Draw the crystal-field energy-level diagrams and show the placement of \(d\)
electrons for each of the following: (a)
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}\)
(four unpaired electrons), (b) \(\left[\mathrm{Mn}\left(\mathrm{H}_{2}
\mathrm{O}\right)_{6}\right]^{2+}\) (high spin), (c)
\(\left[\mathrm{Ru}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{H}_{2}
\mathrm{O}\right)\right]^{2+}\) (low spin), (d)
\(\left[\mathrm{IrCl}_{6}\right]^{2-}\) (low spin), (c)
\(\left[\mathrm{Cr}(\mathrm{cn})_{3}\right]^{1+}\), (f)
\(\left[\mathrm{NiF}_{6}\right]^{4-}\).