Chapter 13: Problem 31
(a) Explain why carbonated beverages must be stored in sealed containers. (b) Once the beverage has been opened, why does it maintain more carbonation when refrigerated than at room temperature?
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Chapter 13: Problem 31
(a) Explain why carbonated beverages must be stored in sealed containers. (b) Once the beverage has been opened, why does it maintain more carbonation when refrigerated than at room temperature?
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A dilute aqueous solution of an organic compound soluble in water is formed by dissolving \(2.35 \mathrm{~g}\) of the compound in water to form \(0.250 \mathrm{~L}\) solution. The resulting solution has an osmotic pressure of \(0.605 \mathrm{~atm}\) at \(25^{\circ} \mathrm{C}\). Assuming that the organic compound is a nonelectrolyte, what is its molar mass?
Acetonitrile (CH \(_{3} \mathrm{CN}\) ) is a polar organic solvent that dissolves a wide range of solutes, including many salts. The density of a \(1.80 \mathrm{M}\) LiBr solution in acetonitrile is \(0.826 \mathrm{~g} / \mathrm{cm}^{3}\). Calculate the concentration of the solution in (a) molality, (b) mole fraction of LiBr, (c) mass percentage of \(\mathrm{CH}_{3} \mathrm{CN}\).
During a typical breathing cycle the \(\mathrm{CO}_{2}\) concentration in the expired air rises to a peak of \(4.6 \%\) by volume. Calculate the partial pressure of the \(\mathrm{CO}_{2}\) at this point, assuming 1 atm pressure. What is the molarity of the \(\mathrm{CO}_{2}\) in air at this point, assuming a body temperature of \(37^{\circ} \mathrm{C} ?\)
(a) Many proteins that remain homogeneously distributed in water have molecular masses in the range of 30,000 amu and larger. In what sense is it appropriate to consider such suspensions to be colloids rather than solutions? Explain. (b) What general name is given to a colloidal dispersion of oneliquid in another? What is an emulsifying agent?
At ordinary body temperature \(\left(37^{\circ} \mathrm{C}\right)\) the solubility of \(\mathrm{N}_{2}\) in water in contact with air at ordinary atmospheric pressure \((1.0 \mathrm{~atm})\) is \(0.015 \mathrm{~g} / \mathrm{L}\). Air is approximately \(78 \mathrm{~mol} \% \mathrm{~N}_{2}\). Calculate the number of moles of \(\mathrm{N}_{2}\) dissolved per liter of blood, which is essentially an aqueous solution. At a depth of \(100 \mathrm{ft}\) in water, the pressure is \(4.0 \mathrm{~atm}\). What is the solubility of \(\mathrm{N}_{2}\) from air in blood at this pressure? If a scuba diver suddenly surfaces from this depth, how many milliliters of \(\mathrm{N}_{2}\) gas, in the form of tiny bubbles, are released into the bloodstream from each liter of blood?
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