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Explain the difference between the rate law for a reaction and the in- tegrated rate law for a reaction. What relationship does each kind of rate law express?

Short Answer

Expert verified
The rate law expresses the relationship between the reaction rate and the concentrations of reactants at a specific moment, while the integrated rate law shows the relationship between the concentrations of reactants or products and time throughout the course of the reaction.

Step by step solution

01

Understanding Rate Law

The rate law for a chemical reaction is an equation that links the reaction rate with the concentrations of reactants. It is usually expressed in the form: rate = k[A]^m[B]^n, where k is the rate constant, [A] and [B] are the molar concentrations of reactants A and B, and m and n are the reaction orders with respect to A and B respectively. This law shows how the rate of reaction depends on the concentration of the reactants.
02

Understanding Integrated Rate Law

The integrated rate law is derived from the rate law and gives the concentration of reactants or products over time. Unlike the rate law which shows the rate at a specific instance, the integrated rate law considers the overall progression of the reaction. It can take several forms depending on the order of the reaction, such as first-order, second-order, etc., and it allows us to calculate the concentrations of reactants or products at any given time.
03

Relating Rate Law and Integrated Rate Law

The rate law and integrated rate law are closely connected. The rate law gives instant information about the rate of reaction, while the integrated rate law uses that information to provide a broader picture over the course of time. To put it simply, the rate law is a snapshot, and the integrated rate law is the entire movie. The integrated rate law is obtained by integrating the rate law with respect to time.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Kinetics
Chemical kinetics is a branch of chemistry that studies the rates of chemical reactions and the mechanisms by which they occur. It's essential to understand how various factors like temperature, pressure, concentration, and the presence of catalysts affect the speed of a reaction. In the context of chemical kinetics, we often use the rate law and integrated rate law to describe and predict the rate and progression of chemical reactions.

Through the analysis of these laws, we can optimize conditions to increase the efficiency of reactions, which is crucial in fields ranging from industrial manufacturing to pharmaceuticals. Furthermore, the study of kinetics helps chemists to unravel the steps (mechanism) leading from reactants to products, thus providing deeper insight into the fundamental nature of chemical transformations.
Reaction Rate
The reaction rate is the speed at which a chemical reaction proceeds. It is typically expressed in terms of the change in concentration of a reactant or product per unit time. For instance, you might measure how quickly a reactant is consumed or how rapidly a product is formed. Factors like reactant concentration, surface area, temperature, and the presence of a catalyst can significantly influence the reaction rate.

To quantify the reaction rate, we examine the rate at which the reactants are converted into products. It's the initial glimpse into a reaction's dynamics and can be directly observed in a laboratory setting through experiments designed to monitor changes in reactants or products over time.
Rate Constant
The rate constant, represented by the symbol 'k', is a proportionality factor that features in the rate law of a chemical reaction. It's a measure of the intrinsic reactivity of the reaction and is independent of the concentration of the reactants. However, k does depend on the temperature of the reaction and, in some cases, pressure.

Every chemical reaction has its unique rate constant that can only be altered by changing the reaction conditions. The rate constant links the reaction rate to the concentrations of the reactants raised to their respective powers, which corresponds to the reaction order. It's crucial for predicting how quickly a reaction will occur under specified conditions and for determining the effect of temperature changes on the reaction rate.
Reaction Order
Reaction order is a term in kinetics that describes the power to which the concentration of a reactant is raised in the rate law equation. It provides insight into the relationship between the concentration of reactants and the reaction rate. The overall order of a reaction is the sum of the orders with respect to each reactant as seen in the rate law, for example, if the rate law is rate = k[A]^m[B]^n, then the overall order is m + n.

Reaction orders are not always integers and can't be inferred from the chemical equation alone; they must be determined experimentally. Understanding the order is vital because it affects the form of the integrated rate law and helps chemists understand how various species are involved in the rate-determining step of the reaction.
Concentration-Time Relationship
The concentration-time relationship in chemical kinetics links the change in the concentration of reactants or products with time. It's revealed by the integrated rate law, which describes how concentrations vary as the reaction proceeds. This relationship is crucial for predicting the amount of reactants and products at any given point and is used to design chemical processes where timing is critical.

The shape of the concentration vs. time curve can indicate the order of the reaction. For example, a straight line suggests a first-order reaction, while a curve that becomes less steep over time may suggest a second-order reaction. By analyzing how the concentration of reactants decreases with time or how the products increase, scientists can make informed decisions about the conditions necessary to carry out a reaction to its completion.

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Most popular questions from this chapter

The previous exercise shows how the first-order integrated rate law is derived from the first-order differential rate law. Begin with the sec- ond-order differential rate law and derive the second-order integrated rate law.

\(\begin{aligned} \text { Consider the reaction. } \\ & 2 \mathrm{N}_{2} \mathrm{O}(g) \longrightarrow 2 \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g) \end{aligned}\) \begin{equation} \begin{array}{l}{\text { a. Express the rate of the reaction in terms of the change in }} \\ {\text { concentration of each of the reactants and products. }} \\ {\text { b. In the first } 15.0 \text { s of the reaction, 0.015 mol of } \mathrm{O}_{2} \text { is produced in a }} \\ {\text { reaction vessel with a volume of } 0.500 \text { L. What is the average rate }} \\ {\text { of the reaction during this time interval? }}\end{array} \end{equation} \begin{equation} \begin{array}{l}{\text { c. Predict the rate of change in the concentration of } \mathrm{N}_{2} \mathrm{O} \text { during this }} \\ {\text { time interval. In other words, what is } \Delta\left[\mathrm{N}_{2} \mathrm{O}\right] / \Delta t?}\end{array} \end{equation}

Geologists can estimate the age of rocks by their uranium- \(238 \mathrm{con}-\) tent. The uranium is incorporated in the rock as it hardens and then decays with first-order kinetics and a half-life of 4.5 billion years. A rock contains 83.2\(\%\) of the amount of uranium-238 that it contained when it was formed. (The amount that the rock contained when it was formed can be deduced from the presence of the decay products of \(U-238 . )\) How old is the rock?

The first-order integrated rate law for a reaction \(\mathrm{A} \longrightarrow\) products is derived from the rate law using calculus. \begin{equation} \begin{aligned} \text { Rate } &=k[\mathrm{A}] \quad \text { (first-order rate law) } \\ \text { Rate } &=\frac{d[\mathrm{A}]}{d t} \\\ \frac{d[\mathrm{A}]}{d t} &=-k[\mathrm{A}] \end{aligned} \end{equation} The equation just given is a first-order, separable differential equa- tion that can be solved by separating the variables and integrating: \begin{equation} \begin{aligned} \frac{d[\mathrm{A}]}{[\mathrm{A}]} &=-k d t \\\ \int_{[\mathrm{A}]_{0}}^{[\mathrm{A]}} \frac{d[\mathrm{A}]}{[\mathrm{A}]} &=-\int_{0}^{t} k d t \end{aligned} \end{equation} In the integral just given, \([\mathrm{A}]_{0}\) is the initial concentration of \(\mathrm{A} . \mathrm{We}\) then evaluate the integral: \begin{equation} \begin{aligned}[\ln [\mathrm{A}]]_{[\mathrm{A}]_{0}}^{[\mathrm{Al}} &=-k[t]_{0}^{t} \\ \ln [\mathrm{A}]-\ln [\mathrm{A}]_{0} &=-k t \end{aligned} \end{equation} \begin{equation} \ln [\mathrm{A}]=-k t+\ln [\mathrm{A}]_{0}(\text { integrated rate law }) \end{equation} \begin{equation} \begin{array}{l}{\text { a. Use a procedure similar to the one just shown to derive an inte- }} \\ {\text { grated rate law for a reaction } A \longrightarrow \text { products, which is one-half- }} \\ {\text { order in the concentration of } A \text { (that is, Rate }=k[A]^{1 / 2} )}\end{array} \end{equation} \begin{equation} \begin{array}{l}{\text { b. Use the result from part a to derive an expression for the half-life }} \\ {\text { of a one-half-order reaction. }}\end{array} \end{equation}

Write integrated rate laws for zero-order, first-order, and second-order reactions of the form \(A \longrightarrow\) products.

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