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The molar mass of a volatile substance was determined by the Dumas-bulb method described in Exercise \(10.53 .\) The unknown vapor had a mass of 0.846 g; the volume of the bulb was \(354 \mathrm{cm}^{3},\) pressure 752 torr, and temperature \(100^{\circ} \mathrm{C}\) . Calculate the molar mass of the unknown vapor.

Short Answer

Expert verified
The molar mass of the unknown vapor is approximately \(27.8 \: g/mol\).

Step by step solution

01

Convert given units to appropriate SI units

First, we need to convert all given values to appropriate SI units to use the ideal gas law equation. The pressure needs to be in pascals (Pa), volume needs to be in meters cubed (m鲁), and the temperature needs to be in kelvin (K). The given values are: - Pressure (P) = 752 torr - Volume (V) = 354 cm鲁 - Temperature (T) = 100掳C - Mass (m) = 0.846 g Convert them to SI units: - P = 752 torr 脳 (101325 Pa / 760 torr) 鈮 100662 Pa - V = 354 cm鲁 脳 (1 m鲁 / 1000000 cm鲁) = 3.54 脳 10鈦烩伌 m鲁 - T = 100掳C + 273.15 = 373.15 K
02

Apply ideal gas law equation to find the number of moles

The ideal gas law equation is: PV = nRT We can solve for the number of moles (n) using the equation: n = PV / RT Substitute the converted values of P, V, and T, and use the R value for SI units (8.314 J/(mol路K)): n = (100662 Pa * 3.54 脳 10鈦烩伌 m鲁) / (8.314 J/(mol路K) * 373.15 K) 鈮 0.0304 moles
03

Calculate the molar mass

The molar mass (M) of the substance can be calculated by dividing the mass by the number of moles: M = mass (g) / n (moles) Substitute the values for mass and the number of moles we just calculated: M = 0.846 g / 0.0304 moles 鈮 27.8 g/mol The molar mass of the unknown vapor is approximately 27.8 g/mol.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Calculating the molar mass of a substance is fundamental in chemistry for understanding the properties and behavior of molecules. The molar mass is simply the mass of one mole of a substance. It helps to determine how much of a substance is needed to achieve a desired chemical reaction. To find the molar mass, you divide the given mass of a substance by the number of moles.
For example, if you have a substance weighing 0.846 grams and have determined via the ideal gas law that it contains 0.0304 moles, the molar mass is calculated as follows:
  • Molar Mass (\( M \)) = Mass (in grams) / Number of moles (\( n \))
  • \( M = 0.846 \text{ g} / 0.0304 \text{ moles} \approx 27.8 \text{ g/mol} \)
This simple division helps in various areas like comparing gases, determining yield in reactions, and converting between amounts of substances.
Ideal Gas Law
The ideal gas law is a crucial equation in chemistry that couples pressure, volume, temperature, and moles of a gas using the formula \( PV = nRT \). This equation is key to understanding gas behavior under various conditions and simplifies analyzing and predicting the state of a gas. Here's a quick breakdown of each component:
  • P: Pressure exerted by the gas, which in SI units is measured in Pascals (Pa).
  • V: Volume occupied by the gas, measured in cubic meters (m鲁).
  • n: Number of moles of the gas.
  • R: The universal gas constant, approximately 8.314 J/(mol路K) for SI units.
  • T: Temperature in Kelvin (K), which must always be used to ensure accuracy.
By rearranging the equation to \( n = \frac{PV}{RT} \), you can calculate the number of moles of gas if pressure, volume, and temperature are known, as seen in solving for the molar mass in the Dumas Bulb Method.
Unit Conversion in Chemistry
Unit conversion plays a fundamental role in chemistry, allowing for consistent measurements across various systems. Here鈥檚 how to handle common conversions:
  • Pressure: Dumas Bulb Method often involves converting pressure from torr to pascals (Pa). Use \( \frac{101325 \text{ Pa}}{760 \text{ torr}} \) as the conversion factor. So, \( 752 \text{ torr} \times \frac{101325}{760} \approx 100662 \text{ Pa} \).
  • Volume: Convert volume from cubic centimeters (cm鲁) to cubic meters (m鲁) using \( \frac{1 \text{ m鲁}}{1000000 \text{ cm鲁}} \). For instance, \( 354 \text{ cm}^3 = 3.54 \times 10^{-4} \text{ m}^3 \).
  • Temperature: Convert Celsius to Kelvin by adding 273.15. So \( 100^{\circ} \text{C} + 273.15 = 373.15 \text{ K} \).
Such conversions ensure compatibility with the ideal gas law and other calculations, enhancing accuracy in measuring and manipulating substances in chemical reactions.
Volatility in Chemistry
Volatility refers to how quickly a substance can vaporize, which is an important factor in chemical experiments and processes. Volatile substances have higher vapor pressures at given temperatures and thus evaporate more readily than less volatile substances. This concept plays a key role in various fields:
  • Distillation Processes: Volatile components are more easily separated through distillation due to differing vapor pressures.
  • Environmental Impact: Understanding volatility helps predict the spread and concentration of substances in air or water.
  • Product Formulation: Volatility knowledge informs the creation of perfumes or pharmaceuticals, where controlled evaporation rates are needed.
In the Dumas Bulb Method, a substance's volatility allows for the determination of molar mass because only volatile substances form vapors that can be measured under standard conditions.

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Most popular questions from this chapter

Calculate each of the following quantities for an ideal gas: (a) the volume of the gas, in liters, if 1.50 mol has a pressure of 1.25 atm at a temperature of \(-6^{\circ} \mathrm{C} ; \mathbf{b}\) ) the absolute temperature of the gas at which \(3.33 \times 10^{-3}\) mol occupies 478 \(\mathrm{mL}\) at 750 torr; (c) the pressure, in atmospheres, if 0.00245 \(\mathrm{mol}\) occupies 413 \(\mathrm{mL}\) at \(138^{\circ} \mathrm{C} ;(\mathbf{d})\) the quantity of gas, in moles, if 126.5 \(\mathrm{L}\) at \(54^{\circ} \mathrm{C}\) has a pressure of 11.25 \(\mathrm{kPa}\) .

The temperature of a \(5.00-\mathrm{L}\) container of \(\mathrm{N}_{2}\) gas is increased from \(20^{\circ} \mathrm{C}\) to \(250^{\circ} \mathrm{C}\) . If the volume is held constant, predict qualitatively how this change affects the following: (a) the average kinetic energy of the molecules; (b) the root-mean- square speed of the molecules; (c) the strength of the impact of an average molecule with the container walls; (d) the total number of collisions of molecules with walls per second.

(a) What conditions are represented by the abbreviation STP? (b) What is the molar volume of an ideal gas at STP? (c) Room temperature is often assumed to be \(25^{\circ} \mathrm{C}\) . Calculate the molar volume of an ideal gas at \(25^{\circ} \mathrm{C}\) and 1 atm pressure. (d) If you measure pressure in bars instead of atmospheres, calculate the corresponding value of \(R\) in L-bar/mol-K.

Hurricane Wilma of 2005 is the most intense hurricane on record in the Atlantic basin, with a low-pressure reading of 882 mbar (millibars). Convert this reading into \((\mathbf{a})\) atmospheres, \((\mathbf{b})\) torr, and \((\mathbf{c})\) inches of Hg.

Ammonia and hydrogen chloride react to form solid ammonium chloride: $$\mathrm{NH}_{3}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{NH}_{4} \mathrm{Cl}(s)$$ Two 2.00 -L flasks at \(25^{\circ} \mathrm{C}\) are connected by a valve, as shown in the drawing. One flask contains 5.00 \(\mathrm{g}\) of \(\mathrm{NH}_{3}(g),\) and the other contains 5.00 \(\mathrm{g}\) of \(\mathrm{HCl}(g) .\) When the valve is opened, the gases react until one is completely consumed. (a) Which gas will remain in the system after the reaction is complete? (b) What will be the final pressure of the system after the reaction is complete? (Neglect the volume of the ammonium chloride formed.) (c) What mass of ammonium chloride will be formed?

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