Chapter 24: Problem 54
Acetic anhydride is formed from two acetic acid molecules, in a condensation reaction that involves the removal of a molecule of water. Write the chemical equation for this process, and show the structure of acetic anhydride.
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Chapter 24: Problem 54
Acetic anhydride is formed from two acetic acid molecules, in a condensation reaction that involves the removal of a molecule of water. Write the chemical equation for this process, and show the structure of acetic anhydride.
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Which statement best explains the chemical differences between DNA and RNA? (a) DNA has two different sugars in its sugar-phosphate backbone, but RNA only has one. (b) Thymine is one of the DNA bases, whereas RNA's corresponding base is thymine minus a methyl group. (c) The RNA sugar-phosphate backbone contains fewer oxygen atoms than DNA's backbone. (d) DNA forms double helices but RNA cannot.
(a) One test for the presence of an alkene is to add a small amount of bromine, which is a red-brown liquid, and look for the disappearance of the red-brown color. This test does not work for detecting the presence of an aromatic hydrocarbon. Explain. (b) Write a series of reactions leading to para-bromoethylbenzene, beginning with benzene and using other reagents as needed. What isomeric side products might also be formed?
(a) Are \(\alpha\) -glucose and \(\beta\) -glucose enantiomers? (b) Show the condensation of two glucose molecules to form a disaccharide with an \(\alpha\) linkage. (c) Repeat part (b) but with a \(\beta\) linkage.
Indicate whether each statement is true or false. (a) Pentane has a higher molar mass than hexane. (b) The longer the linear alkyl chain for straight- chain hydrocarbons, the higher the boiling point. (c) The local geometry around the alkyne group is linear. (d) Propane has two structural isomers.
True or false: The weaker a single bond in a molecule, the greater the chance it will be the site of a reaction (compared to stronger single bonds in the molecule).
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