Chapter 15: Problem 9
Why do we omit the concentrations of solids and liquids from equilibrium expressions?
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Chapter 15: Problem 9
Why do we omit the concentrations of solids and liquids from equilibrium expressions?
These are the key concepts you need to understand to accurately answer the question.
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Consider the reaction: A solution is made containing an initial [Fe3+] of 1.0 * 10-3 M and an initial [SCN-] of 8.0 * 10-4 M. At equilibrium, [FeSCN2+] = 1.7 * 10-4 M. Calculate the value of the equilibrium constant (Kc).
Consider the reaction: N2(g) + 3 H2(g)->2 NH3(g). a. Write the equilibrium constant expression for this reaction. If some hydrogen is added, before the reaction shifts: b. How will the numerator and denominator of the expression in part a compare to the value at equilibrium? c. Will Q be larger or smaller than K? Why? d. Will the reaction have to shift forward or backward to retain equilibrium? Explain. e. Are your answers for b-d consistent with Le Chatelier"s principle? Explain.
Write an equilibrium expression for each chemical equation involving one or more solid or liquid reactants or products. a. CO3 2-(aq) + H2O(I)HCO3 -(aq) + OH-(aq) b. 2 KCIO3(s)2 KCI(s) + 3 O2(g) c. HF(aq) + H2O(I)H3O+(aq) + F-(aq) d. NH3(aq) + H2O(I)NH4 +(aq) + OH-(aq)
Does the value of the equilibrium constant depend on the initial concentrations of the reactants and products? Do the equilibrium concentrations of the reactants and products depend on their initial concentrations? Explain.
If two reactions sum to an overall reaction, and the equilibrium constants for the two reactions are K1 and K2 what is the equilibrium constant for the overall reaction?
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