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Predict the chemical formula of the ionic compound formed between the following pairs of elements: (a) \(\mathrm{Al}\) and \(\mathrm{F}\), (b) \(\mathrm{K}\) and \(\mathrm{S}\), (c) \(\mathrm{Y}\) and \(\mathrm{O}\), (d) \(\mathrm{Mg}\) and \(\mathrm{N}\).

Short Answer

Expert verified
The chemical formulas of the ionic compounds formed between the given pairs of elements are as follows: (a) \(\mathrm{AlF_3}\), (b) \(\mathrm{K_2S}\), (c) \(\mathrm{Y_2O_3}\), and (d) \(\mathrm{Mg_3N_2}\).

Step by step solution

01

Identify the charges on the elements

We can find the charges of the elements by using the periodic table and looking at their groups. Elements in Group 1 form ions with a +1 charge, Group 2 with a +2 charge, Group 13 with a +3 charge, Group 15 with a -3 charge, Group 16 with a -2 charge, and Group 17 with a -1 charge. (a) \(\mathrm{Al}\) and \(\mathrm{F}\): \(\mathrm{Al}\) is in Group 13, so it forms a +3 ion. \(\mathrm{F}\) is in Group 17, so it forms a -1 ion. (b) \(\mathrm{K}\) and \(\mathrm{S}\): \(\mathrm{K}\) is in Group 1, so it forms a +1 ion. \(\mathrm{S}\) is in Group 16, so it forms a -2 ion. (c) \(\mathrm{Y}\) and \(\mathrm{O}\): \(\mathrm{Y}\) (yttrium) is in Group 3, so it forms a +3 ion. \(\mathrm{O}\) is in Group 16, so it forms a -2 ion. (d) \(\mathrm{Mg}\) and \(\mathrm{N}\): \(\mathrm{Mg}\) is in Group 2, so it forms a +2 ion. \(\mathrm{N}\) is in Group 15, so it forms a -3 ion.
02

Determine the chemical formula

Now, we will determine the chemical formula by satisfying the electrical neutrality in the compound by ensuring that the total positive charge equals the total negative charge. (a) \(\mathrm{Al}\) and \(\mathrm{F}\): We need 3 \(\mathrm{F}\) ions (-1 each) for every \(\mathrm{Al}\) ion (+3) to satisfy neutrality: \(\mathrm{AlF_3}\) (b) \(\mathrm{K}\) and \(\mathrm{S}\): We need 2 \(\mathrm{K}\) ions (+1 each) for every \(\mathrm{S}\) ion (-2) to satisfy neutrality: \(\mathrm{K_2S}\) (c) \(\mathrm{Y}\) and \(\mathrm{O}\): We need 2 \(\mathrm{Y}\) ions (+3 each) for every 3 \(\mathrm{O}\) ions (-2 each) to satisfy neutrality: \(\mathrm{Y_2O_3}\) (d) \(\mathrm{Mg}\) and \(\mathrm{N}\): We need 3 \(\mathrm{Mg}\) ions (+2 each) for every 2 \(\mathrm{N}\) ions (-3 each) to satisfy neutrality: \(\mathrm{Mg_3N_2}\) We have the chemical formulas of the ionic compounds for each pair of elements.

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Most popular questions from this chapter

The substance chlorine monoxide, \(\mathrm{ClO}(\mathrm{g})\), is important in atmospheric processes that lead to depletion of the ozone layer. The ClO molecule has an experimental dipole moment of \(1.24 \mathrm{D}\), and the \(\mathrm{Cl}\) - \(\mathrm{O}\) bond length is \(1.60 \hat{A}\). (a) Determine the magnitude of the charges on the \(\mathrm{Cl}\) and \(\mathrm{O}\) atoms in units of the electronic charge, \(e\). (b) Based on the electronegativities of the elements, which atom would you expect to have a partial negative charge in the \(\mathrm{ClO}\) molecule? (c) Using formal charges as a guide, propose the dominant Lewis structure for the molecule. (d) The anion \(\mathrm{ClO}^{-}\)exists. What is the formal charge on the \(\mathrm{Cl}\) for the best Lewis structure for \(\mathrm{ClO}^{-}\)?

By referring only to the periodic table, select (a) the most electronegative element in group \(6 A ;(b)\) the least electronegative element in the group \(\mathrm{Al}, \mathrm{Si}, \mathrm{P}\); (c) the most electronegative element in the group Ga, \(\mathrm{P}, \mathrm{Cl}, \mathrm{Na}\) (d) the element in the group \(\mathrm{K}, \mathrm{C}, \mathrm{Zn}, \mathrm{F}\) that is most likely to form an ionic compound with Ba.

Draw Lewis structures for the following: (a) \(\mathrm{SiH}_{4}\), (b) \(\mathrm{CO}\), (c) \(\mathrm{SF}_{2}\), (d) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) ( \(\mathrm{H}\) is bonded to \(\mathrm{O}\) ), (e) \(\mathrm{ClO}_{2}^{-}\), (f) \(\mathrm{NH}_{2} \mathrm{OH}\).

Arrange the bonds in each of the following sets in order of increasing polarity: (a) \(\mathrm{C}-\mathrm{F}, \mathrm{O}-\mathrm{F}, \mathrm{Be}-\mathrm{F}\); (b) \(\mathrm{O}-\mathrm{Cl}, \mathrm{S}-\mathrm{Br}, \mathrm{C}-\mathrm{P}\); (c) \(\mathrm{C}-\mathrm{S}, \mathrm{B}-\mathrm{F}, \mathrm{N}-\mathrm{O}\).

One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity \(=k(I-E A)\), where \(k\) is a proportionality constant. (a) How does this definition explain why the electronegativity of \(\mathrm{F}\) is greater than that of \(\mathrm{Cl}\) even though \(\mathrm{Cl}\) has the greater electron affinity? (b) Why are both ionization energy and electron affinity relevant to the notion of electronegativity? (c) By using data in Chapter 7 , determine the value of \(k\) that would lead to an electronegativity of \(4.0\) for \(F\) under this definition. (d) Use your result from part (c) to determine the electronegativities of \(\mathrm{Cl}\) and \(\mathrm{O}\) using this scale. (e) Another scale for electronegativity defines electronegativity as the average of an atom's first ionization energy and its electron affinity. Using this scale, calculate the electronegativities for the halogens, and scale them so fluorine has an electronegativity of 4.0. On this scale, what is Br's electronegativity?

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