Chapter 15: Problem 4
Write two Br酶nsted-Lowry acid-base reactions and show how they represent proton-transfer reactions.
Short Answer
Expert verified
Reactions: HCl + H鈧侽 鈫 Cl鈦 + H鈧僌鈦 and NH鈧 + H鈧侽 鈫 NH鈧勨伜 + OH鈦, both showing proton transfer.
Step by step solution
01
Understand Br酶nsted-Lowry theory
In Br酶nsted-Lowry theory, an acid is a substance that donates a proton (H鈦) and a base is a substance that accepts a proton. These reactions can occur in aqueous solutions or in gas phases.
02
Choose the first acid-base reaction
Consider the reaction between hydrochloric acid (HCl) and water (H鈧侽). In this reaction, HCl is the Br酶nsted-Lowry acid and H鈧侽 is the base. HCl donates a proton to H鈧侽, forming hydronium ion (H鈧僌鈦) and chloride ion (Cl鈦).
03
Represent the first reaction as a proton-transfer
The reaction can be written as:
HCl + H鈧侽 鈫 Cl鈦 + H鈧僌鈦
Here, HCl donates a proton to H鈧侽, thereby acting as an acid, and H鈧侽 accepts the proton, acting as a base.
04
Choose the second acid-base reaction
Consider the reaction between ammonia (NH鈧) and water (H鈧侽). In this reaction, NH鈧 is the base and H鈧侽 is the acid. H鈧侽 donates a proton to NH鈧, forming ammonium ion (NH鈧勨伜) and hydroxide ion (OH鈦).
05
Represent the second reaction as a proton-transfer
The reaction can be written as:
NH鈧 + H鈧侽 鈫 NH鈧勨伜 + OH鈦
Here, H鈧侽 donates a proton to NH鈧, thereby acting as an acid, and NH鈧 accepts the proton, acting as a base.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Transfer
Proton transfer is an essential concept in many chemical reactions, and it's straightforward once you get the hang of it. Imagine a game of tag, where the proton (H鈦) is the person being tagged. The proton is passed from one molecule (the acid) to another (the base).
In Br酶nsted-Lowry acid-base reactions, the acid is always the one to donate the proton. In the reaction example between hydrochloric acid (HCl) and water (H鈧侽), HCl passes its proton to H鈧侽. This forms a hydronium ion (H鈧僌鈦), and the chloride ion (Cl鈦) is left behind.
In the second example involving ammonia (NH鈧) and water (H鈧侽), water is the donor. Water donates a proton to ammonia, creating ammonium (NH鈧勨伜) and hydroxide ions (OH鈦). These reactions demonstrate how a proton moves from one molecule to another, involving role-reversals depending on the molecules involved.
In Br酶nsted-Lowry acid-base reactions, the acid is always the one to donate the proton. In the reaction example between hydrochloric acid (HCl) and water (H鈧侽), HCl passes its proton to H鈧侽. This forms a hydronium ion (H鈧僌鈦), and the chloride ion (Cl鈦) is left behind.
In the second example involving ammonia (NH鈧) and water (H鈧侽), water is the donor. Water donates a proton to ammonia, creating ammonium (NH鈧勨伜) and hydroxide ions (OH鈦). These reactions demonstrate how a proton moves from one molecule to another, involving role-reversals depending on the molecules involved.
Chemical Reactions
Understanding chemical reactions is crucial for grasping how substances interact with each other. Reactions involve rearrangements of atoms and changes in the energy states of substances.
In any Br酶nsted-Lowry reaction, the key interaction is between the acid and the base. As protons are exchanged, this facilitates a connection between pairs of reactants and products. It's essential to write the equation that shows this interchange of protons.
Let's revisit the equations from our examples. For HCl and H鈧侽, the chemical reaction can be written as: \[ \text{HCl} + \text{H}_2\text{O} \rightarrow \text{Cl}^- + \text{H}_3\text{O}^+ \].
For NH鈧 and H鈧侽, the reaction appears as: \[ \text{NH}_3 + \text{H}_2\text{O} \rightarrow \text{NH}_4^+ + \text{OH}^- \]. Writing reactions this way clearly shows each component and how they transform.
In any Br酶nsted-Lowry reaction, the key interaction is between the acid and the base. As protons are exchanged, this facilitates a connection between pairs of reactants and products. It's essential to write the equation that shows this interchange of protons.
Let's revisit the equations from our examples. For HCl and H鈧侽, the chemical reaction can be written as: \[ \text{HCl} + \text{H}_2\text{O} \rightarrow \text{Cl}^- + \text{H}_3\text{O}^+ \].
For NH鈧 and H鈧侽, the reaction appears as: \[ \text{NH}_3 + \text{H}_2\text{O} \rightarrow \text{NH}_4^+ + \text{OH}^- \]. Writing reactions this way clearly shows each component and how they transform.
Acid-Base Theory
The Br酶nsted-Lowry Acid-Base Theory provides a foundation for understanding how acids and bases behave. It redefines acids and bases based on their ability to donate or accept protons, which offers a more versatile framework than older theories.
According to Br酶nsted-Lowry, an acid is a proton donor, and a base is a proton acceptor. This kind of interaction is significant not only in laboratory settings but also in biological systems and industrial processes.
For example, in our reactions, HCl and H鈧侽 act as the acid-base pair. Here, they showcase the dynamic nature of molecules depending on their reaction environment. Understanding this theory helps predict the outcome when different substances are mixed.
According to Br酶nsted-Lowry, an acid is a proton donor, and a base is a proton acceptor. This kind of interaction is significant not only in laboratory settings but also in biological systems and industrial processes.
For example, in our reactions, HCl and H鈧侽 act as the acid-base pair. Here, they showcase the dynamic nature of molecules depending on their reaction environment. Understanding this theory helps predict the outcome when different substances are mixed.
Aqueous Solutions
Many Br酶nsted-Lowry reactions take place in aqueous solutions, which contain substances dissolved in water. Water acts as both a solvent and a participant in many reactions, providing a medium for these interactions.
In our examples, water (H鈧侽) plays a pivotal role. It accepts a proton from HCl in the first example, forming a hydronium ion. In the second example, it donates a proton to NH鈧, forming an ammonium ion and a hydroxide ion.
The presence of water facilitates the flow of protons and underscores its critical role in chemistry as a versatile molecule. Understanding aqueous reactions is essential for working with solutions in chemistry, and it highlights water's unique dual capacity as an acid or a base in different contexts.
In our examples, water (H鈧侽) plays a pivotal role. It accepts a proton from HCl in the first example, forming a hydronium ion. In the second example, it donates a proton to NH鈧, forming an ammonium ion and a hydroxide ion.
The presence of water facilitates the flow of protons and underscores its critical role in chemistry as a versatile molecule. Understanding aqueous reactions is essential for working with solutions in chemistry, and it highlights water's unique dual capacity as an acid or a base in different contexts.