Chapter 24: Problem 58
Is 3 -chloro-3-methylhexane chiral?
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Chapter 24: Problem 58
Is 3 -chloro-3-methylhexane chiral?
These are the key concepts you need to understand to accurately answer the question.
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Name or write the condensed structural formula for the following compounds: \begin{equation}\begin{array}{l}{\text { (a) } 4 \text { -methyl-2-pentene }} \\\ {\text { (b) } \text {cis}-2,5 \text { -dimethyl-3-hexene }} \\ {\text { (c) ortho-dimethylbenzene }}\\\\{\text { (d) } \mathrm{HC}=\mathrm{CCH}_{2} \mathrm{CH}_{3}} \\ {\text { (e) } \text {trans}-\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CHCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}}\end{array}\end{equation}
(a) True or false: Alkenes undergo addition reactions and aromatic hydrocarbons undergo substitution reactions. (b) Using condensed structural formulas, write the balanced equation for the reaction of 2 -pentene with Br\(_{2}\) and name the resulting compound. Is this an addition or a substitution reaction? (c) Write a balanced chemical equation for the reaction of \(\mathrm{Cl}_{2}\) with benzene to make paradichlorobenzene in the presence of \(\mathrm{FeCl}_{3}\) as a catalyst. Is this an addition or a substitution reaction?
A typical amino acid with one amino group and one carboxylic acid group, such as serine, can exist in water in several ionic forms. (a) Suggest the forms of the amino acid at low pH and at high pH. (b) Amino acids generally have two pK\(_{a}\) values, one in the range of 2 to 3 and the other in the range of 9 to \(10 .\) Serine, for example, has pK\(_{a}\) values of 2.19 and \(9.21 .\) Using species such as acetic acid and ammonia as models, suggest the origin of the two pK\(_{a}\) values. (c) Glutamic acid is an amino acid that has three \(\mathrm{p} K_{a}^{\prime} \mathrm{s} : 2.10,4.07,\) and \(9.47 .\) Draw the structure of glutamic acid, and assign each \(\mathrm{pK}_{a}\) to the appropriate part of the molecule. (d) An unknown amino acid is titrated with strong base, producing the following titration curve. Which amino acids are likely candidates for the unknown?
You have samples of four compounds: dimethyl ether, methane, difluoromethane, and ethanol. You measure the boiling points of the compounds as \(-128^{\circ} \mathrm{C},-52^{\circ} \mathrm{C}\) \(-25^{\circ} \mathrm{C},\) and \(78^{\circ} \mathrm{C},\) but then lose the labels for each sample. Make the following predictions: (a) Which compound boils at \(-128^{\circ} \mathrm{C} ?(\mathbf{b})\) Which boils at \(-52^{\circ} \mathrm{C} ?(\mathbf{c})\) Which boils at \(-25^{\circ} \mathrm{C} ?(\mathbf{d})\) Which boils at \(78^{\circ} \mathrm{C} ?\)
Write a condensed structural formula for each of the following: (a) an acid with the formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{2},\) (b) a cyclic ketone with the formula \(\mathrm{C}_{5} \mathrm{H}_{8} \mathrm{O},(\mathbf{c})\) a dihydroxy compound with the formula \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}_{2},(\mathbf{d})\) a cyclic ester with the formula \(\mathrm{C}_{5} \mathrm{H}_{8} \mathrm{O}_{2} .\)
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