Chapter 22: Problem 24
List (a) three commercial means of producing \(\mathrm{H}_{2}\), (b) three industrial uses of \(\mathrm{H}_{2}\).
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Chapter 22: Problem 24
List (a) three commercial means of producing \(\mathrm{H}_{2}\), (b) three industrial uses of \(\mathrm{H}_{2}\).
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(a) What is the oxidation state of \(\mathrm{P}\) in \(\mathrm{PO}_{4}{ }^{3-}\) and of \(\mathrm{N}^{-}\)in \(\mathrm{NO}_{3}{ }^{-}\)? (b) Why doesn't N form a stable \(\mathrm{NO}_{4}^{3-}\). ion analogous to \(\mathrm{P}\) ?
Write a balanced equation for each of the following reactions: (a) preparation of white phosphorus from calcium phosphate, (b) hydrolysis of \(\mathrm{PBr}_{3}\), (c) reduction of \(\mathrm{PBr}_{3}\) to \(\mathrm{P}_{4}\) in the gas phase, using \(\mathrm{H}_{2}\).
Write the Lewis structure for each of the following species, and indicate the structure of each: (a) \(\mathrm{SeO}_{3}{ }^{2-} ;\) (b) \(\mathrm{S}_{2} \mathrm{Cl}_{2}\); (c) chlorosulfonic acid, \(\mathrm{HSO}_{3} \mathrm{Cl}\) (chlorine is bonded to sulfur).
Write the Lewis structure for each of the following species, describe its geometry, and indicate the oxidation state of the nitrogen: (a) \(\mathrm{HNO}_{2}\), (b) \(\mathrm{N}_{3}^{-}\), (c) \(\mathrm{N}_{2} \mathrm{H}_{5}^{+}\), (d) \(\mathrm{NO}_{3}^{-}\).
Indicate whether each of the following statements is true or false (a) \(\mathrm{H}_{2}(g)\) and \(\mathrm{D}_{2}(g)\) are allotropic forms of hydrogen. (b) \(\mathrm{ClF}_{3}\) is an interhalogen compound. (c) \(\mathrm{MgO}(\) s) is an acidic anhydride. (d) \(\mathrm{SO}_{2}(g)\) is an acidic anhydride. (c) \(2 \mathrm{H}_{3} \mathrm{PO}_{4}(l) \rightarrow \mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7}(l)+\mathrm{H}_{2} \mathrm{O}(g)\) is an example of a condensation reaction. (f) Tritium is an isotope of the element hydrogen. (g) \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightarrow 2 \mathrm{SO}_{3}(g)\) is an example of a disproportionation reaction.
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