Chapter 13: Problem 35
(a) Explain why carbonated beverages must be stored in sealed containers. (b) Once the beverage has been opened, why does it maintain more carbonation when refrigerated than at room temperature?
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Chapter 13: Problem 35
(a) Explain why carbonated beverages must be stored in sealed containers. (b) Once the beverage has been opened, why does it maintain more carbonation when refrigerated than at room temperature?
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By referring to Figure 13.15, determine the mass of each of the following salts required to form a saturated solution in \(250 \mathrm{~g}\) of water at \(30^{\circ} \mathrm{C}\) : (a) \(\mathrm{KClO}_{3}\), (b) \(\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}\), (c) \(\mathrm{Ce}_{2}\left(\mathrm{SO}_{4}\right)_{3}\).
At ordinary body temperature \(\left(37^{\circ} \mathrm{C}\right)\), the solubility of \(\mathrm{N}_{2}\) in water at ordinary atmospheric pressure ( \(1.0 \mathrm{~atm})\) is \(0.015 \mathrm{~g} / \mathrm{L}\). Air is approximately \(78 \mathrm{~mol} \% \mathrm{~N}_{2}\). (a) Calculate the number of moles of \(\mathrm{N}_{2}\) dissolved per liter of blood, assuming blood is a simple aqueous solution. (b) At a depth of \(100 \mathrm{ft}\) in water, the external pressure is \(4.0 \mathrm{~atm}\). What is the solubility of \(\mathrm{N}_{2}\) from air in blood at this pressure? (c) If a scuba diver suddenly surfaces from this depth, how many milliliters of \(\mathrm{N}_{2}\) gas, in the form of tiny bubbles, are released into the bloodstream from each liter of blood?
An ionic compound has a very negative \(\Delta H_{\text {soln }}\) in water. (a) Would you expect it to be very soluble or nearly insoluble in water? (b) Which term would you expect to be the largest negative number: \(\Delta H_{\text {solvent }} \Delta H_{\text {solute }}\) or \(\Delta H_{\text {mix }}\) ?
Describe how you would prepare each of the following aqueous solutions: (a) \(1.50 \mathrm{~L}\) of \(0.110 \mathrm{M}\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\) solution, starting with solid \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\); (b) \(225 \mathrm{~g}\) of a solution that is \(0.65 \mathrm{~m}\) in \(\mathrm{Na}_{2} \mathrm{CO}_{3}\), starting with the solid solute; (c) \(1.20 \mathrm{~L}\) of a solution that is \(15.0 \% \mathrm{~Pb}\left(\mathrm{NO}_{3}\right)_{2}\) by mass (the density of the solution is \(1.16 \mathrm{~g} / \mathrm{mL}\) ), starting with solid solute; (d) a \(0.50 \mathrm{M}\) solution of \(\mathrm{HCl}\) that would just neutralize \(5.5 \mathrm{~g}\) of \(\mathrm{Ba}(\mathrm{OH})_{2}\) starting with \(6.0 \mathrm{M} \mathrm{HCl}\)
A solution is made containing \(20.8 \mathrm{~g}\) of phenol \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}\right)\) in \(425 \mathrm{~g}\) of ethanol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\right)\). Calculate (a) the mole fraction of phenol, (b) the mass percent of phenol, (c) the molality of phenol.
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