Chapter 16: Problem 15
(a) Give the conjugate base of the following Bronsted-Lowry acids: (i) \(\mathrm{HIO}_{3},(\mathbf{i} \mathbf{i}) \mathrm{NH}_{4}^{+} .(\mathbf{b})\) Give the conjugate acid of the following Bronsted-Lowry bases: (i) \(\mathrm{O}^{2-},(\mathbf{i} \mathbf{i}) \mathrm{H}_{2} \mathrm{PO}_{4}^{-}\)
Short Answer
Expert verified
The conjugate bases and acids of the given Bronsted-Lowry acids and bases are:
(a) Conjugate bases:
(i) HIO鈧 鉃 IO鈧冣伝
(ii) NH鈧勨伜 鉃 NH鈧
(b) Conjugate acids:
(i) O虏鈦 鉃 OH鈦
(ii) H鈧侾O鈧勨伝 鉃 H鈧働O鈧
Step by step solution
01
Identify the acid as HIO鈧
The given Bronsted-Lowry acid is HIO鈧.
02
Remove a proton from the acid
To find the conjugate base, we need to remove a proton (H鈦) from the given acid, which means we are left with IO鈧冣伝.
03
Write down the conjugate base
The conjugate base of HIO鈧 is IO鈧冣伝.
(ii) NH鈧勨伜
04
Identify the acid as NH鈧勨伜
The given Bronsted-Lowry acid is NH鈧勨伜.
05
Remove a proton from the acid
To find the conjugate base, we need to remove a proton (H鈦) from the given acid, which means we are left with NH鈧.
06
Write down the conjugate base
The conjugate base of NH鈧勨伜 is NH鈧.
(b) Give the conjugate acid of the following Bronsted-Lowry bases:
(i) O虏鈦
07
Identify the base as O虏鈦
The given Bronsted-Lowry base is O虏鈦.
08
Add a proton to the base
To find the conjugate acid, we need to add a proton (H鈦) to the given base, which means we end up with OH鈦.
09
Write down the conjugate acid
The conjugate acid of O虏鈦 is OH鈦.
(ii) H鈧侾O鈧勨伝
10
Identify the base as H鈧侾O鈧勨伝
The given Bronsted-Lowry base is H鈧侾O鈧勨伝.
11
Add a proton to the base
To find the conjugate acid, we need to add a proton (H鈦) to the given base, which means we end up with H鈧働O鈧.
12
Write down the conjugate acid
The conjugate acid of H鈧侾O鈧勨伝 is H鈧働O鈧.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91影视!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Conjugate Base
In the world of Bronsted-Lowry acids and bases, understanding the concept of a conjugate base is central. When an acid donates a proton, or hydrogen ion (
H^+
), it transforms into its conjugate base. This transformation is crucial to acid-base reactions. For example, when
HIO_3
, an acid, loses a proton, it becomes the conjugate base,
IO_3^-
. Similarly,
NH_4^+
, when losing a proton, turns into
NH_3
, its conjugate base.
To recognize a conjugate base:
To recognize a conjugate base:
- Start by identifying the acid in the reaction.
- Remove one proton from this acid.
- The resulting species is the conjugate base.
Conjugate Acid
Just as acids have conjugate bases, bases have conjugate acids. The concept of a conjugate acid comes into play when a base accepts a proton, resulting in a newly formed acid. Consider the base
O^{2-}
; when it gains a proton, it transforms into the conjugate acid
OH^-
. Another example is
H_2PO_4^-
, which, upon accepting a proton, becomes
H_3PO_4
.
To understand conjugate acids, follow these steps:
To understand conjugate acids, follow these steps:
- Identify the base involved in the reaction.
- Add one proton to the identified base.
- The new species formed is the conjugate acid.
Proton Transfer
At the heart of Bronsted-Lowry acid-base theory is the concept of proton transfer. This process involves the movement of a proton from an acid to a base. Such transfers are fundamental to many chemical reactions and drive the formation of conjugate acid-base pairs.
Consider the transformation of HIO_3 to IO_3^- and NH_4^+ to NH_3 , where protons are transferred from these acids, converting them to their respective conjugate bases. Similarly, the transition of O^{2-} to OH^- and H_2PO_4^- to H_3PO_4 involves an addition of protons, forming conjugate acids.
Important points to remember about proton transfer:
Consider the transformation of HIO_3 to IO_3^- and NH_4^+ to NH_3 , where protons are transferred from these acids, converting them to their respective conjugate bases. Similarly, the transition of O^{2-} to OH^- and H_2PO_4^- to H_3PO_4 involves an addition of protons, forming conjugate acids.
Important points to remember about proton transfer:
- Proton transfer creates two new entities: a conjugate base and a conjugate acid.
- It demonstrates the reversible reactions where an acid becomes a base and vice versa.