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(a) Define the terms limiting reactant and excess reactant. (b) Why are the amounts of products formed in a reaction determined only by the amount of the limiting reactant? (c) Why should you base your choice of which compound is the limiting reactant on its number of initial moles, not on its initial mass in grams?

Short Answer

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(a) A limiting reactant is the reactant that is entirely consumed when a chemical reaction reaches completion, determining the maximum amount of product that can be formed. An excess reactant is a reactant that remains after a reaction is complete, being present in greater quantity than needed to react with the limiting reactant. (b) The amounts of products formed in a reaction are determined only by the amount of the limiting reactant because once it is used up, the reaction cannot continue. The excess reactant cannot form the desired product without a corresponding stoichiometric amount of another reactant to react with. (c) The choice of which compound is the limiting reactant should be based on its number of initial moles, not on its initial mass in grams, because chemical reactions occur on a mole-to-mole basis according to the stoichiometry of the balanced reaction. Comparing the amounts of reactants in moles allows for the accurate determination of the limiting reactant.

Step by step solution

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(a) Definitions

A limiting reactant is the reactant in a chemical reaction that is entirely consumed when the reaction reaches completion. It determines the maximum amount of product that can be formed, as it limits the progression of the reaction. An excess reactant is a reactant that remains after a reaction is complete. It is present in greater quantity than is required to fully react with the limiting reactant.
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(b) Reason for limiting reactant determining product amounts

The amounts of products formed in a reaction are determined only by the amount of the limiting reactant because once the limiting reactant is used up, the reaction cannot continue. The excess reactant cannot form the desired product without a corresponding stoichiometric amount of another reactant to react with. This means that the limiting reactant determines the maximum amount of product that can be formed in a given reaction.
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(c) Basing limiting reactant choice on initial moles

The choice of which compound is the limiting reactant should be based on its number of initial moles, not on its initial mass in grams because chemical reactions occur on a mole-to-mole basis. In other words, reactions progress according to the ratios of moles of reactants expressed in balanced chemical equations. When comparing the quantities of different reactants, it is essential to convert masses into moles, as this allows us to respect the stoichiometry of the balanced reaction. By comparing the amounts of reactants in moles, we can accurately determine which one will be consumed first, and hence, identify the limiting reactant in the reaction.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Excess Reactant
In any given chemical reaction, certain reactants may be present in quantities larger than what is stoichiometrically necessary to react with other chemicals in the mixture. This is called an excess reactant. It’s like having more bread slices than cheese in a grilled cheese sandwich; no matter how much cheese you have, the number of sandwiches you can make is limited by the amount of cheese. Similarly, in a chemical reaction, the excess reactant remains after all of the limiting reactant has been used up. Understanding excess reactants is crucial because it directly relates to how reactants are consumed and how much waste or leftover chemicals you might have after a reaction.

In practical applications, excess reactants are frequently used to ensure that the limiting reactant is completely consumed, maximizing the desired product. However, keeping track of the excess reactant is also crucial in optimizing the cost-efficiency and environmental impact of industrial chemical processes.
Chemical Reaction Stoichiometry
Stoichiometry is the backbone of chemical reactions; it's the map that guides us through the intricate dance of atoms and molecules as they transform into new products. Chemical reaction stoichiometry refers to the quantitative relationship between reactants and products in a chemical reaction. It's akin to the recipe for cooking; it tells us exactly how much of each ingredient is needed to make the final dish without any leftovers.

To master stoichiometry, one must be familiar with the mole concept, as reactions are described in terms of moles rather than individual atoms or molecules. The reason? Moles allow chemists to

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Most popular questions from this chapter

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