compared with the photodissociation of \(\mathrm{O}_{2} ?\)
A reaction that contributes to the depletion of ozone in the stratosphere is the direct reaction of oxygen atoms with ozone: $$\mathrm{O}(\mathrm{g})+\mathrm{O}_{3}(g) \longrightarrow 2 \mathrm{O}_{2}(g)$$ At \(298 \mathrm{~K}\) the rate constant for this reaction is \(4.8 \times 10^{5} \mathrm{M}^{-1} \mathrm{~s}^{-1}\). (a) Based on the units of the rate constant, write the likely rate law for this reaction. (b) Would you expect this reaction to occur via a single elementary process? Explain why or why not. (c) From the magnitude of the rate constant, would you expect the activation energy of this reaction to be large or small? Explain. (d) Use \(\Delta H_{f}^{\circ}\) values from Appendix \(C\) to estimate the enthalpy change for this reaction. Would this reaction raise or lower the temperature of the stratosphere?
Phosphorus is present in seawater to the extent of \(0.07 \mathrm{ppm}\) by mass. If the phosphorus is present as phosphate, \(\mathrm{PO}_{4}{ }^{3-}\), calculate the corresponding molar concentration of phosphate in seawater.
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