Chapter 12: Problem 66
Which of the following properties are typical characteristics of a covalent- network solid, a metallic solid, or both: (a) ductility, (b) hardness, (c) high melting point?
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Chapter 12: Problem 66
Which of the following properties are typical characteristics of a covalent- network solid, a metallic solid, or both: (a) ductility, (b) hardness, (c) high melting point?
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Amorphous silica, \(\mathrm{SiO}_{2}\), has a density of about \(2.2 \mathrm{~g} / \mathrm{cm}^{3}\), whereas the density of crystalline quartz, another form of \(\mathrm{SiO}_{2}\), is \(2.65 \mathrm{~g} / \mathrm{cm}^{3}\). Which of the following statements is the best explanation for the difference in density? (a) Amorphous silica is a network-covalent solid, but quartz is metallic. (b) Amorphous silica crystallizes in a primitive cubic lattice. (c) Quartz is harder than amorphous silica. (d) Quartz must have a larger unit cell than amorphous silica. (e) The atoms in amorphous silica do not pack as efficiently in three dimensions as compared to the atoms in quartz
The densities of the elements \(\mathrm{K}, \mathrm{Ca}, \mathrm{Sc}\), and \(\mathrm{Ti}\) are \(0.86,1.5,3.2\), and \(4.5 \mathrm{~g} / \mathrm{cm}^{3}\), respectively. One of these elements crystallizes in a body-centered cubic structure; the other three crystallize in a face-centered cubic structure. Which one crystallizes in the body-centered cubic structure? Justify your answer.
Classify each of the following statements as true or false: (a) For molecular solids, the melting point generally increases as the strengths of the covalent bonds increase. (b) For molecular solids, the melting point generally increases as the strengths of the intermolecular forces increase.
When you shine light of band gap energy or higher on a semiconductor and promote electrons from the valence band to the conduction band, do you expect the conductivity of the semiconductor to (a) remain unchanged, (b) increase, or (c) decrease?
Explain why \(\mathrm{X}\) rays can be used to measure atomic distances in crystals but visible light cannot be used for this purpose.
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