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Calculate each of the following quantities:

(a) Volume of 18.0 M sulfuric acid that must be added to water to prepare 2.00 L of a 0.429 M solution

(b) Molarity of the solution obtained by diluting 80.6 mL of 0.225 M ammonium chloride to 0.250 L

(c) Volume of water added to 0.130 L of 0.0372 M sodium hydroxide to obtain a 0.0100 M solution (assume the volumes are additive at these low concentrations)

(d) Mass of calcium nitrate in each milliliter of a solution prepared by diluting 64.0 mL of 0.745 M calcium nitrate to a 铿乶al volume of 0.100 L

Short Answer

Expert verified

Answer

  1. Volume of sulfuric acid is 0.0477L

  2. Molarity of the solution is 0.0725 M

  3. Volume of water is 0.354L

  4. Mass of calcium nitrate is 0.0782g/L

Step by step solution

01

(a) Calculating volume of sulfuric acid

The dilution problems are solved by using molarity and volume relationship.

MdilVdil=MconcVconc

Where M and V stands for the molarity and volume of the dilute and concentrated solutions. In these types of dilution problems, the volume units should be same.

M1= 180M

M2= 0.429M

V2= 2.00L

V1=?

M1V1= M2V2

V1=M2V2M1=(0.429M)(2.00L)18.0M=0.0477L

02

(b) Calculating the molarity of the solution

The molarity is the number of moles of solute in each litre of solution.

M1 = 0.225M

V1 = 80.6 mL

Converting mL to L,

V1 = 80.6 脳 10-3= 0.0806 L

V2 = 2.250L

M2=?

M2=M1V1V2=(0.225M)(0.0876L)0.250L=0.07254M

03

(c) Calculating volume of water

The volume of water added is calculated by subtracting initial volume from final volume.

M1 = 0.0372M

V1 = 0.130L

M2 = 0.0100M

V2 =?

V2=M1V1M2=(0.0372M)(0.130L)0.0100M=0.4836L

Volumeofwateradded(L)=Finalvolume-Initialvolume=0.4836-0.130=0.3536L

04

(d) Calculating mass of calcium nitrate

M1 = 0.745M

V1 = 64.0mL 脳 10-3= 0.064L

V2 = 0.100L

M2= ?

M2=M1V1V2=(0.745M)(0.0640L)(0.100L)=0.4768M

Converting from moles of solute to grams per milliliter

Massof(CaNO3)2=(4.768molCa(NO3)2)164.10gCa(NO3)21molCa(NO3)2103mL=0.0782gCa(NO3)2/mL

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