Chapter 5: Problem 127
Write the formulas for the following compounds. (a) cobalt (III) nitrate (b) iron(III) sulfate (c) gold (III) chloride (d) manganese (IV) oxide (e) tungsten (VI) chloride
Short Answer
Expert verified
(a) Co(NO鈧)鈧 (b) Fe鈧(SO鈧)鈧 (c) AuCl鈧 (d) MnO鈧 (e) WCl鈧
Step by step solution
01
Cobalt (III) Nitrate
Cobalt in the (III) oxidation state has a charge of +3, so it is represented as Co鲁鈦. Nitrate is a polyatomic ion with a formula of NO鈧冣伝. To balance the charges, we need three NO鈧冣伝 ions for one Co鲁鈦 ion. Thus, the formula is Co(NO鈧)鈧.
02
Iron (III) Sulfate
Iron in the (III) oxidation state is Fe鲁鈦. Sulfate is a polyatomic ion with the formula SO鈧劼测伝. To balance the charges, two Fe鲁鈦 ions will pair with three SO鈧劼测伝 ions, resulting in the formula Fe鈧(SO鈧)鈧.
03
Gold (III) Chloride
Gold in the (III) oxidation state is Au鲁鈦. Chloride ions are Cl鈦. To balance the charges, three Cl鈦 ions are needed for one Au鲁鈦 ion. Therefore, the formula is AuCl鈧.
04
Manganese (IV) Oxide
Manganese in the (IV) oxidation state is Mn鈦粹伜. Oxide ions are O虏鈦. To balance the charges, two O虏鈦 ions will balance the charge of one Mn鈦粹伜. Therefore, the formula is MnO鈧.
05
Tungsten (VI) Chloride
Tungsten in the (VI) oxidation state is W鈦垛伜. Chloride ions are Cl鈦. To balance the charges, six Cl鈦 ions are needed for one W鈦垛伜 ion. Thus, the formula is WCl鈧.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation States
Oxidation states, often referred to as oxidation numbers, play a crucial role in understanding how atoms interact in chemical compounds. They indicate the degree of oxidation of an atom within a compound. In simpler terms, an oxidation state represents the charge an atom would have if all bonds were ionic.
When you see a Roman numeral in the name of a compound, it tells you the oxidation state of the transition metal involved. For example, in cobalt (III) nitrate and gold (III) chloride, the Roman numeral III signifies an oxidation state of +3. This means cobalt and gold are each donating three electrons or getting three electrons pulled away in an ionic bond.
When you see a Roman numeral in the name of a compound, it tells you the oxidation state of the transition metal involved. For example, in cobalt (III) nitrate and gold (III) chloride, the Roman numeral III signifies an oxidation state of +3. This means cobalt and gold are each donating three electrons or getting three electrons pulled away in an ionic bond.
- This allows us to understand what kind of chemical behavior to expect from these elements when they form compounds.
- Determining the oxidation state helps in predicting reaction products and balancing chemical equations.
Polyatomic Ions
Polyatomic ions are ions that consist of two or more atoms bonded together, carrying a net positive or negative charge. These ions function as a single unit in chemical reactions.
Common polyatomic ions such as nitrate ( ext{NO}_3^-), sulfate ( ext{SO}_4^{2-}), and phosphate ( ext{PO}_4^{3-}) are frequently encountered in chemical formulas. They have specific names, formulas, and charges that need to be memorized or referenced when writing chemical equations.
Common polyatomic ions such as nitrate ( ext{NO}_3^-), sulfate ( ext{SO}_4^{2-}), and phosphate ( ext{PO}_4^{3-}) are frequently encountered in chemical formulas. They have specific names, formulas, and charges that need to be memorized or referenced when writing chemical equations.
- These ions maintain their structure and charge even when they undergo chemical reactions.
- For writing chemical formulas, knowing the charge is crucial for balancing with other ions.
Balancing Charges
Balancing charges in chemical formulas is essential to achieving electrically neutral compounds. This process often involves pairing positively charged cations with negatively charged anions to nullify their charges when forming compounds.
For example, nitrate ( ext{NO}_3^-) has a -1 charge, so when paired with cobalt in the +3 oxidation state ( ext{Co}^{3+}), three ext{NO}_3^- ions are needed to balance the single ext{Co}^{3+} cation, resulting in the compound ext{Co(NO}_3 ext{)}_3.
For example, nitrate ( ext{NO}_3^-) has a -1 charge, so when paired with cobalt in the +3 oxidation state ( ext{Co}^{3+}), three ext{NO}_3^- ions are needed to balance the single ext{Co}^{3+} cation, resulting in the compound ext{Co(NO}_3 ext{)}_3.
- The aim is always to have the sum of the positive charges equal the sum of the negative charges.
- Each compound must be electrically neutral when complete.
Transition Metals
Transition metals are known for their ability to form compounds with a wide range of oxidation states. Elements like iron (Fe), copper (Cu), and cobalt (Co) are situated in the center block of the periodic table and are categorized as transition metals.
These metals can form complex ions and compounds because their d electrons can participate in bonding. This versatility allows transition metals to exhibit a variety of colors and have significant magnetic and conductive properties.
These metals can form complex ions and compounds because their d electrons can participate in bonding. This versatility allows transition metals to exhibit a variety of colors and have significant magnetic and conductive properties.
- The varying oxidation states allow them to form numerous types of compounds.
- They often form colorful compounds and are used widely in catalysts.