/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 64 An iron ore sample contains \(\m... [FREE SOLUTION] | 91Ó°ÊÓ

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An iron ore sample contains \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) together with other substances. Reaction of the ore with CO produces iron metal: $$ \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g) $$ (a) Balance this equation. (b) Calculate the number of grams of CO that can react with 0.350 \(\mathrm{kg}\) of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) . (c) Calculate the number of grams of Fe and the number of grams of \(\mathrm{CO}_{2}\) formed when 0.350 \(\mathrm{kg}\) of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) reacts. (d) Show that your calculations in parts (b) and (c) are consistent with the law of conservation of mass.

Short Answer

Expert verified
The balanced equation is: \(\mathrm{Fe}_{2}\mathrm{O}_{3}(s)+3\mathrm{CO}(g) \longrightarrow 2\mathrm{Fe}(s)+3\mathrm{CO}_{2}(g)\). For 0.350 kg of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\), 184 grams of CO can react with it, producing 245 grams of Fe and 289 grams of CO\(_2\). These calculations are consistent with the law of conservation of mass, as both the total mass of reactants and products are equal to 534 grams.

Step by step solution

01

(a) Balancing the equation

To balance the chemical equation, we must ensure that there are the same number of atoms of each element on both sides of the equation. The initial equation is: $$ \mathrm{Fe}_{2}\mathrm{O}_{3}(s)+\mathrm{CO}(g) \longrightarrow \mathrm{Fe}(s)+\mathrm{CO}_{2}(g) $$ To balance the equation, we multiply the substances as needed: $$ \mathrm{Fe}_{2}\mathrm{O}_{3}(s)+3\mathrm{CO}(g) \longrightarrow 2\mathrm{Fe}(s)+3\mathrm{CO}_{2}(g) $$ Now, we have the same number of each type of atom on both sides of the equation.
02

(b) Calculating the mass of CO

We are given 0.350 kg of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\) and need to find the mass of CO that can react with it. First, convert the mass of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\) to moles using its molar mass (159.69 g/mol): $$ \text{moles of}\ \mathrm{Fe}_{2}\mathrm{O}_{3} = \frac{0.350\,\text{kg}\, \times\, 1000\,\text{g/kg}}{159.69\,\text{g/mol}} = 2.191\,\text{mol} $$ Now, use the stoichiometry of the balanced equation to find the moles of CO that react with 2.191 moles of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\): $$ \text{moles of CO} = 2.191\,\text{mol}\ \mathrm{Fe}_{2}\mathrm{O}_{3} \times \frac{3\,\text{mol}\,\mathrm{CO}}{1\,\text{mol}\,\mathrm{Fe}_{2}\mathrm{O}_{3}} = 6.573\,\text{mol}\,\mathrm{CO} $$ Finally, convert the moles of CO to grams using its molar mass (28.01 g/mol): $$ \text{mass of CO} = 6.573\,\text{mol}\,\mathrm{CO} \times 28.01\,\text{g/mol} = 184\,\text{g} $$ So, 184 grams of CO can react with 0.350 kg of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\).
03

(c) Calculating the mass of Fe and CO\(_2\) formed

To find the mass of Fe and CO\(_2\) formed when 0.350 kg of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\) reacts, first find the moles of Fe produced using the stoichiometry of the balanced equation: $$ \text{moles of Fe} = 2.191\,\text{mol}\ \mathrm{Fe}_{2}\mathrm{O}_{3} \times \frac{2\,\text{mol}\,\mathrm{Fe}}{1\,\text{mol}\,\mathrm{Fe}_{2}\mathrm{O}_{3}} = 4.382\,\text{mol}\,\mathrm{Fe} $$ Now, convert the moles of Fe to grams using its molar mass (55.845 g/mol): $$ \text{mass of Fe} = 4.382\,\text{mol}\,\mathrm{Fe} \times 55.845\,\text{g/mol} = 245\,\text{g} $$ Next, find the moles of CO\(_2\) produced using the stoichiometry of the balanced equation: $$ \text{moles of CO}_{2} = 2.191\,\text{mol}\ \mathrm{Fe}_{2}\mathrm{O}_{3} \times \frac{3\,\text{mol}\,\mathrm{CO}_{2}}{1\,\text{mol}\,\mathrm{Fe}_{2}\mathrm{O}_{3}} = 6.573\,\text{mol}\,\mathrm{CO}_{2} $$ Then, convert the moles of CO\(_2\) to grams using its molar mass (44.01 g/mol): $$ \text{mass of CO}_{2} = 6.573\,\text{mol}\,\mathrm{CO}_{2} \times 44.01\,\text{g/mol} = 289\,\text{g} $$ So, 245 grams of Fe and 289 grams of CO\(_2\) are formed when 0.350 kg of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\) reacts.
04

(d) Verifying the law of conservation of mass

According to the law of conservation of mass, the total mass of reactants should be equal to the total mass of products. We will now verify this by comparing the mass of reactants with the mass of products: Mass of reactants = mass of \(\mathrm{Fe}_{2}\mathrm{O}_{3}\) + mass of CO Mass of reactants = 0.350 kg (350 g) + 184 g = 534 g Mass of products = mass of Fe + mass of CO\(_2\) Mass of products = 245 g + 289 g = 534 g Since the mass of reactants (534 g) is equal to the mass of products (534 g), our calculations are consistent with the law of conservation of mass.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balancing Chemical Equations
Balancing chemical equations involves ensuring that the same number of each type of atom is present on both sides of a chemical equation. This is crucial to accurately represent chemical reactions. In the given equation, \( \mathrm{Fe}_2\mathrm{O}_3(s) + \mathrm{CO}(g) \rightarrow \mathrm{Fe}(s) + \mathrm{CO}_2(g) \), we start by balancing the iron (Fe) atoms.
1. We have 2 Fe atoms in \( \mathrm{Fe}_2\mathrm{O}_3 \), so we need 2 Fe atoms on the product side. We place a coefficient of 2 in front of \( \mathrm{Fe} \).2. Next, we balance oxygen (O). There are 3 oxygen atoms in \( \mathrm{Fe}_2\mathrm{O}_3 \), and each \( \mathrm{CO}_2 \) has 2, so using 3 \( \mathrm{CO}_2 \) molecules gives us 6 O atoms on the right. Adjusting the CO reactant to 3 balances the carbon as well. Therefore, the balanced equation becomes:\[ \mathrm{Fe}_2\mathrm{O}_3(s) + 3\mathrm{CO}(g) \rightarrow 2\mathrm{Fe}(s) + 3\mathrm{CO}_2(g) \]Remember, balancing equations ensures the conservation of atoms, reflecting their immutability during chemical reactions.
Stoichiometry
Stoichiometry is the scientific study of the quantities of reactants and products in a chemical reaction. It is rooted in the balanced chemical equation.
First, let's convert 0.350 kg of \( \mathrm{Fe}_2\mathrm{O}_3 \) to grams (350 g), simplifying calculations. Using its molar mass (159.69 g/mol), we find:\[ \text{moles of } \mathrm{Fe}_2\mathrm{O}_3 = \frac{350\ g}{159.69\ g/mol} = 2.191\ mol \]Using the balanced equation, the mole ratio instructs stoichiometric proportions:- For CO: \( 2.191\ mol \ \mathrm{Fe}_2\mathrm{O}_3 \times \frac{3\ mol\ \mathrm{CO}}{1\ mol\ \mathrm{Fe}_2\mathrm{O}_3} = 6.573\ mol\ \mathrm{CO} \)- Convert to mass: \( 6.573\ mol\ \mathrm{CO} \times 28.01\ g/mol = 184\ g \ \mathrm{CO} \)This confirms the precise amount of reactants and products through required conversions.
For products:- Fe: \( 2.191\ mol\ \mathrm{Fe}_2\mathrm{O}_3 \times \frac{2\ mol\ \mathrm{Fe}}{1\ mol\ \mathrm{Fe}_2\mathrm{O}_3} = 4.382\ mol\ \mathrm{Fe} \)- Convert to grams: \( 4.382\ mol\ \mathrm{Fe} \times 55.845\ g/mol = 245\ g \ \mathrm{Fe} \)And:- CO\(_2\): \( 2.191\ mol\ \mathrm{Fe}_2\mathrm{O}_3 \times \frac{3\ mol\ \mathrm{CO}_2}{1\ mol\ \mathrm{Fe}_2\mathrm{O}_3} = 6.573\ mol\ \mathrm{CO}_2 \)- Convert to grams: \( 6.573\ mol\ \mathrm{CO}_2 \times 44.01\ g/mol = 289\ g \ \mathrm{CO}_2 \)These stoichiometric calculations underscore how precise mole ratios enable predictability for reaction outcomes.
Law of Conservation of Mass
The law of conservation of mass dictates that in a closed system, mass is neither created nor destroyed by chemical reactions. Instead, the mass of reactants equals the mass of products, a fundamental principle in chemistry.
In this reaction:- Mass of reactants = 350 g \( \mathrm{Fe}_2\mathrm{O}_3 \) + 184 g \( \mathrm{CO} \) = 534 g- Mass of products = 245 g \( \mathrm{Fe} \) + 289 g \( \mathrm{CO}_2 \) = 534 gBoth sides of the equation total to 534 grams, confirming that every atom from the reactants is present in the products.
This verification showcases the principle that total mass remains constant over a chemical reaction's course. It's imperative for calculations in chemistry, ensuring that predictions accurately reflect reality. By adhering to this principle, chemists consistently achieve balance through careful measurement and adjustments during experiments.

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Most popular questions from this chapter

Vanillin, the dominant flavoring in vanilla, contains \(\mathrm{C}, \mathrm{H}\) , and \(\mathrm{O} .\) When 1.05 \(\mathrm{g}\) of this substance is completely combusted, 2.43 \(\mathrm{g}\) of \(\mathrm{CO}_{2}\) and 0.50 \(\mathrm{g}\) of \(\mathrm{H}_{2} \mathrm{O}\) are produced. What is the empirical formula of vanillin?

The fizz produced when an Alka-Seltzer tablet is dissolved in water is due to the reaction between sodium bicarbonate \(\left(\mathrm{NaHCO}_{3}\right)\) and citric acid \(\left(\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}\right) :\) $$ \begin{aligned} 3 \mathrm{NaHCO}_{3}(a q)+\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(a q) & \longrightarrow \\ & 3 \mathrm{CO}_{2}(g)+3 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{Na}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(a q) \end{aligned} $$ In a certain experiment 1.00 g of sodium bicarbonate and 1.00 g of citric acid are allowed to react. (a) Which is the limiting reactant? (b) How many grams of carbon dioxide form? (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed?

Define the terms theoretical yield, actual yield, and percent yield. (b) Why is the actual yield in a reaction almost always less than the theoretical yield?(c) Can a reaction ever have 110\(\%\) actual yield?

Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 \(\mathrm{mg}\) HCN per kilogram of air when inhaled. (a) Calculate the amount of HCN that gives the lethal dose in a small laboratory room measuring \(12 \times 15 \times 8.0 \mathrm{ft}\) . The density of air at \(26^{\circ} \mathrm{C}\) is 0.00118 \(\mathrm{g} / \mathrm{cm}^{3} .\) (b) If the HCN is formed by reaction of \(\mathrm{NaCN}\) with an acid such as \(\mathrm{H}_{2} \mathrm{SO}_{4}\) what mass of NaCN gives the lethal dose in the room? $$ 2 \mathrm{NaCN}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{HCN}(g) $$ (c) HCN forms when synthetic fibers containing Orlon or Acrilan burn. Acrilan has an empirical formula of \(\mathrm{CH}_{2} \mathrm{CHCN},\) so HCN is 50.9\(\%\) of the formula by mass. A rug measures \(12 \times 15 \mathrm{ft}\) and contains 30 oz of Acrilan fibers per square yard of carpet. If the rug burns, will a lethal dose of HCN be generated in the room? Assume that the yield of HCN from the fibers is 20\(\%\) and that the carpet is 50\(\%\) consumed.

Valproic acid, used to treat seizures and bipolar disorder, is composed of \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{O} . \mathrm{A}\) . \(165-\mathrm{g}\) sample is combusted to produce 0.166 \(\mathrm{g}\) of water and 0.403 \(\mathrm{g}\) of carbon dioxide. What is the empirical formula for valproic acid? If the molar mass is \(144 \mathrm{g} / \mathrm{mol},\) what is the molecular formula?

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