Chapter 22: Problem 32
A friend tells you that the "neon" in neon signs is a compound of neon and aluminum. Can your friend be correct? Explain.
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Chapter 22: Problem 32
A friend tells you that the "neon" in neon signs is a compound of neon and aluminum. Can your friend be correct? Explain.
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(a) What is the characteristic geometry about silicon in all silicate minerals? (b) Metasilicic acid has the empirical formula \(\mathrm{H}_{2} \mathrm{SiO}_{3}\). Which of the structures shown in Figure \(22.34\) would you expect metasilicic acid to have? 22.76 Speculate as to why carbon forms carbonate rather than silicate analogs.
Ultrapure germanium, like silicon, is used in semiconductors. Germanium of "ordinary" purity is prepared by the high-temperature reduction of \(\mathrm{GeO}_{2}\) with carbon. The Ge is converted to \(\mathrm{GeCl}_{4}\) by treatment with \(\mathrm{Cl}_{2}\) and then purified by distillation; \(\mathrm{GeCl}_{4}\) is then hydrolyzed in water to \(\mathrm{GeO}_{2}\) and reduced to the elemental form with \(\mathrm{H}_{2}\). The element is then zone refined. Write a balanced chemical equation for each of the chemical transformations in the course of forming ultrapure Ge from \(\mathrm{GeO}_{2}\).
Write balanced equations for each of the following reactions. (a) When mercury(II) oxide is heated, it decomposes to form \(\mathrm{O}_{2}\) and mercury metal. (b) When copper(II) nitrate is heated strongly, it decomposes to form copper(II) oxide, nitrogen dioxide, and oxygen. (c) Lead(II) sulfide, \(\mathrm{PbS}(s)\), reacts with ozone to form \(\mathrm{PbSO}_{4}(s)\) and \(\mathrm{O}_{2}(g)\). (d) When heated in air, \(\mathrm{ZnS}(s)\) is converted to \(\mathrm{ZnO}\). (e) Potassium peroxide reacts with \(\mathrm{CO}_{2}(g)\) to give potassium carbonate and \(\mathrm{O}_{2}\) (f) Oxygen is converted to ozone in the upper atmosphere.
Complete and balance the following equations: (a) \(\mathrm{NaOCH}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\) (b) \(\mathrm{CuO}(s)+\mathrm{HNO}_{3}(a q) \longrightarrow\) (c) \(\mathrm{WO}_{3}(s)+\mathrm{H}_{2}(g) \stackrel{\Delta}{\longrightarrow}\) (d) \(\mathrm{NH}_{2} \mathrm{OH}(l)+\mathrm{O}_{2}(g) \longrightarrow\) (c) \(\mathrm{Al}_{1} \mathrm{C}_{1}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\)
Chemists tried for a long time to make molecular compounds containing silicon- silicon double bonds, they finally succeeded in 1981 . The trick is having large, bulky R groups on the silicon atoms to make \(\mathrm{R}_{2} \mathrm{Si}=\mathrm{SiR}_{2}\) compounds. What experiments could you do to prove that a new compound has a silicon-silicon double bond rather than a silicon-silicon single bond?
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