Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
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Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
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Consider the formate ion, \(\mathrm{HCO}_{2}^{-}\), which is the anion formed when formic acid loses an \(\mathrm{H}^{+}\)ion. The \(\mathrm{H}\) and the two \(\mathrm{O}\) atoms are bonded to the central \(\mathrm{C}\) atom. (a) Draw the best Lewis structure(s) for this ion. (b) Are resonance structures needed to describe the structure? (c) Would you predict that the \(\mathrm{C}-\mathrm{O}\) bond lengths in the formate ion would be longer or shorter relative to those in \(\mathrm{CO}_{2}\) ?
Consider the following statement: "For some molecules and ions, a Lewis structure that satisfies the octet rule does not lead to the lowest formal charges, and a Lewis structure that leads to the lowest formal charges does not satisfy the octet rule." Illustrate this statement using the hydrogen sulfite ion, \(\mathrm{HSO}_{3}{ }^{-}\), as an example (the \(\mathrm{H}\) atom is bonded to one of the O atoms).
Write Lewis structures for the following: (a) \(\mathrm{H}_{2} \mathrm{CO}\) (both \(\mathrm{H}\) atoms are bonded to \(\mathrm{C}\) ), (b) \(\mathrm{H}_{2} \mathrm{O}_{2}\), (c) \(\mathrm{C}_{2} \mathrm{~F}_{6}\) (contains a \(\mathrm{C}-\mathrm{C}\) bond), (d) \(\mathrm{AsO}_{3}{ }^{3-}\), (e) \(\mathrm{H}_{2} \mathrm{SO}_{3}\) ( \(\mathrm{H}\) is bonded to \(\mathrm{O}\) ), (f) \(\mathrm{NH}_{2} \mathrm{Cl}\).
(a) Triazine, \(\mathrm{C}_{3} \mathrm{H}_{3} \mathrm{~N}_{3}\), is like benzene except that in triazine every other \(\mathrm{C}-\mathrm{H}\) group is replaced by a nitrogen atom. Draw the Lewis structure(s) for the triazine molecule. (b) Estimate the carbon-nitrogen bond distances in the ring.
An ionic substance of formula MX has a lattice energy of \(6 \times 10^{3} \mathrm{~kJ} / \mathrm{mol}\). Is the charge on the ion M likely to be \(1+, 2+\), or \(3+\) ? Explain.
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