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Calculate the molar mass of a gaseous element if 0.480 \(\mathrm{g}\) of the gas occupies \(367 \mathrm{~mL}\) at 365 torr and \(45^{\circ} \mathrm{C}\). Suggest the identity of the element.

Short Answer

Expert verified
The molar mass is approximately 70.28 g/mol, likely identifying the element as germanium (Ge).

Step by step solution

01

Convert Units

First, convert the given units into the standard units used in gas calculations. Convert the volume from milliliters to liters by knowing that 1 L = 1000 mL. Thus, \(367 \text{ mL} = 0.367 \text{ L}\). Convert pressure from torr to atm using the conversion \(1 \text{ atm} = 760 \text{ torr}\), so \(365 \text{ torr} = \frac{365}{760} \text{ atm} \approx 0.480 \text{ atm}\). Temperature in Celsius is converted to Kelvin by adding 273.15: \(45^{\circ} \text{C} = 45 + 273.15 = 318.15 \text{ K}\).
02

Apply the Ideal Gas Law

Use the Ideal Gas Law \(PV = nRT\) to find the number of moles of the gas \(n\). Plug in the known values: \(P = 0.480 \text{ atm}\), \(V = 0.367 \text{ L}\), \(R = 0.0821 \text{ L atm/mol K}\), and \(T = 318.15 \text{ K}\). Solve for \(n\): \(n = \frac{PV}{RT} = \frac{0.480 \times 0.367}{0.0821 \times 318.15} \approx 0.00683 \text{ moles}\).
03

Calculate Molar Mass

With the number of moles known, calculate molar mass by dividing the given mass by the number of moles: Molar Mass \(= \frac{\text{mass}}{n} = \frac{0.480 \text{ g}}{0.00683 \text{ moles}} \approx 70.28 \text{ g/mol}\).
04

Identify the Element

Compare the calculated molar mass to known values of gaseous elements. The molar mass approximates 70.91 g/mol, which corresponds to the element germanium (Ge) in gaseous form.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and amount of gas. The law is expressed in the formula \(PV = nRT\), where:
  • \(P\) stands for pressure.
  • \(V\) is the volume the gas occupies.
  • \(n\) represents the amount of substance in moles.
  • \(R\) is the ideal gas constant and is approximately equal to 0.0821 L atm/mol K.
  • \(T\) signifies the temperature, which must be measured in Kelvin.
To effectively use this equation, you need the gas's pressure, volume, and temperature in the right units. By manipulating the formula, you can solve for any one of the variables provided you have the others. In our example, we derived the number of moles \(n\) using the other parameters. This is a useful approach when trying to determine an unknown quantity of gas in a problem.
Unit Conversion
Unit conversion is crucial for solving problems related to gases. Since the Ideal Gas Law requires specific units, it's often necessary to convert measurements before calculations.
  • Volume should be in liters, which can be converted from milliliters (1 L = 1000 mL).
  • Pressure should be in atmospheres, which can be converted from torr using the relation 1 atm = 760 torr.
  • Temperature must be in Kelvin, converted from Celsius by adding 273.15 to the Celsius temperature.
Let's discuss the given problem. We started with a volume of 367 mL, which was converted to 0.367 L. Similarly, a pressure of 365 torr was converted to approximately 0.480 atm. Finally, a temperature of 45°C was converted to 318.15 K. These conversions are vital for the application of the Ideal Gas Law.
Molar Mass
Molar mass is the weight of one mole of a substance, usually expressed in grams per mole (g/mol). It's an important concept in chemistry that links the mass of a substance to its amount in moles. In our exercise, calculating the molar mass involved dividing the known mass of gas by the number of moles.Here's the step-by-step approach:
  • Find the number of moles using the Ideal Gas Law, which we calculated to be approximately 0.00683 moles.
  • Divide the mass of the gas (0.480 g) by the number of moles to find molar mass: \( \frac{0.480 \text{ g}}{0.00683 \text{ moles}} \approx 70.28 \text{ g/mol} \).
This value is a stepping stone toward identifying unknown substances, as specific elements and compounds have characteristic molar masses. In this problem, our calculated molar mass closely matched that of germanium.
Gaseous Elements
Gaseous elements are those which exist in the gaseous state under standard conditions. In this exercise, once we determined the molar mass, the next step was to identify the gaseous element. Several tools and data tables list the molar masses of elements, which can be cross-referenced with calculated values to hypothesize an element's identity. Given our approximate molar mass of 70.28 g/mol, we matched it with germanium, which has a molar mass close to our calculated value. While many gases like oxygen and nitrogen are familiar, it's crucial to remember that certain elements can transition into gaseous states and have unique molar masses that distinguish them. Knowing their properties and molar masses is fundamental in solving these types of problems effectively.

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Most popular questions from this chapter

Hydrogen gas is frequently prepared in the laboratory by the reaction of zinc metal with sulfuric acid, \(\mathrm{H}_{2} \mathrm{SO}_{4}\). The other product of the reaction is zinc(II) sulfate. The hydrogen gas is generally collected over water. What volume of pure \(\mathrm{H}_{2}\) gas is produced by the reaction of \(0.113 \mathrm{~g}\) zinc metal and excess sulfuric acid if the temperature is 24 \({ }^{\circ} \mathrm{C}\) and the barometric pressure is 750 torr?

Natural gas has been stored in an expandable tank that keeps a constant pressure as gas is added or removed. The tank has a volume of \(4.50 \times 10^{4} \mathrm{ft}^{3}\) when it contains 77.4 million mol natural gas at \(-5^{\circ} \mathrm{C}\). What is the new volume of the tank if consumers use up 5.3 million mol and the temperature increases to \(7^{\circ} \mathrm{C} ?\)

A sample of gas at 1.02 atm of pressure and \(39^{\circ} \mathrm{C}\) is heated to \(499^{\circ} \mathrm{C}\) at constant volume. What is the new pressure in atmospheres?

A Calculate (a) the rms speed (in \(\mathrm{m} / \mathrm{s}\) ) of samples of hydrogen and nitrogen at STP; and (b) the average kinetic energies per molecule (in \(\mathrm{kg} \mathrm{m}^{2} / \mathrm{s}^{2}\) ) of the two gases under these conditions.

A sample of gas occupies \(135 \mathrm{~mL}\) at \(22.5^{\circ} \mathrm{C} ;\) the pressure is 165 torr. What is the pressure of the gas sample when it is placed in a \(252-\mathrm{mL}\) flask at a temperature of \(0.0^{\circ} \mathrm{C} ?\)

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