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(a) Use orbital diagrams to illustrate what happens when an oxygen atom gains two electrons. (b) Why does \(\mathrm{O}^{3-}\) not exist?

Short Answer

Expert verified
(a) The oxygen atom with electronic configuration 1s虏 2s虏 2p鈦 will have its orbital diagram as: 1s: 鈫戔啌 2s: 鈫戔啌 2p: 鈫戔啌 | 鈫 | 鈫 When it gains two electrons, the 2p orbitals get filled, and the orbital diagram for O虏鈦 becomes: 1s: 鈫戔啌 2s: 鈫戔啌 2p: 鈫戔啌 | 鈫戔啌 | 鈫戔啌 (b) O鲁鈦 doesn't exist due to its higher energy and decreased stability when compared to the O虏鈦 ion. Gaining a third electron would require occupying the 3s orbital, which is less stable, and increase electron repulsion in the already filled 2p orbitals.

Step by step solution

01

(a) Orbital Diagram of Oxygen Atom and Oxygen Ion with 2 Extra Electrons

First, we need to examine the electronic configuration of an oxygen atom and use orbital diagrams to represent it. Oxygen has 8 electrons with the following electronic configuration: 1s虏 2s虏 2p鈦. To represent the gained electrons in the oxygen atom, we can show an oxygen ion with two extra electrons in the 2p orbital: Oxygen atom orbital diagram: 1s: 鈫戔啌 2s: 鈫戔啌 2p: 鈫戔啌 | 鈫 | 鈫 When an oxygen atom gains two electrons, these extra electrons will fill into the 2p orbitals. Then, we have: Oxygen ion orbital diagram ( O虏鈦 ): 1s: 鈫戔啌 2s: 鈫戔啌 2p: 鈫戔啌 | 鈫戔啌 | 鈫戔啌 The oxygen atom has added two electrons to the 2p orbital, resulting in the oxygen ion with a charge of 2- (O虏鈦).
02

(b) Explanation of Why Oxygen Ion with 3 Extra Electrons (O鲁鈦) Does Not Exist

In the case of the oxygen atom, it has 6 electrons in its outer shell (2s虏 2p鈦). Gaining two electrons will complete its outer shell with 8 electrons, completing its octet, which results in a more stable configuration for the oxygen atom: O虏鈦 ion. However, if the oxygen atom were to gain an additional electron to form O鲁鈦, the incoming electron would not fit into the already completed 2p orbitals. The added electron would have to occupy the 3s orbital, which is more energy-intensive and less stable for the atom. Furthermore, taking in a third electron would also increase the repulsion between the electrons in the already filled 2p orbitals, making the ion even less stable. Thus, an O鲁鈦 ion would not exist due to its higher energy and decreased stability when compared to the O虏鈦 ion.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electronic Configuration
Understanding the electronic configuration of an atom is critical for grasping many fundamental concepts in chemistry. Simply put, the electronic configuration is the arrangement of electrons around the nucleus of an atom in its atomic orbitals. For oxygen, with an atomic number of 8, the configuration is noted as 1s虏 2s虏 2p鈦. This indicates that the first energy level, or shell, contains two electrons in the 1s orbital, and the second shell has two electrons in the 2s orbital and four electrons in the 2p orbitals.

When we represent this using orbital diagrams, we show the orbitals as boxes or lines and the electrons as arrows, indicating the spin of each electron. The principle of minimizing electron repulsion ensures that electrons will fill an empty or half-filled orbital before pairing up. In oxygen's case, the 2p orbital will have unpaired electrons indicated as: 鈫 | 鈫 | 鈫 in the orbital diagram for the atom.

A solid understanding of electronic configuration lays the groundwork for studying chemical reactions, bonding, and more, as the way electrons are arranged determines how atoms interact with one another.
Oxygen Ion
The formation of ions is a common and important process in chemistry. An ion is an atom or molecule that has gained or lost one or more electrons, thereby acquiring a net electric charge. In the case of oxygen, an oxygen ion commonly forms when the atom gains two electrons, resulting in a negative two charge, written as O虏鈦. This process can be visualized in an orbital diagram where the extra electrons fill the empty spaces in the oxygen's 2p orbitals, aligning with the goals of achieving lower energy and greater stability.

The orbital diagram after oxygen gains two electrons will show all the 2p orbitals filled: 2p: 鈫戔啌 | 鈫戔啌 | 鈫戔啌. This fuller electronic configuration illustrates how the oxygen atom has achieved a stable, more energetically favorable state. It's essential to appreciate this transition from oxygen atom to oxygen ion as it underlines the atom's drive towards stability through electron gain or loss.
Octet Rule
The octet rule is a chemical principle that reflects the tendency of atoms to prefer to have eight electrons in their valence shell, the outermost electron shell in an atom. This rule is based on the observation that atoms with eight electrons in their valence shell tend to be more stable, resembling the electronic structure of noble gases.

For oxygen, which has six valence electrons, following the octet rule means that gaining two additional electrons to fill its 2p orbitals results in the desirable, stable arrangement of eight valence electrons. This is the driving force behind the oxygen atom's tendency to form the O虏鈦 ion. The completion of the octet through the gain of electrons is a recurrent theme in chemical bonding and is at the heart of many ionic and covalent bonding interactions.
Electron Repulsion
Electron repulsion is a principle coming from Coulomb's law, stating that like charges repel each other. In the context of an atom's orbitals, this translates to the behavior that electrons, all negatively charged, will repel one another and seek to minimize this repulsion by occupying different spaces if available.

In oxygen's 2p orbitals, each electron will initially occupy an empty orbital to minimize repulsion: the first three electrons fill as 鈫 in each 2p orbital. When oxygen becomes an ion by gaining two additional electrons, to minimize repulsion, these electrons pair up with the existing unpaired electrons, resulting in a fully occupied 2p sublevel with paired spins: 鈫戔啌 | 鈫戔啌 | 鈫戔啌.

Conversely, an oxygen ion with a -3 charge, purportedly O鲁鈦, would violate the minimized repulsion principle. The extra third electron would have to unnecessarily pair up in a higher energy 3s orbital or contribute to increased repulsion in the filled 2p orbitals, making the O鲁鈦 ion highly unstable and energetically unfavorable, hence it does not commonly exist.

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Most popular questions from this chapter

It is possible to define metallic character as we do in this book and base it on the reactivity of the element and the ease with which it loses electrons. Alternatively, one could measurehow well electricity is conducted by each of the elements to determine how "metallic" the elements are. On the basis of conductivity, there is not much of a trend in the periodic table: silver is the most conductive metal, and manganese the least. Look up the first ionization energies of silver and manganese; which of these two elements would you call more metallic based on the way we define it in this book?

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