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Although \(\mathrm{HCl}\) and \(\mathrm{H}_{2} \mathrm{SO}_{4}\) have very different properties as pure substances, their aqueous solutions possess many common properties. List some general properties of these solutions, and explain their common behavior in terms of the species present.

Short Answer

Expert verified
The common properties of aqueous solutions of \(\mathrm{HCl}\) and \(\mathrm{H}_2\mathrm{SO}_4\) include a sour taste, color change in indicators, reaction with metals to produce hydrogen gas, strong electrolyte behavior, and neutralization of basic solutions. These properties can be attributed to the presence and behavior of hydrogen ions (\(\mathrm{H}^{+}\)) in the solutions. The dissociation reactions of these acids in water produce \(\mathrm{H}^{+}\) ions, which are responsible for the observed chemical properties of the acid solutions.

Step by step solution

01

Identify properties of \(\mathrm{HCl}\) and \(\mathrm{H}_2\mathrm{SO}_4\) solutions

First, let's list some general properties that aqueous solutions of \(\mathrm{HCl}\) and \(\mathrm{H}_2\mathrm{SO}_4\) share: 1. Both solutions have a sour taste. 2. They can change the color of certain indicators (e.g., turn blue litmus paper red). 3. They react with metals to produce hydrogen gas. 4. Both are strong electrolytes in solution, meaning they dissolve into ions and conduct electricity. 5. They neutralize basic solutions to form salts and water.
02

Determine the species present in the solutions

When these acids dissolve in water, the following dissociation reactions occur: 1. For \(\mathrm{HCl}\): \(\mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{H}^{+}(\mathrm{aq}) + \mathrm{Cl}^{-}(\mathrm{aq})\) 2. For \(\mathrm{H}_2\mathrm{SO}_4\): \(\mathrm{H}_2\mathrm{SO}_4(\mathrm{aq}) \rightarrow 2\mathrm{H}^{+}(\mathrm{aq}) + \mathrm{SO}_4^{2-}(\mathrm{aq})\) In both reactions, there is a common species produced: the hydrogen ion, \(\mathrm{H}^{+}\).
03

Relate the properties to the common species

Now that we know that both solutions produce a common species (\(\mathrm{H}^{+}\)), we can explain their common properties: 1. The sour taste is a characteristic of acidic solutions, which is due to the presence of hydrogen ions. 2. The color change in indicators is due to the transfer of a proton, \( \mathrm{H}^+ \), from the acid to the indicator, which changes its structure and subsequently its color. 3. When an acid reacts with a metal, hydrogen gas is produced as hydrogen ions (\(\mathrm{H}^{+}\)) are supplied by the acidic solution and combined with metal atoms to form hydrogen molecules, \(\mathrm{H}_2\mathrm{(g)}\). 4. Both solutions are strong electrolytes because the dissociation reactions of \(\mathrm{HCl}\) and \(\mathrm{H}_2\mathrm{SO}_4\) produce ions, which increase the electrical conductivity of the solution. 5. The neutralization process occurs as \(\mathrm{H}^{+}\) ions from the acidic solution react with \(\mathrm{OH}^{-}\) ions from the basic solution to form water, with the remaining ions forming salts. This common behavior is due to the presence of \(\mathrm{H}^{+}\) ions in both acid solutions. In conclusion, the common properties of \(\mathrm{HCl}\) and \(\mathrm{H}_2\mathrm{SO}_4\) solutions are attributed to the presence and behavior of hydrogen ions (\(\mathrm{H}^{+}\)) in the solutions. The chemical properties of these acid solutions are determined by the presence and interactions of \(\mathrm{H}^{+}\) ions.

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Most popular questions from this chapter

Predict the products of the following acid-base reactions, and predict whether the equilibrium lies to the left or to the right of the equation: (a) \(\mathrm{O}^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons\) (b) \(\mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{HS}^{-}(a q) \rightleftharpoons\) (c) \(\mathrm{NO}_{2}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons\)

Identify the Lewis acid and Lewis base among the reactants in each of the following reactions: (a) \(\mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{3}(s)+6 \mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons\) \(\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}{ }^{3+}(a q)+3 \mathrm{ClO}_{4}^{-}(a q)\) (b) \(\mathrm{CN}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{OH}^{-}(a q)\) (c) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(g)+\mathrm{BF}_{3}(g) \rightleftharpoons\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NBF}_{3}(s)\) (d) \(\mathrm{HIO}(l q)+\mathrm{NH}_{2}^{-}(l q) \rightleftharpoons \mathrm{NH}_{3}(l q)+\mathrm{IO}^{-}(l q)\) (lq denotes liquid ammonia as solvent)

A hypothetical acid \(\mathrm{H}_{2} \mathrm{X}\) is both a strong acid and a diprotic acid. (a) Calculate the pH of a \(0.050 \mathrm{M}\) solution of \(\mathrm{H}_{2} \mathrm{X}\), assuming that only one proton ionizes peracid molecule. (b) Calculate the \(\mathrm{pH}\) of the solution from part (a), now assuming that both protons of each acid molecule completely ionize. (c) In an experiment it is observed that the \(\mathrm{pH}\) of a \(0.050 \mathrm{M}\) solution of \(\mathrm{H}_{2} \mathrm{X}\) is \(1.27 .\) Comment on the relative acid strengths of \(\mathrm{H}_{2} \mathrm{X}\) and \(\mathrm{H} \mathrm{X}^{-}\). (d) Would a solution of the salt \(\mathrm{NaH} \mathrm{X}\) be acidic, basic, or neutral? Explain.

Although pure \(\mathrm{NaOH}\) and \(\mathrm{NH}_{3}\) have very different properties, their aqueous solutions possess many common properties. List some general properties of these solutions, and explain their common behavior in terms of the species present.

Calculate the pH of each of the following strong acid solutions: (a) \(8.5 \times 10^{-3} \mathrm{M} \mathrm{HBr}\), (b) \(1.52 \mathrm{~g}\) of \(\mathrm{HNO}_{3}\) in \(575 \mathrm{~mL}\) of solution, \((\mathrm{c}) 5.00 \mathrm{~mL}\) of \(0.250 \mathrm{M} \mathrm{HClO}_{4}\) diluted to \(50.0 \mathrm{~mL}\), (d) a solution formed by mixing \(10.0 \mathrm{~mL}\) of \(0.100 \mathrm{M} \mathrm{HBr}\) with \(20.0 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{HCl}\).

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