Chapter 2: Problem 126
Write the formula of each of the following compounds, and indicate whether each is ionic or molecular. (a) calcium phosphate (b) germanium dioxide (c) iron(III) sulfate (d) phosphorus tribromide
Short Answer
Expert verified
(a) Ca鈧(PO鈧)鈧 (ionic), (b) GeO鈧 (molecular), (c) Fe鈧(SO鈧)鈧 (ionic), (d) PBr鈧 (molecular).
Step by step solution
01
Identify the Elements and their Types
To determine whether a compound is ionic or molecular, first identify the elements involved. Ionic compounds typically consist of metals and non-metals, while molecular compounds are formed between non-metals. In this exercise:
(a) Calcium phosphate involves calcium (a metal) and phosphate (a polyatomic ion).
(b) Germanium dioxide involves germanium (a metalloid) and oxygen (a non-metal).
(c) Iron(III) sulfate involves iron (a metal) and sulfate (a polyatomic ion).
(d) Phosphorus tribromide involves phosphorus (a non-metal) and bromine (a non-metal).
02
Determine the Compound Type
Based on the element types, we classify the compounds:
(a) Calcium phosphate: Ionic, because it contains a metal (calcium).
(b) Germanium dioxide: Molecular, as it is between a metalloid and a non-metal.
(c) Iron(III) sulfate: Ionic, because it contains a metal (iron).
(d) Phosphorus tribromide: Molecular, since it is between two non-metals.
03
Write the Chemical Formulas
Determine the chemical formulas for each compound:
(a) Calcium phosphate: Calcium has a charge of +2 and phosphate (PO鈧) has a charge of -3. The formula is determined by balancing these charges, resulting in Ca鈧(PO鈧)鈧.
(b) Germanium dioxide: Germanium typically forms +4 ions and oxygen forms -2 ions. Therefore, the formula is GeO鈧.
(c) Iron(III) sulfate: Iron(III) indicates Fe鲁鈦 ions, and sulfate (SO鈧) has a charge of -2. Balancing these charges gives Fe鈧(SO鈧)鈧.
(d) Phosphorus tribromide: The naming indicates one phosphorus and three bromine atoms, resulting in the formula PBr鈧.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Compounds
Ionic compounds are formed when metals and non-metals bond together. In these compounds, electrons are transferred from one atom to another, creating electrically charged ions. This transfer of electrons leads to the formation of positively charged cations, typically from metals, and negatively charged anions, usually from non-metals. The electrostatic attraction between these oppositely charged ions results in the formation of a solid lattice structure.
For example, in the compound calcium phosphate, calcium (Ca) acts as a metal giving up electrons, and phosphate acts as a polyatomic ion accepting those electrons. The resulting formula of calcium phosphate is Ca鈧(PO鈧)鈧, with calcium ions carrying a +2 charge and phosphate ions a -3 charge. Charge balancing ensures the entire compound is neutral.
For example, in the compound calcium phosphate, calcium (Ca) acts as a metal giving up electrons, and phosphate acts as a polyatomic ion accepting those electrons. The resulting formula of calcium phosphate is Ca鈧(PO鈧)鈧, with calcium ions carrying a +2 charge and phosphate ions a -3 charge. Charge balancing ensures the entire compound is neutral.
Molecular Compounds
Molecular compounds, also known as covalent compounds, are formed between non-metals. These compounds result from the sharing of electrons rather than the transfer, which means there are no ions present. This sharing allows each atom to achieve a noble gas-like electron configuration. Due to this sharing mechanism, molecular compounds often exist as discrete molecules rather than extensive networks.
Take germanium dioxide as an example: it consists of germanium (a metalloid) and oxygen (a non-metal). They share electrons to achieve stability, leading to the formula GeO鈧. Each germanium atom shares electrons with two oxygen atoms to fulfill the electron requirements.
Take germanium dioxide as an example: it consists of germanium (a metalloid) and oxygen (a non-metal). They share electrons to achieve stability, leading to the formula GeO鈧. Each germanium atom shares electrons with two oxygen atoms to fulfill the electron requirements.
Polyatomic Ions
Polyatomic ions are groups of atoms that are covalently bonded together, but that collectively carry a charge. These ions function as discrete units when participating in ionic compounds.
Common examples of polyatomic ions include sulfate (SO鈧劼测伝), phosphate (PO鈧劼斥伝), and nitrate (NO鈧冣伝). Each of these ions behaves as a single charged entity in a chemical reaction.
A real-world example involves iron(III) sulfate, where the sulfate ion (SO鈧劼测伝) pairs with iron to form the compound. Here, each sulfate ion acts as a single unit as it bonds with metals to neutralize charge, leading to the compound formula Fe鈧(SO鈧)鈧.
Charge Balancing
Charge balancing is a key concept in determining the correct formula for ionic compounds. It involves ensuring that the total positive charge from cations equals the total negative charge from anions, resulting in an overall neutral compound. This is necessary because compounds are generally electrically neutral.
When balancing charges, the simplest whole-number ratio of ions is used to achieve neutrality. This is evident in formulas like Ca鈧(PO鈧)鈧, where three calcium ions (Ca虏鈦) perfectly balance with two phosphate ions (PO鈧劼斥伝).
When balancing charges, the simplest whole-number ratio of ions is used to achieve neutrality. This is evident in formulas like Ca鈧(PO鈧)鈧, where three calcium ions (Ca虏鈦) perfectly balance with two phosphate ions (PO鈧劼斥伝).
- The calcium ions contribute a total charge of +6 (3 x +2).
- The phosphate ions contribute a total charge of -6 (2 x -3).