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Elements in the same group of the periodic table often form oxyanions with the same general formula. The anions are also named in a similar fashion. Based on these observations,suggest a chemical formula or name, as appropriate, for each of the following ions:\((\mathbf{a}) \mathrm{BrO}_{4}^{-},(\mathbf{b}) \mathrm{SeO}_{3}^{2-}\) \((\mathbf{c})\) arsenate ion, \((\mathbf{d})\) hydrogen tellurate ion.

Short Answer

Expert verified
The chemical formula and names for the given ions are as follows: a) BrO鈧勨伝: Perbromate ion b) SeO鈧兟测伝: Selenite ion c) Arsenate ion: AsO鈧劼斥伝 d) Hydrogen tellurate ion: HTeO鈧冣伝 (Hydrogen Tellurite Ion)

Step by step solution

01

Analyzing Given Ions

Let's start with the first ion BrO鈧勨伝. In this case, the central element is Bromine (Br) from group 17 (halogens) and is combined with four Oxygen atoms (O) with a total charge of -1. It is called Perbromate ion. Next, we have SeO鈧兟测伝 where the central atom is Selenium (Se) from group 16 (chalcogens) combined with three Oxygen atoms, overall with a charge of -2. This ion is called Selenite ion.
02

Finding the Formula for Arsenate Ion

Arsenate ion has Arsenic (As) as the central element. Arsenic belongs to group 15 (pnictogens), below Nitrogen and Phosphorus. As Phosphate ion (PO鈧劼斥伝) has a similar structure, we can assume that the formula for the arsenate ion would also follow the same pattern. Therefore, the arsenate ion (AsO鈧) will also have a charge of -3, because like Phosphorus, Arsenic needs 3 more electrons to complete its octet. Thus, the chemical formula for the Arsenate ion becomes AsO鈧劼斥伝.
03

Finding the Name for Hydrogen Tellurate Ion

The name indicates that there is one hydrogen atom joined with the tellurate ion. The central element in the tellurate ion is Tellurium (Te) from group 16 (chalcogens), same as Selenium. Since we know that the selenite ion has the formula SeO鈧兟测伝, we can infer that the tellurate ion will be TeO鈧兟测伝 because they are both in the same group. Now, we have to add a hydrogen atom to form the hydrogen tellurate ion. When a hydrogen atom (with +1 charge) binds to the tellurate ion (TeO鈧兟测伝), the overall charge will become -1. Thus, the name for hydrogen tellurate ion with the formula HTeO鈧冣伝 is "Hydrogen Tellurite Ion".

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Periodic Table Groups
Understanding periodic table groups is essential for grasping why certain elements form specific oxyanions. Elements in the same group often exhibit similar chemical behavior because of their similar valence electron configurations.

For example, elements in group 17, known as halogens, often form oxyanions with similar formulas. Bromine (Br), when forming the perbromate ion (BrO鈧勨伝), follows a pattern seen in other halogens like chlorine (ClO鈧勨伝). This regularity helps predict chemical behaviors and formulas.
  • Group 15 (pnictogens): Includes elements like nitrogen and phosphorus, known for forming oxyanions with a -3 charge, such as arsenate (AsO鈧劼斥伝).
  • Group 16 (chalcogens): Includes oxygen, sulfur, and selenium, forming oxyanions usually with a -2 charge, like selenite (SeO鈧兟测伝).
  • Group 17 (halogens): Known for different oxyanion structures, as seen with perbromate (BrO鈧勨伝).
Understanding these group similarities simplifies predicting chemical formulas and ion nomenclature.
Chemical Formula
A chemical formula represents the elements in a compound and shows the ratio of atoms. For oxyanions, these formulas help indicate the type and number of atoms involved, as well as the charges.

The formula for perbromate, BrO鈧勨伝, reveals a structure where bromine is central, surrounded by four oxygens. This is analogous to how other elements in the same group arrange with oxygen.

Similarly, the formula SeO鈧兟测伝 for selenite shows selenium centrally bonded to three oxygens. Utilizing this formula pattern aids in predicting structures like that of arsenate (AsO鈧劼斥伝), where arsenic takes the place similar to phosphorus in phosphate (PO鈧劼斥伝).
  • Formulas highlight electron sharing or transfer that define ion charges.
  • Common patterns in formulas emerge from periodic table groups.
  • Predictive value: Knowledge of similar structure in group elements aids in determining unknown oxyanion formulas.
These formulas form a foundation in studying chemical bonding and reactions.
Ion Nomenclature
Ion nomenclature is the system used for naming ions, providing insight into their composition and charge. Accurate naming can guide chemical understanding and predict reactions.

The name 'perbromate' indicates a specific oxyanion series, with -ate endings typically signifying a higher number of oxygen atoms compared to -ite endings. In the perbromate ion, BrO鈧勨伝, 'per-' indicates even more oxygen than a standard bromate.

Selenite, SeO鈧兟测伝, uses the -ite suffix to signify fewer oxygens than selenate (SeO鈧劼测伝). Understanding these naming conventions reveals the balance between oxygen and the central atom.
  • Suffixes like -ite and -ate help identify oxygen atom count.
  • Prefixes like per- (more oxygen) and hypo- (less oxygen) highlight variations within the same element.
  • Hydrogen added to oxyanions, as in hydrogen tellurite (HTeO鈧冣伝), shifts the charge, adding complexity to nomenclature.
Mastering these naming rules aids in effective communication of chemical identities.

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Most popular questions from this chapter

The elements of group 4 \(\mathrm{A}\) show an interesting change in properties moving down the group. Give the name and chemical symbol of each element in the group and label it as a nonmetal, metalloid, or metal.

(a) What is the mass in amu of a carbon-12 atom? (b) Why is the atomic weight of carbon reported as 12.011 in the table of elements and the periodic table in the front inside cover of this text?

Because many ions and compounds have very similar names, there is great potential for confusing them. Write the correct chemical formulas to distinguish between \((\mathbf{a})\) calcium sulfide and calcium hydrogen sulfide, \((\mathbf{b})\) hydrobromic acid and bromic acid \((\mathbf{c})\) aluminum nitride and aluminum nitrite,\((\mathbf{d})\)iron(II) oxide and iron(III) oxide,\((\mathbf{e})\)ammonia and ammonium ion, \((\mathbf{f})\)potassium sulfite and potassium bisulfite,\((\mathbf{g})\) mercurous chloride and mercuric chloride, \((\mathbf{h})\) chloric acid and perchloric acid.

The explosion of an atomic bomb releases many radioactive isotopes, including strontium- \(90 .\) Considering the location of strontium in the periodic table, suggest a reason for the fact that this isotope is particularly dangerous for human health.

Answer the following questions without referring to Table \(2.1 :\) (a) What are the main subatomic particles that make up the atom? (b) What is the relative charge (in multiples of the electronic charge ) of each of the particles? (c) Which of the particles is the most massive? (d) Which is the least massive?

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