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Does Q for the formation of 1 mol of NO from its elements differ from Q for the decomposition of 1 mol of NO to its elements? Explain and give the relationship between the two Q鈥檚.

Short Answer

Expert verified

The answer is,

Yes, the reaction quotient in the case of the formation of NO is the reciprocal of the reaction quotient in the case of decomposition of NO.

Step by step solution

01

Reaction quotient

The Reaction quotient of a chemical reaction at a particular point of time at a constant temperature is the ratio of the concentration of the products to that of the reactants raised with the stoichiometry of the compounds in the chemical equation of the reactions.

02

Explanation

The chemical equation for the formation of 1 mol of NO from its elements is given below.

12N2+12O2NO

Then the reaction quotient is given below.

Q=NON21/2O21/2

The chemical equation for the decomposition of 1 mol of NO to its elements is given below.

NO12N2+12O2

Then the reaction quotient is given below.

Q=N21/2O21/2NO

The reaction quotient for the formation and decomposition of NO is different. The reaction quotient in the case of the formation of NO is the reciprocal of the reaction quotient in the case of decomposition of NO.

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Most popular questions from this chapter

Consider the formation of ammonia in two experiments.

  1. To a 1.00-L container at727oC1.30mol of N2and 1.65molofH2are added. At equilibrium, 0.100molofNH3 is present. Calculate the equilibrium concentrations of N2andH2, and find Kcfor the reaction: 2NH3(g)N2(g)+3H2(g)
  2. In a different 1.00-L container at the same temperature, equilibrium is established with 8.3410-2molofNH3,1.50molofN2,and1.25molofH2 present. CalculateKc for the reaction:NH3(g)N2(g)+32H2(g)
  3. (c) What is the relationship between the Kc values in parts (a) and (b) ? Why aren't these values the same?

What does 鈥渄isturbance鈥 mean in Le Ch芒telier鈥檚 principle?

A mixture of \(5.00\) volumes of N2and 1.00 volume ofO2passes slowly through a heated furnace. Assuming it reaches equilibrium at1850Kand5.00atm, the reaction is

N2(g)+O2(g)2NO(g)Kp=1.4710-4

(a) What is the partial pressure of NO?

(b) What is the concentration in micrograms per litre(渭驳/L) ofNOin the mixture?

The molecular scenes below depict the reaction Y2Z at four different times, out of sequence, as it reaches equilibrium. Each sphere (Y is red and Zis green) represents0.025mol and the volume is0.40L .

(a) Which scene represents equilibrium?

(b) List the scenes in the correct sequence.

(c) CalculateKc .

Predict the effect of decreasing the temperature on the amounts of reactants in the following reactions:

(a) C2H2(g)+H2O(g)CH3CHO(g)螖贬rxn0=-151kj

(b) CH3CH2OH(I)+O2(g)CH3CO2H(I)+HO2(g)螖贬rxn0=-451kj

(c) 2c2H4(g)+O2(g)2CH3CHO(g)(exothermic) (d)N2O42NO2(g)(endothermic)
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