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What is the general relationship between and EN for the elements? Why?

Short Answer

Expert verified

As the electronegativity increases of the atom, the ionization energy of the atom increases. It is difficult to eject an electron from the valence shell as the electrons are held tightly to the nucleus. Therefore, ionization energy decreases as the electronegativity decreases.

Both, electronegativity and first ionization energy increase across the period.

Step by step solution

01

Definition 

Electronegativityis defined as the property of an atom/molecule to attract the electron of the other atom/molecule. Every atom has an electronegativity property which depends on the size of the atom and also the electron cloud.

Ionization energy is defined as the amount of energy required to eject the electron from the loosely held electron from the valence shell of the atom.

02

Explanation

Electronegativity is a qualitative property thatdepends on the electron cloud and size of an atom.For example, the most electronegative atom in the periodic table is Fluorine.

Ionization energyis a quantitative property thatdepends on the amount of energy. As the amount of energy provided is greater, the faster the electron eject from the valence shell of the atom.

For example, the sodium atomrequires less energy to remove electrons from the valence shell and the fluorine atom requires a huge amount of I.E.

Hence, both, electronegativity (EN) and first ionization energy (1E1) increase across the period. Itis because while moving across the period, the number of valence electrons increases, and therefore, they more easily attract electrons towards themselves for completing their octet.

As the elements on the right side of the periodic table have a greater tendency to attract electrons, therefore they do not donate easily.Because of the huge difficulty in removing electrons needs more ionization energy.

Hence, both the tendency to attract electrons (EN) and the energy required to remove electron ( 1E1) increases across the period.

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Most popular questions from this chapter

Rank the members of each set of compounds in order of increasing the ionic character of their bonds. Use polar arrows to indicate the bond polarity of each:

(a) PCI3 , PBr3, PI3

(b) BF3 , NF3 , CF4

(c) SeF4 , TeF4, BrF3

The energy of the C-C bond is 347 kJ/mol, and that of the Cl-Cl bond is 243 kJ/mol. Which of the following values might you expect for the C-Cl bond energy? Explain.

(a) 590 kJ/mol (sum of the values given)

(b) 104 kJ/mol (difference of the values given)

(c) 295 kJ/mol (average of the values given)

(d) 339 kJ/mol (greater than the average of the values given)

There are two main types of covalent bond breakage. In homolytic breakage, each atom in the bond gets one of the shared electrons. In some cases, the electronegativity of adjacent atoms affects the bond energy. In heterolytic breakage, one atom gets both electrons and the other gets none; thus, a cation and an anion form.

a) Why is C-C bond in H3C-CF3 (423kJ/mol) stronger than that in H3C-CH3

(376kJ/mol)?

b) use bond energy and any other data to calculate the heat of reaction for the heterolytic cleavage ofO2 .

Using the periodic table only, arrange the elements in each set-in order of decreasing EN:

(a) N, P, Si;

(b) Ca, Ga, As.

Linear, triatomic CO2vibrates by symmetric stretch, bend, and asymmetric stretch with frequencies of 4.02×1013s-1, 2.00×1013s-1and 7.05×1013s-1 respectively.

  1. In what region of the electromagnetic spectrum are these frequencies?
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