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Predict whether each of the following compounds is soluble in water: (a) AgI, (b) \(\mathrm{Na}_{2} \mathrm{CO}_{3}\), (c) \(\mathrm{BaCl}_{2}\), (d) \(\mathrm{Al}(\mathrm{OH})_{3}\), (e) \(\mathrm{Zn}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{2}\).

Short Answer

Expert verified
Using the solubility rules, we can predict the solubility of each compound in water: (a) AgI: Insoluble (b) Na鈧侰O鈧: Soluble (c) BaCl鈧: Soluble (d) Al(OH)鈧: Insoluble (e) Zn(CH鈧僀OO)鈧: Soluble

Step by step solution

01

Identify the ions in each compound

For each compound, identify the cation (positively charged ion) and the anion (negatively charged ion). Apply the solubility rules to determine whether the compound is soluble in water or not. (a) AgI: Ag鈦 (silver) and I鈦 (iodide) (b) Na鈧侰O鈧: Na鈦 (sodium) and CO鈧兟测伝 (carbonate) (c) BaCl鈧: Ba虏鈦 (barium) and Cl鈦 (chloride) (d) Al(OH)鈧: Al鲁鈦 (aluminium) and OH鈦 (hydroxide) (e) Zn(CH鈧僀OO)鈧: Zn虏鈦 (zinc) and CH鈧僀OO鈦 (acetate)
02

Apply the solubility rules

The following solubility rules can be used for this exercise: 1. Most group 1 (alkali metals) and ammonium compounds are soluble. 2. Most nitrates, acetates (CH鈧僀OO鈦), and perchlorates are soluble. 3. Most halogens (Cl鈦, Br鈦, I鈦) are soluble, except when combined with Ag鈦, Pb2鈦, and Hg鈧偮测伜. 4. Most sulfates are soluble, except when combined with Ba虏鈦, Pb虏鈦, Ca虏鈦, and Sr虏鈦. 5. Most hydroxides are insoluble, except when combined with group 1, Ca虏鈦, Sr虏鈦, and Ba虏鈦. 6. Most carbonates (CO鈧兟测伝), phosphates (PO鈧劼斥伝), chromates (CrO鈧劼测伝), and sulfides are insoluble unless combined with group 1 or ammonium.
03

Determine the solubility of each compound based on the solubility rules

(a) AgI: The compound contains I鈦 (a halogen) and Ag鈦. According to rule 3, this compound is insoluble in water. (b) Na鈧侰O鈧: The compound contains Na鈦 (a group 1 element) and CO鈧兟测伝. According to rule 1, this compound is soluble in water. (c) BaCl鈧: The compound contains Ba虏鈦 and Cl鈦 (a halogen). According to rule 3, this compound is soluble in water, because Ba虏鈦 is not an exception for halogens. (d) Al(OH)鈧: The compound contains Al鲁鈦 and OH鈦. According to rule 5, this compound is insoluble in water, because Al鲁鈦 is not an exception for hydroxides. (e) Zn(CH鈧僀OO)鈧: The compound contains Zn虏鈦 and CH鈧僀OO鈦 (acetate). According to rule 2, this compound is soluble in water.
04

Summarize the solubility results

Based on the solubility rules applied to each compound: (a) AgI: Insoluble (b) Na鈧侰O鈧: Soluble (c) BaCl鈧: Soluble (d) Al(OH)鈧: Insoluble (e) Zn(CH鈧僀OO)鈧: Soluble

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Solubility in Water
Understanding how solubility in water works is essential for predicting the behavior of substances in various chemical processes. Solubility refers to the maximum amount of a substance that can dissolve in a solvent at a given temperature and pressure. Water, often called the 'universal solvent', can dissolve many compounds due to its polar nature.

Solubility is governed by the interplay between the forces of attraction among the solute particles and between the solute particles and solvent. If the attractions between the solvent molecules (water) and the solute are strong enough, then the substance will dissolve. Temperature also plays a crucial role; generally, as temperature increases, so does solubility for most soluble substances.

For the exercise at hand, the solubility rules are key to determining whether a compound will dissolve in water. Knowing these rules allows us to predict that sodium carbonate, Na鈧侰O鈧, will dissolve due to its positive cation being from group 1, which are generally soluble in water.
Ionic Compounds
Ionic compounds are chemical compounds made up of ions that are held together by ionic bonds. The ions are atoms or molecules that have gained or lost electrons and thus have a net negative or positive charge. In the context of solubility, when ionic compounds dissolve in water, the cations and anions separate and disperse uniformly throughout the solution.

Ionic compounds typically dissolve well in polar solvents such as water, but there are exceptions based on the charge and size of the ion, and the specific ionic lattice structure. For instance, silver iodide (AgI) does not dissolve in water despite being ionic because the solubility rules indicate the exception due to the presence of the Ag鈦 ion. These nuances make the study of ionic compounds intriguing, as one must consider both the properties of the ions involved and the overarching solubility rules.
Soluble and Insoluble Compounds
In chemistry, distinguishing between soluble and insoluble compounds is a fundamental skill. Soluble compounds are those that dissolve in a solvent, such as water, to a significant extent. Conversely, insoluble compounds do not dissolve appreciably in a solvent.

The solubility rules help predict the solubility of ionic compounds in water. For example, hydroxides are generally insoluble, but an important exception is when they are combined with certain cations like those from the Group 1 elements. This rule explains why Al(OH)鈧 is insoluble, as it does not fall within the exceptions listed. Understanding and applying these rules allow scientists to predict the behavior of substances in various environments, which is crucial in fields ranging from pharmacology to environmental science.

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Most popular questions from this chapter

(a) Starting with solid sucrose, \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\), describe how you would prepare \(250 \mathrm{~mL}\) of a \(0.250 \mathrm{M}\) sucrose solution. (b) Describe how you would prepare \(350.0 \mathrm{~mL}\) of \(0.100 \mathrm{MC}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\) starting with \(3.00 \mathrm{~L}\) of \(1.50 \mathrm{M} \mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\).

The average adult human male has a total blood volume of \(5.0 \mathrm{~L}\). If the concentration of sodium ion in this average individual is \(0.135 \mathrm{M}\), what is the mass of sodium ion circulating in the blood?

Which of the following are redox reactions? For those that are, indicate which element is oxidized and which is reduced. For those that are not, indicate whether they are precipitation or neutralization reactions. (a) \(\begin{aligned} \mathrm{P}_{4}(s)+10 \mathrm{HClO}(a q)+6 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow & \longrightarrow \mathrm{H}_{3} \mathrm{PO}_{4}(a q)+10 \mathrm{HCl}(a q) \end{aligned}\) (b) \(\mathrm{Br}_{2}(l)+2 \mathrm{~K}(s) \longrightarrow 2 \mathrm{KBr}(s)\) (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}(l)+3 \mathrm{O}_{2}(g) \longrightarrow 3 \mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{CO}_{2}(g)\) (d) \(\mathrm{ZnCl}_{2}(a q)+2 \mathrm{NaOH}(a q) \longrightarrow \mathrm{Zn}(\mathrm{OH})_{2}(s)+\) \(2 \mathrm{NaCl}(a q)\)

Separate samples of a solution of an unknown ionic compound are treated with dilute \(\mathrm{AgNO}_{3}, \mathrm{~Pb}\left(\mathrm{NO}_{3}\right)_{2}\), and \(\mathrm{BaCl}_{2}\). Precipitates form in all three cases. Which of the following could be the anion of the unknown salt: \(\mathrm{Br}^{-}, \mathrm{CO}_{3}{ }^{2-}, \mathrm{NO}_{3}{ }^{-}\)?

Classify each of the following aqueous solutions as a nonelectrolyte, weak electrolyte, or strong electrolyte: (a) \(\mathrm{LiClO}_{4}\), (b) \(\mathrm{HClO}\), (c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\) (propanol), (d) \(\mathrm{HClO}_{3}\), (e) \(\mathrm{CuSO}_{4}\), (f) \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\) (sucrose).

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