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(a) The hydrogen sulfite ion \(\left(\mathrm{HSO}_{3}^{-}\right)\) is amphiprotic. Write a balanced chemical equation showing how it acts as an acid toward water and another equation showing how it acts as a base toward water. (b) What is the conjugate acid of HSO \(_{3}^{-}?\) What is its conjugate base?

Short Answer

Expert verified
(a) As an acid: \( \mathrm{HSO_{3}^{-}} + \mathrm{H_{2}O} \rightleftharpoons \mathrm{H_{3}O^{+}} + \mathrm{SO_{3}^{2-}} \) As a base: \( \mathrm{HSO_{3}^{-}} + \mathrm{H_{2}O} \rightleftharpoons \mathrm{OH^{-}} + \mathrm{H_{2}SO_{3}} \) (b) Conjugate acid: H鈧係O鈧 (sulfurous acid); Conjugate base: SO鈧兟测伝 (sulfite ion)

Step by step solution

01

Part (a): HSO鈧冣伝 acting as an acid

As an acid, HSO鈧冣伝 donates a proton (H鈦) to the water molecule, forming a hydronium ion (H鈧僌鈦) and a corresponding conjugate base. The balanced chemical equation for this reaction is as follows: \( \mathrm{HSO_{3}^{-}} + \mathrm{H_{2}O} \rightleftharpoons \mathrm{H_{3}O^{+}} + \mathrm{SO_{3}^{2-}} \)
02

Part (a): HSO鈧冣伝 acting as a base

As a base, HSO鈧冣伝 accepts a proton (H鈦) from the water molecule, forming a hydroxide ion (OH鈦) and a corresponding conjugate acid. The balanced chemical equation for this reaction is as follows: \( \mathrm{HSO_{3}^{-}} + \mathrm{H_{2}O} \rightleftharpoons \mathrm{OH^{-}} + \mathrm{H_{2}SO_{3}} \)
03

Part (b): Conjugate acid of HSO鈧冣伝

When HSO鈧冣伝 acts as a base, as seen in the previous step, it accepts a proton and forms a conjugate acid. The conjugate acid of HSO鈧冣伝 is H鈧係O鈧 (sulfurous acid).
04

Part (b): Conjugate base of HSO鈧冣伝

When HSO鈧冣伝 acts as an acid, as seen in the first step, it donates a proton and forms a conjugate base. The conjugate base of HSO鈧冣伝 is SO鈧兟测伝 (sulfite ion). In conclusion, the hydrogen sulfite ion (HSO鈧冣伝) can act as both an acid and a base when reacting with water. Its conjugate acid is H鈧係O鈧, and its conjugate base is SO鈧兟测伝.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Equilibrium
In the intriguing world of chemical reactions, chemical equilibrium is a state where the rate of the forward reaction equals the rate of the reverse reaction, meaning that the concentrations of reactants and products remain constant over time. This doesn't imply that the reaction has ceased, but rather that it's proceeding in both directions at the same rate.

Consider a simple acid-base reaction taking place in water. At equilibrium, the number of acid molecules donating a proton to become the conjugate base equals the number of conjugate base molecules accepting a proton to revert to the acid form. The phenomenon of the hydrogen sulfite ion acting both as an acid and a base in water, and reaching equilibrium, illustrates this beautifully.
Conjugate Acid-Base Pairs
The concept of conjugate acid-base pairs is at the heart of understanding acid-base reactions. This pair consists of two species that transform into each other by gain or loss of a proton (H+). In the instance of the hydrogen sulfite ion (HSO鈧冣伝), when it acts as an acid, it donates a proton to form its conjugate base, the sulfite ion (SO鈧兟测伝). Conversely, when HSO鈧冣伝 accepts a proton, it forms its conjugate acid, sulfurous acid (H鈧係O鈧).

These pairs are like two sides of the same coin 鈥 they can be flipped back and forth through acid-base reactions, and understanding them is crucial for predicting the direction and extent of such reactions.
Hydrogen Sulfite Ion
The hydrogen sulfite ion, or HSO鈧冣伝, is an interesting character in the acid-base saga due to its ability to play both roles as required. As an amphiprotic substance, it can lend a proton to become SO鈧兟测伝, or accept one to form H鈧係O鈧. This flexibility is due to its molecular structure which harbours both a hydrogen atom available for donation and spots ripe for accepting a new proton.

Understanding the behavior of such ions is fundamental in many chemical processes, including industrial applications and biological systems where pH balance is pivotal. The amphiprotic nature makes HSO鈧冣伝 incredibly versatile and an essential part of the acid-base dance in chemistry.
Acid-Base Reactions
Delving into acid-base reactions, these are processes where an acid donates a proton to a base. This transaction of protons is not a one-way street but rather a bustling interchange. The acid (proton donor) and base (proton acceptor) in such a reaction can be found in several states 鈥 gaseous, liquid, or even solid.

In the case of HSO鈧冣伝, it can donate a proton to water (acting as a base), or accept one from water (acting as an acid), showing the dynamic nature of these reactions. The ability of a substance to act as either an acid or base in different scenarios is a cornerstone of acid-base chemistry, and it plays a crucial role in many biological systems and industrial chemical processes.

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