/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 27 One of the nuclides in each of t... [FREE SOLUTION] | 91Ó°ÊÓ

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One of the nuclides in each of the following pairs is radioactive. Predict which is radioactive and which is stable: (a) \({ }_{19}^{39} \mathrm{~K}\) and \({ }_{19}^{40} \mathrm{~K}\), (b) \({ }^{209} \mathrm{Bi}\) and \({ }^{208} \mathrm{Bi}\), (c) nickel-58 and nickel-65.

Short Answer

Expert verified
The radioactive isotopes are \({ }_{19}^{40}\mathrm{K}\), \({ }^{208}\mathrm{Bi}\), and Nickel-65, as their proton and neutron numbers are farther from the magic numbers, making them less stable compared to their counterparts.

Step by step solution

01

Identify isotopes and their numbers of protons and neutrons

First, let's list the isotopes given in the exercise and identify their numbers of protons (Z) and neutrons (N): (a) \({ }_{19}^{39}\mathrm{K}\) (Z=19, N=20) and \({ }_{19}^{40}\mathrm{K}\) (Z=19, N=21) (b) \({ }^{209}\mathrm{Bi}\) (Z=83, N=126) and \({ }^{208}\mathrm{Bi}\) (Z=83, N=125) (c) Nickel-58 (Z=28, N=30) and Nickel-65 (Z=28, N=37)
02

Compare with magic numbers

Now, let's compare the numbers of protons and neutrons for each isotope to the magic numbers. The closer they are, the more stable the isotope. (a) \({ }_{19}^{39}\mathrm{K}\): Z = 19 (not close to any magic numbers), N = 20 (magic number) \({ }_{19}^{40}\mathrm{K}\): Z = 19 (not close to any magic numbers), N = 21 (not close to any magic numbers) (b) \({ }^{209}\mathrm{Bi}\): Z = 83 (not close to any magic numbers), N = 126 (magic number) \({ }^{208}\mathrm{Bi}\): Z = 83 (not close to any magic numbers), N = 125 (close to magic number 126) (c) Nickel-58: Z = 28 (magic number), N = 30 (not close to any magic numbers) Nickel-65: Z = 28 (magic number), N = 37 (not close to any magic numbers)
03

Determine stability

Based on our comparison with the magic numbers, we can now predict which isotopes are more stable, and which are likely to be radioactive: (a) \({ }_{19}^{39}\mathrm{K}\) is more stable (N = magic number), so \({ }_{19}^{40}\mathrm{K}\) is likely radioactive. (b) \({ }^{209}\mathrm{Bi}\) is more stable (N = magic number), so \({ }^{208}\mathrm{Bi}\) is likely radioactive. (c) Nickel-58 is more stable (Z = magic number), so Nickel-65 is likely radioactive. So the radioactive isotopes are \({ }_{19}^{40}\mathrm{K}\), \({ }^{208}\mathrm{Bi}\), and Nickel-65.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Radioactive Isotopes
Radioactive isotopes, also known as radioisotopes, are atoms that emit radiation as they decay into a more stable form. Unlike stable isotopes, radioactive isotopes have an imbalance in the number of protons and neutrons that makes them unstable. This radioactivity often stems from having too many protons, too many neutrons, or a mix of both, which disrupts the energy balance within the nucleus.
The stability of isotopes greatly depends on how their nucleus is composed and how well it can resist decay.
  • Radioactive isotopes decay over time, emitting energy in the form of radiation, such as alpha, beta, or gamma rays.
  • The process by which they decay is random but quantifiable in terms of half-life, the time it takes for half of the radioactive atoms in a sample to decay.
  • Isotopes that are closer to having equal numbers of protons and neutrons tend to be more stable.
When assessing whether an isotope might be radioactive, scientists often compare the neutron-to-proton ratio and consult known magic numbers, which reflect particularly stable configurations.
Magic Numbers
Magic numbers are key ingredients for understanding nuclear stability. They refer to specific numbers of protons or neutrons in the nucleus that are arranged in a complete or closed shell within the atomic nucleus. These numbers lead to greater stability in the atom and thus make it less likely to be radioactive.
Magic numbers are based on a model similar to electron shells in atoms, but rather they apply to the nucleons in the nucleus, which are the protons and neutrons.
Understanding magic numbers can help predict nuclear stability:
  • Common magic numbers for protons and neutrons include 2, 8, 20, 28, 50, 82, and 126.
  • Magical configurations arise due to the full occupancy of nuclear energy levels, similar to how noble gases reflect full electron shells and increased stability.
  • An isotope close to possessing these magic numbers will exhibit heightened stability relative to others not near magic numbers.
The insight given by magic numbers aids scientists in predicting which isotopes are more likely to be stable or radioactive, based on its nuclear configuration.
Protons and Neutrons
Protons and neutrons are the fundamental building blocks of atomic nuclei. Together, they are known as nucleons. The balance between these nucleons greatly determines the nuclear stability of isotopes.
Protons carry a positive charge, while neutrons are neutral. This distinction plays a significant role in the forces within the nucleus:
  • Protons, being positively charged, repel each other due to the electromagnetic force.
  • Neutrons contribute to the strong nuclear force, which helps to bind the nucleus together, offsetting the repulsion between protons.
  • In balancing these forces, a stable nucleus commonly has nearly equal numbers of protons and neutrons, especially in lighter elements.
The relative numbers of protons and neutrons act like a delicate scale.
When this balance tips too far toward excess protons or neutrons, instability and radioactivity may occur. Observing this balance, along with magic numbers, allows scientists to deduce nuclear stability.

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Most popular questions from this chapter

How much time is required for a \(6.25-\mathrm{mg}\) sample of \({ }^{51} \mathrm{Cr}\) to decay to \(0.75 \mathrm{mg}\) if it has a half-life of \(27.8\) days?

The energy from solar radiation falling on Earth is \(1.07 \times 10^{16} \mathrm{~kJ} / \mathrm{min}\). (a) How much loss of mass from the Sun occurs in one day from just the encrgy falling on Farth? (b) If the energy released in the reaction $$ { }^{235} \mathrm{U}+{ }_{0}^{1} \mathrm{n} \longrightarrow{ }_{56}^{141} \mathrm{Ba}+{ }_{36}^{92} \mathrm{Kr}+3{ }_{0}^{1} \mathrm{n} $$ \(\left({ }^{235} \mathrm{U}\right.\) nuclear mass, \(234.9935 \mathrm{amu} ;{ }^{141} \mathrm{Ba}\) nuclear mass, \(140.8833 \mathrm{amu} ;{ }^{92} \mathrm{Kr}\) nuclear mass, 91.9021 amu) is taken as typical of that occurring in a nuclear reactor, what mass of uranium-235 is required to equal \(0.10 \%\) of the solar energy that falls on Earth in \(1.0\) day?

When two protons fuse in a star, the product is \({ }^{2} \mathrm{H}\) plus a positron (Equation 21.26). Why do you think the more obvious product of the reaction, \({ }^{2} \mathrm{He}\) is unstable?

(a) Which of the following statements about the uranium used in nuclear reactors is or are true? (i) Natural uranium has too little \({ }^{295} \mathrm{U}\) to be used as a fuel. (ii) \({ }^{24} \mathrm{U}\) cannot be used as a fucl because it forms a supereritical mass too casily. (iii) To be used as fuel, uranium must be enriched so that it is more than \(50 \%{ }^{2.35} \mathrm{U}\) in composition. (iv) The neutron-induced fission of \({ }^{235} \mathrm{U}\) releases more neutrons per nucleus than fission of \({ }^{2.85} \mathrm{U}\). (b) Which of the following statements about the plutonium shown in the chapter-opening photograph explains why it cannot be used for nuclear power plants or nuclear weapons? (i) None of the isotopes of Pu possess the characteristics needed to support nuclear fission chain reactions. (ii) The orange glow indicates that the only radioactive decay products are heat and visible light. (iii) The particular isotope of plutonium used for RTGs is incapable of sustaining a chain reaction. (iv) Plutonium can be used as a fuel, but only atter it decays to uranium.

The naturally occurring radioactive decay series that begins with \({ }_{92}^{235} \mathrm{U}\) stops with formation of the stable \({ }_{82}^{207} \mathrm{~Pb}\) nucleus. The decays proceed through a series of alpha-particle and beta-particle emissions. How many of each type of emission are involved in this series?

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