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Calculate each of the following quantities for an ideal gas: (a) the volume of the gas, in liters, if 1.50 mol has a pressure of 1.25 atm at a temperature of \(-6^{\circ} \mathrm{C} ; \mathbf{b}\) ) the absolute temperature of the gas at which \(3.33 \times 10^{-3}\) mol occupies 478 \(\mathrm{mL}\) at 750 torr; (c) the pressure, in atmospheres, if 0.00245 \(\mathrm{mol}\) occupies 413 \(\mathrm{mL}\) at \(138^{\circ} \mathrm{C} ;(\mathbf{d})\) the quantity of gas, in moles, if 126.5 \(\mathrm{L}\) at \(54^{\circ} \mathrm{C}\) has a pressure of 11.25 \(\mathrm{kPa}\) .

Short Answer

Expert verified
The short answer for each part is as follows: (a) The volume of the gas is \(16.54 L\). (b) The absolute temperature of the gas is \(170.90 K\). (c) The pressure of the gas is \(0.487 atm\). (d) The quantity of gas is \(5.92 mol\).

Step by step solution

01

Part (a): Calculate the volume of the gas

We are given the pressure \(P = 1.25 atm\), the number of moles \(n = 1.50 mol\), and the temperature \(T = -6^{\circ}C\). We have to find the volume of the gas (V). First, we need to convert the temperature into Kelvin (K). Temperature in Kelvin (K) = Temperature in Celsius (C) + 273.15 \(T = -6^{\circ}C + 273.15 = 267.15K\) Now we can use the ideal gas law equation \(PV = nRT\) to find the volume. Here, we will use the value of R in atm L/mol K which is 0.08206 \(atm L / (mol K)\). \(V = \frac{nRT}{P} = \frac{1.50 mol × 0.08206 \frac{atm L}{mol K} × 267.15K}{1.25 atm} = 16.54L\) The volume of the gas is 16.54 liters.
02

Part (b): Calculate the absolute temperature of the gas

We are given the number of moles \(n = 3.33 \times 10^{-3} mol\), the volume V = 478 mL, and the pressure \(P = 750 torr\). We need to find the temperature of the gas (T). First, we need to convert the pressure to atm and the volume to L: \(P = \frac{750 torr}{760 torr/atm} = 0.9868 atm\) \(V = \frac{478mL}{1000mL/L} = 0.478L\) Now we can use the ideal gas law equation \(PV = nRT\) to find the temperature. \(T = \frac{PV}{nR} = \frac{0.9868 atm × 0.478L}{3.33 \times 10^{-3} mol × 0.08206 \frac{atm L}{mol K}} = 170.90 K\) The absolute temperature of the gas is 170.90 K.
03

Part (c): Calculate the pressure of the gas

We are given the number of moles \(n = 0.00245 mol\), the volume \(V = 413 mL\), and the temperature \(T = 138^{\circ}C\). We have to find the pressure of the gas (P). First, convert the temperature to Kelvin and the volume to L: \(T = 138^{\circ}C + 273.15 = 411.15K\) \(V = \frac{413 mL}{1000 mL/L} = 0.413 L\) Now we can use the ideal gas law equation \(PV = nRT\) to find the pressure. \(P = \frac{nRT}{V} = \frac{0.00245 mol × 0.08206 \frac{atm L}{mol K} × 411.15K}{0.413 L} = 0.487 atm\) The pressure of the gas is 0.487 atmospheres.
04

Part (d): Calculate the quantity of gas in moles

We are given the volume \(V = 126.5L\), the temperature \(T = 54^{\circ}C\), and the pressure \(P = 11.25 kPa\). We have to find the number of moles (n) of the gas. First, we need to convert the temperature to Kelvin and the pressure to atm: \(T = 54^{\circ}C + 273.15 = 327.15 K\) \(P = \frac{11.25kPa}{101.325kPa/atm} = 0.1110 atm\) Now we can use the ideal gas law equation \(PV = nRT\) to find the number of moles. \(n = \frac{PV}{RT} = \frac{0.1110 atm × 126.5L}{0.08206 \frac{atm L}{mol K} × 327.15K} = 5.92 mol\) The quantity of gas is 5.92 moles.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

PV=nRT
The ideal gas law is a fundamental equation in chemistry and physics that links together four key quantities of a gas: pressure (P), volume (V), number of moles (n), and temperature (T). The equation is expressed as \( PV = nRT \). Here, R is the ideal gas constant, which has a value of 0.08206 atm L/mol K when using these units.

By rearranging the equation, you can solve for any one of these variables if the others are known. For example, to find volume, you can use \( V = \frac{nRT}{P} \). This makes the ideal gas law a powerful tool for solving problems involving gases, as you can calculate pressure, volume, temperature, or the amount of substance in moles given enough information about the other variables.
  • Understand that \( n \) is the number of moles.
  • R = 0.08206 atm L/mol K is the constant used in these calculations.
  • Ensure all units are appropriate before inserting into the equation.
moles calculation
In chemistry, calculating moles is essential when dealing with gas problems. Moles represent the amount of substance present. We can calculate moles using the ideal gas law by rearranging it to \( n = \frac{PV}{RT} \).

This is useful when you know the pressure, volume, and temperature of a gas. Just plug these values into the equation with the proper units, and you can find out how much gas is present in moles.
  • Use the ideal gas law rearranged for moles: \( n = \frac{PV}{RT} \).
  • Ensure your data (P, V, T) is in the correct units before calculating.
Moles act as a bridge allowing us to connect chemical equations with physical quantities of gases.
temperature conversion
Temperature plays a critical role in gas calculations. In these equations, temperature must always be expressed in Kelvin (K). This is because Kelvin is an absolute temperature scale, and the relationships in the ideal gas law depend on absolute temperature.

Conversion from Celsius to Kelvin is straightforward. Simply add 273.15 to the Celsius temperature: \( T_{K} = T_{C} + 273.15 \).
  • Always convert °C to K before solving gas law problems.
  • Remember: Kelvin = Celsius + 273.15.
When plugging values into the ideal gas law, using Kelvin ensures the accuracy of your calculations and results.
pressure conversion
Pressure must be converted to consistent units before performing calculations with the ideal gas law. Often, pressure needs to be in atmospheres (atm) for the constant R (0.08206 atm L/mol K) to be applicable.

For example, to convert from torr to atm, use the relationship \( 1 \, \text{atm} = 760 \, \text{torr} \). To convert kPa to atm, recall \( 1 \, \text{atm} = 101.325 \, \text{kPa} \).
  • Use \( P(\text{atm}) = \frac{P(\text{torr})}{760} \) to convert torr to atm.
  • Use \( P(\text{atm}) = \frac{P(\text{kPa})}{101.325} \) for kPa to atm conversion.
Converting pressures correctly ensures that the calculations using the ideal gas law remain accurate and reliable.

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Most popular questions from this chapter

The temperature of a \(5.00-\mathrm{L}\) container of \(\mathrm{N}_{2}\) gas is increased from \(20^{\circ} \mathrm{C}\) to \(250^{\circ} \mathrm{C}\) . If the volume is held constant, predict qualitatively how this change affects the following: (a) the average kinetic energy of the molecules; (b) the root-mean- square speed of the molecules; (c) the strength of the impact of an average molecule with the container walls; (d) the total number of collisions of molecules with walls per second.

A 6.53 -g sample of a mixture of magnesium carbonate and calcium carbonate is treated with excess hydrochloric acid. The resulting reaction produces 1.72 \(\mathrm{L}\) of carbon dioxide gas at \(28^{\circ} \mathrm{C}\) and 743 torr pressure. (a) Write balanced chemical equations for the reactions that occur between hydrochloric acid and each component of the mixture. (b) Calculate the total number of moles of carbon dioxide that forms from these reactions. (c) Assuming that the reactions are complete, calculate the percentage by mass of magnesium carbonate in the mixture.

Calculate the pressure that \(\mathrm{CCl}_{4}\) will exert at \(80^{\circ} \mathrm{C}\) if 1.00 mol occupies \(33.3 \mathrm{L},\) assuming that (a) \(\mathrm{CCl}_{4}\) obeys the ideal-gas equation; (b) \(\mathrm{CCl}_{4}\) obeys the van der Waals equation. (Values for the van der Waals constants are given in Table \(10.3 .\) ) (c) Which would you expect to deviate more from ideal behavior under these conditions, \(\mathrm{Cl}_{2}\) or \(\mathrm{CCl}_{4}\) ? Explain.

Which of the following statements best explains why nitrogen gas at STP is less dense than Xe gas at STP? \begin{equation}\begin{array}{l}{\text { (a) Because Xe is a noble gas, there is less tendency for the Xe }} \\ {\text { atoms to repel one another, so they pack more densely in }} \\ {\text { the gaseous state. }} \\ {\text { (b) Xe atoms have a higher mass than } \mathrm{N}_{2} \text { molecules. Because }} \\ {\text { both gases at STP have the same number of molecules per }} \\ {\text { unit volume, the Xe gas must be denser. }}\\\\{\text { (c) The Xe atoms are larger than } \mathrm{N}_{2} \text { molecules and thus take }} \\ {\text { up a larger fraction of the space occupied by the gas. }} \\\ {\text { (d) Because the Xe atoms are much more massive than the }} \\\ {\mathrm{N}_{2} \text { molecules, they move more slowly and thus exert }} \\\ {\text { less upward force on the gas container and make the gas }} \\ {\text { appear denser. }}\end{array}\end{equation}

Calcium hydride, CaH \(_{2},\) reacts with water to form hydrogen gas: $$\mathrm{CaH}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(a q)+2 \mathrm{H}_{2}(g)$$ This reaction is sometimes used to inflate life rafts, weather balloons, and the like, when a simple, compact means of generating \(\mathrm{H}_{2}\) is desired. How many grams of \(\mathrm{CaH}_{2}\) are needed to generate 145 \(\mathrm{L}\) of \(\mathrm{H}_{2}\) gas if the pressure of \(\mathrm{H}_{2}\) is 825 torr at \(21^{\circ} \mathrm{C} ?\)

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