/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q11.57CP The compound 2,6-dimethyl pyrazi... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

The compound 2,6-dimethyl pyrazine (below) gives chocolate its odor and is used in flavourings.

  1. Which atomic orbitals mix to form the hybrid orbitalsN ?
  2. In what type of hybrid orbital do the lone pairsN reside?
  3. Is C inCH3 hybridized the same as anyC in the ring? Explain.

Short Answer

Expert verified

Hybridization provides a hybrid state for the overlapping of electrons to maximize stability.

The answer for

a)onesand two role="math" localid="1658940566747" p atomic orbitals.

b) sp2orbital

c) No

Step by step solution

01

Step 1: Definition

The atomic orbitals fuse to form new orbitals with completely different energies, shapes, and so on.

Atomic orbitals are mixed together to create hybrid orbitals. The total number of hybrid orbitals is equal to the no. of bond pair +no. of lone pair on the central atom.

02

Atomic orbital of  N

In the benzene ring, nitrogen is surrounded by two bond pairs and one lone pair. the one and two p atomic orbitals mix to form a hybrid orbital N. Hence, its hybridization isrole="math" localid="1658940814316" sp2 .

03

For lone pair of  N 

In the vacant sp2 orbital residing on the N atom, the lone pairs of nitrogen reside.

In the hybridized sp2 orbitals the lone pair is held because nitrogen has a pi bond (the unhybridized role="math" localid="1658940934760" p orbital) which must contain a pair of electrons used to form the double bond.

04

Hybridization of C  in  CH3

No, the hybridization of carbon CH3 issp3 as it is surrounded by 4 bond pairs (3H atoms+1C atom) whereas other carbon issp2 as it is surrounded by 2 bond pairs (2C atoms) and one lone pair.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Use MO diagrams and the bond orders you obtain from them to answer:

(a) IsBe2+ stable?

(b) Is Be2+diamagnetic?

(c) What is the outer (valence) electron configuration of Be2+?

The illustrations below depict differences in orbital hybridization of some tellurium ( Te ) fluorides.

(a) Which depicts the difference, if any, between TeF6 (left) and TeF5 (right)? (b) Which depicts the difference, if any, between TeF4 (left) and TeF6 (right)?

Use partial orbital diagrams to show how the atomic orbitals of the central atom lead to hybrid orbitals in

(a) AsCI3

(b) SnCI2

(c) PF6-

There is concern in health-related government agencies that the American diet contains too much meat, and numerous recommendations have been made urging people to consume more fruit and vegetables. One of the richest sources of vegetable protein is soy, available in many forms. Among these is soybean curd, or tofu, which is a staple of many Asian diets. Chemists have isolated an anticancer agent called genistein from tofu, which may explain the much lower incidence of cancer among people in the Far East. A valid Lewis structure for genistein is NN

  1. Is the hybridization of each Cin the right-hand ring the same? Explain.
  2. Is the hybridization of theO atom in the centre ring the same as that of theO atoms in OHgroups? Explain.
  3. How many carbon-oxygen σbonds are there? How many carbon-oxygen πbonds?
  4. Do all the lone pairs on oxygens occupy the same type of hybrid orbital? Explain.

Phosphine ( PH3 )reacts with borane ( BH3 ) as follows:

PH3+BH3→PH3-BH3

  1. Which of the illustrations below depicts the change, if any, in the orbital hybridization of P during this reaction?
  2. Which depicts the change, if any, in the orbital hybridization of B


See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.