Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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(a) What is groundwater? (b) What is an aquifer?
An important reaction in the formation of photochemical smog is the photodissociation of \(\mathrm{NO}_{2}\) = $$ \mathrm{NO}_{2}+h w \longrightarrow \mathrm{NO}(g)+\mathrm{O}(g) $$ The maximum wavelength of light that can cause this reaction is \(420 \mathrm{~nm}\). (a) In what part of the electromagnetic spectrum is light with this wavelength found? (b) What is the maximum strength of a bond, in kJ/mol, that can be broken by absorption of a photon of 420 -nm light? (c) Write out the photodissociation reaction showing Lewis-dot structures.
(a) Why is the fluorine present in chlorofluorocarbons not a major contributor to depletion of the ozone layer? (b) What are the chemical forms in which chlorine exists in the stratesphere following cleavage of the carbon-chlorine bond?
For each of the following gases, make a list of known or possible naturally occurring sources: (a) \(\mathrm{CH}_{4}\) (b) \(\mathrm{SO}_{2}\), (c) \(\mathrm{NO}\).
Do the reactions involved in ozone depletion involve changes in oxidation state of the \(\mathrm{O}\) atoms? Explain.
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