Chapter 12: Problem 107
Introduction of carbon into a metallic lattice generally results in a harder, less ductile substance with lower electrical and thermal conductivities. Explain why this might be so.
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Chapter 12: Problem 107
Introduction of carbon into a metallic lattice generally results in a harder, less ductile substance with lower electrical and thermal conductivities. Explain why this might be so.
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A particular form of cinnabar (HgS) adopts the zinc blende structure. The length of the unit cell edge is 5.852 A. (a) Calculate the density of HgS in this form. (b) The mineral tiemannite (HgSe) also forms a solid phase with the zinc blende structure. The length of the unit cell edge in this mineral is 6.085 A. What accounts for the larger unit cell length in tiemmanite? (c) Which of the two substances has the higher density? How do you account for the difference in densities?
Classify each of the following statements as true or false: $$ \begin{array}{l}{\text { (a) Although both molecular solids and covalent- network }} \\ {\text { solids have covalent bonds, the melting points of molec- }} \\ {\text { ular solids are much lower because their covalent bonds }} \\ {\text { are much weaker. }} \\ {\text { (b) Other factors being equal, highly symmetric molecules }} \\ {\text { tend to form solids with highly symmetric molecules }} \\ {\text { asymmetrically shaped molecules. }}\end{array} $$
For each of the following groups, which metal would you expect to have the highest melting point: (a) gold, rhenium, or cesium; (b) rubidium, molybdenum, or indium; (c) ruthenium, strontium, or cadmium?
For each of these solids, state whether you would expect it to possess metallic properties: (a) TiCl_ \(_{4},(\mathbf{b})\) NiCo alloy, \((\mathbf{c}) \mathrm{W}\) \((\mathbf{d}) \mathrm{Ge},(\mathbf{e}) \mathrm{ScN}\)
Iridium crystallizes in a face-centered cubic unit cell that has an edge length of 3.833 \(\dot{A}\). (a) Calculate the atomic radius of an iridium atom. (b) Calculate the density of iridium metal.
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