Chapter 18: Problem 23
Do the reactions involved in ozone depletion involve changes in oxidation state of the O atoms? Explain.
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Chapter 18: Problem 23
Do the reactions involved in ozone depletion involve changes in oxidation state of the O atoms? Explain.
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(a) How are the boundaries between the regions of the atmosphere determined? (b) Explain why the stratosphere, which is about 35 \(\mathrm{km}\) thick, has a smaller total mass than the troposphere, which is about 12 \(\mathrm{km}\) thick.
It was estimated that the eruption of the Mount Pinatubo volcano resulted in the injection of 20 million metric tons of \(S O_{2}\) into the atmosphere. Most of this \(S O_{2}\) underwent oxidation to \(S O_{3},\) which reacts with atmospheric water to form an aerosol. (a) Write chemical equations for the processes leading to formation of the aerosol. (b) The aerosols caused a \(0.5-0.6^{\circ} \mathrm{C}\) drop in surface temperature in the northern hemisphere. What is the mechanism by which this occurs? (c) The sulfate aerosols, as they are called, also cause loss of ozone from the stratosphere. How might this occur?
(a) Distinguish between photodissociation and photoionization. (b) Use the energy requirements of these two processes to explain why photodissociation of oxygen is more important than photoionization of oxygen at altitudes below about 90 km.
The average concentration of carbon monoxide in air in an Ohio city in 2006 was 3.5 ppm. Calculate the number of CO molecules in 1.0 L of this air at a pressure of 759 torr and a temperature of \(22^{\circ} \mathrm{C}\).
The organic anion is found in most detergents. Assume that the anion undergoes aerobic decomposition in the following manner: $$\begin{aligned} 2 \mathrm{C}_{18} \mathrm{H}_{29} \mathrm{SO}_{3}^{-}(a q)+51 \mathrm{O}_{2}(a q) & \longrightarrow \\ & 36 \mathrm{CO}_{2}(a q)+28 \mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{H}^{+}(a q)+2 \mathrm{SO}_{4}^{2-}(a q) \end{aligned}$$ What is the total mass of \(\mathrm{O}_{2}\) required to biodegrade 10.0 \(\mathrm{g}\) of this substance?
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