Chapter 20: Problem 82
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid?
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Chapter 20: Problem 82
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid?
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A voltaic cell is based on \(\mathrm{Ag}^{+}(a q) / \mathrm{Ag}(s)\) and \(\mathrm{Fe}^{3+}(a q) /\) \(\mathrm{Fe}^{2+}(a q)\) half-cells. (a) What is the standard emf of the cell? (b) Which reaction occurs at the cathode and which at the anode of the cell? (c) Use \(S^{\circ}\) values in Appendix \(\mathrm{C}\) and the relationship between cell potential and free-energy change to predict whether the standard cell potential increases or decreases when the temperature is raised above \(25^{\circ} \mathrm{C}\) .
Is each of the following substances likely to serve as an oxidant or a reductant: (a) \(\mathrm{Ce}^{3+}(a q),\)(b) \(\mathrm{Ca}(s),\) (c) \(\mathrm{ClO}_{3}(a q)\) (d) \(\mathrm{N}_{2} \mathrm{O}_{5}(g) ?\)
(a) Calculate the mass of Li formed by electrolysis of molten LiCl by a current of \(7.5 \times 10^{4}\) A flowing for a period of 24 \(\mathrm{h} .\) Assume the electrolytic cell is 85\(\%\) efficient. (b) What is the minimum voltage required to drive the reaction?
A voltaic cell utilizes the following reaction: $$ 4 \mathrm{Fe}^{2+}(a q)+\mathrm{O}_{2}(g)+4 \mathrm{H}^{+}(a q) \longrightarrow 4 \mathrm{Fe}^{3+}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l) $$ (a) What is the emf of this cell under standard conditions? (b) What is the emf of this cell when \(\left[\mathrm{Fe}^{2+}\right]=1.3 \mathrm{M},\left[\mathrm{Fe}^{3+}\right]=\) \(0.010 \mathrm{M}, P_{\mathrm{O}_{2}}=0.50 \mathrm{atm}\) , and the \(\mathrm{pH}\) of the solution in the cathode half-cell is 3.50\(?\)
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
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